Article
Chemistry, Physical
Yi Jin, Fengzhen Zhang, Jingyuan Fan, Hua-Jun S. Fan
Summary: In this study, Ag-Cu bimetallic nanoclusters on halloysite nanotubes (HNT) were successfully prepared using a chemical reduction method, and their antimicrobial effects were demonstrated. HNT is an interesting nanomaterial with a hollow tubular structure that can be used as an important and effective carrier for applications such as drug delivery. The bimetallic nanoclusters exhibited synergistic effects and improved antibacterial properties.
APPLIED CLAY SCIENCE
(2023)
Review
Biology
Xinzhen Fan, L'Hocine Yahia, Edward Sacher
Summary: The antimicrobial properties of Ag and Cu nanoparticles, whether used separately or in combination, are well known and can be further enhanced when mixed or alloyed. Factors such as the size, shape, and surface treatment of nanoparticles can influence their antimicrobial activities.
Article
Chemistry, Inorganic & Nuclear
C. S. Shivananda
Summary: Colloidal silver nanoparticles were synthesized using aqueous silk fibroin under white light and at ambient temperature. The nanoparticles exhibited a characteristic surface plasmon resonance band in the UV-Vis spectrum and were spherical with smooth surfaces, with sizes ranging from 35 to 40 nm. X-ray diffraction analysis confirmed the presence of silver nanocrystals with an FCC crystal structure. These biogenic silver nanoparticles showed significant antibacterial activity against human bacterial pathogens and also exhibited excellent anti-cancer activity at low dosage.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Multidisciplinary Sciences
Deepika Sharma, Lalita Ledwani, Naveen Kumar, Tarang Mehrotra, Naveed Pervaiz, Ravinder Kumar
Summary: This study reports an eco-friendly and cost-effective technique for synthesizing bimetallic silver-copper nanoparticles using R. emodi roots extract (RERE), with potential anticancer and antibacterial applications. The nanoparticles were thoroughly characterized using various techniques to understand their physicochemical properties.
ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING
(2021)
Article
Multidisciplinary Sciences
Sajedeh Tehrani Nejad, Rahmatollah Rahimi, Mahboubeh Rabbani, Sadegh Rostamnia
Summary: This research focuses on the one-step synthesis of novel porphyrin-based nanocomposites using a photochemical strategy under visible light illumination. The synthesized nanocomposites, including ZnTPP/Ag, ZnTPP/Ag/AgCl/Cu, and ZnTPP/Au/Ag/AgCl, exhibited high antibacterial properties, which were tested against Escherichia coli and Staphylococcus aureus using various methods. The nanocomposites also showed admissible photosensitizing properties, mild reaction conditions, and potential for medical applications, photodynamic therapy, and water treatment.
SCIENTIFIC REPORTS
(2023)
Article
Chemistry, Physical
K. Chandramouli, B. Suryanarayana, T. Anil Babu, Vemuri Raghavendra, D. Parajuli, N. Murali, Venkaiah Malapati, Tulu Wegayehu Mammo, P. S. Shanmukhi, Umesh Reddy Gudla
Summary: The structure, particle size, and antibiotic nature of synthesized ZnO nanoparticles were studied using XRD, TEM, and FTIR, revealing spherical particles with a single wurtzite hexagonal crystal structure. The correlation between defect and antibiotic properties of ZnO was identified.
SURFACES AND INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
T. S. Freitas, T. M. F. Marques, L. N. L. C. Barros, J. H. da Silva, R. P. Cruz, R. L. S. Pereira, A. R. P. Silva, A. T. L. Santos, A. Ghosh, E. V. H. Agressott, B. C. Viana, H. D. M. Coutinho, P. T. C. Freire
Summary: Copper ion-exchanged titanate nanotubes were prepared by ion exchange reaction and showed potential antibacterial properties as an adjuvant in antibiotic therapy, enhancing the antibiotic activity against strains of Staphylococcus aureus, Pseudomonas aeruginosa, and Escherichia coli.
MATERIALS TODAY CHEMISTRY
(2021)
Article
Chemistry, Physical
Neli Mintcheva, Marinela Panayotova, Gospodinka Gicheva, Orlin Gemishev, Georgy Tyuliev
Summary: Silver nanoparticles (AgNPs) were supported on natural and modified zeolites through loading silver ions (Ag+) followed by thermal reduction, resulting in nanocomposites with different antibacterial activities. Na-modified zeolite demonstrated the highest antibacterial activity against Escherichia coli among the tested composites.
Article
Chemistry, Physical
Youngtae Park, Changsoo Lee, Jungwoo Choi, Phil Woong Kang, Christina Scheu, Hyuck Mo Lee, Pyuck-Pa Choi, Chanwon Jung
Summary: In this study, it was demonstrated that the interface between Ag-rich and Cu-rich AgCu phases enhances the oxygen reduction activity of model alloys. AgCu alloys with eutectic composition showed a typical lamellar structure of Ag-rich and Cu-rich AgCu phases, and exhibited better oxygen reaction activity despite a lower fraction of Ag-rich AgCu phase. Atom probe tomography analysis revealed the presence of a CuO layer at the interface of the two phases. Density functional theory calculations further explained the enhanced activity by showing the preferential adsorption of OH near the interface, facilitating the most sluggish OH desorption step.
APPLIED SURFACE SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Anupam Mondal, Naba Kumar Mondal
Summary: In this study, Multi-walled carbon nanotubes (MWCNTs) were decorated with bile juice-mediated copper nanoparticles synthesized using a green method. The antimicrobial activity of BJ-Cu@MWCNT was evaluated against S. aureus and P. aeruginosa, with minimum inhibitory concentration (MIC) values of 24 and 16 mu g/mL, respectively. Extensive experiments were conducted to explore the mechanism of bacterial death. The synthesized nanomaterial also showed excellent antibiofilm properties against the same bacterial strains. The findings suggest that the synthesized nanomaterial could be a potent antibacterial and antibiofilm agent against pathogenic Gram-negative and Gram-positive bacteria.
Article
Chemistry, Physical
Fang Zhou, Yan Zhu, Longlai Yang, De-Quan Yang, Edward Sacher
Summary: The aqueous dispersions of AgCu nanoparticles with enhanced antibacterial efficacy were prepared by the catalyzed reduction of Cu ions by PVP/PVA-stabilized Ag nanoparticles at 85 degrees C. The enhanced antibacterial performance of these nanoparticles was correlated with the release of Ag ions, proposing a simple model of AgCu NP formation and an enhanced antibacterial efficacy mechanism involving Ag ion release.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Crystallography
Shalendra Kumar, Faheem Ahmed, Nagih M. Shaalan, Osama Saber
Summary: Bio-inspired synthesis of CeO2 nanoparticles using egg white showed promising antibacterial properties against Escherichia coli and Staphylococcus aureus. The nanoparticles exhibited different levels of antibacterial activity against the two bacteria, with a stronger inhibition effect observed against S. aureus compared to E. coli.
Article
Nanoscience & Nanotechnology
Giuseppe Sanzone, Susan Field, David Lee, Jingzhou Liu, Pengfei Ju, Minshi Wang, Parnia Navabpour, Hailin Sun, Jinlong Yin, Peter Lievens
Summary: Wear-resistant antimicrobial thin films prepared by magnetron sputtering can effectively inhibit the proliferation of bacteria and fungi inside spacecrafts, and they have long-lasting antibacterial effects. Among them, silver cluster-doped amorphous carbon coatings not only have good antibacterial effects, but also have a longer lifespan.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
Michael Burtscher, Markus Alfreider, Christina Kainz, Klemens Schmuck, Daniel Kiener
Summary: Grain refinement of W-Cu composites was achieved using high-pressure torsion, resulting in improved mechanical properties. Various characterization methods were applied to analyze the microstructures and identify the beneficial and unfavourable components affecting the fracture properties.
MATERIALS & DESIGN
(2022)
Article
Chemistry, Multidisciplinary
Muhammad Hamza, Ataf Ali Altaf, Samia Kausar, Shahzad Murtaza, Amen Shahpal, Muhammad Hamayun, Muhammad Tayyab, Komal Rizwan, Hamza Shoukat, Anum Maqsood
Summary: This work investigates the photocatalytic degradation of alizarin red using Cu-doped manganese oxide nanomaterials as catalysts under UV light irradiation. The synthesized nanoparticles, with Cu-doped manganese oxide as the catalyst, exhibited high efficiency in the degradation of alizarin red, with MH20 showing the highest degradation rate. The results indicate the potential of Cu-doped manganese oxides as effective catalysts for the removal of alizarin red.
Article
Polymer Science
M. Leo Edward, K. C. Dharanibalaji, K. Thileep Kumar, A. Raghu Subash Chandrabose, A. M. Shanmugharaj, V Jaisankar
Summary: A bioactive and non-toxic biopolymer-based electrolyte, extracted from shrimp shells and prepared successfully, shows great potential for applications in electrochemical devices with excellent ionic conductivity and mechanical properties. The electrolyte was characterized using various techniques, confirming its superior performance and stability.
Article
Environmental Sciences
T. Veldevi, S. Raghu, R. A. Kalaivani, A. M. Shanmugharaj
Summary: The uncontrolled accumulation of end-of-life tires poses serious environmental concerns, but converting them into value added products can be a viable solution. By developing carbonaceous-based anode materials through a novel chemical activation strategy, significant improvement in lithium battery performance can be achieved, providing a new roadmap for recycling waste tires for energy storage applications.
Article
Energy & Fuels
Swati Chaudhary, Om Prakash Sinha, Raja Mohan
Summary: This study proposes a simple, eco-friendly, and cost-effective method for synthesizing reduced graphene oxide, carbon dots, and zinc oxide nanocomposites. The nanocomposites show promising potential as electrode materials for supercapacitors, with high capacitance and flexibility.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
G. Sivagaami Sundari, K. Thileep Kumar, E. Senthil Kumar, A. M. Shanmugaraj, R. Kalaivani, S. Raghu
Summary: A scalable synthesis of 3D porous graphitized carbon powder using carbonization and activation of Prosopis juliflora has been reported for symmetric supercapacitor applications. The optimized carbon material showed significant improvement in surface area and specific capacitance, making it a promising alternative electrode material for high energy supercapacitors.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2022)
Article
Chemistry, Multidisciplinary
K. Thileep Kumar, S. Raghu, A. M. Shanmugharaj
Summary: Blister packing materials made of foamed plastics are a major environmental concern due to their disposal methods, and the effective recycling of these materials has become a research focus. This study successfully prepared defect-engineered graphene-like turbostratic carbon materials derived from waste plastics and found that they exhibited excellent electrochemical properties and cycling stability when used as anodes for lithium-ion batteries. The research opens up a new pathway for generating value-added carbon materials from blister pack waste.
Article
Multidisciplinary Sciences
G. Sabeena, S. Rajaduraipandian, S. P. Mano Bala, T. Manju, Hisham A. Alhadlaq, Raja Mohan, G. Annadurai, Maqusood Ahamed
Summary: In this study, CuO-SiO2 nanocomposite (CuONC) and Fe doped CuO-SiO2 nanocomposite (FeCuONC) were synthesized and their biological activities and toxicity were investigated. FeCuONC showed higher anti-inflammatory effects and antidiabetic activity compared to CuONC. In addition, FeCuONC induced a higher innate immunity response in zebrafish. This study highlights the potential therapeutic applications of Fe-CuO-SiO2 nanocomposites.
JOURNAL OF KING SAUD UNIVERSITY SCIENCE
(2022)
Article
Multidisciplinary Sciences
Bakeel A. Radman, Bushra Y. H. Al-Khatib, ZabnAllah M. Alaizeri, AbdulHaleem S. Al-Tamimi, Waleed E. Al-Thahibi, Raja Mohan, Hisham A. Alhadlaq, Maqusood Ahamed
Summary: The study showed that L. sativum seeds have the potential to accelerate callus formation, fracture line repairing, and new bone regeneration, highlighting the importance of folk herbs in healing of fractured bones.
JOURNAL OF KING SAUD UNIVERSITY SCIENCE
(2022)
Article
Multidisciplinary Sciences
G. Sabeena, S. Rajaduraipandian, E. Pushpalakshmi, Hisham A. Alhadlaq, Raja Mohan, G. Annadurai, Maqusood Ahamed
Summary: CuO nanoparticles (NPs) are widely used in catalyst, electronics, cosmetics, and biomedicines due to their exceptional physicochemical properties. In this study, the in vitro and in vivo bioactivities of CuO NPs synthesized through green and chemical routes were compared. The results showed that green synthesized CuO NPs exhibited lower toxicity and higher antibacterial, cytotoxic, antidiabetic, and anti-inflammatory activities compared to chemically synthesized CuO NPs. Additionally, green CuO NPs showed higher biocompatibility towards zebrafish embryos. This highlights the importance of eco-friendly green synthesis of CuO NPs for biomedical applications.
JOURNAL OF KING SAUD UNIVERSITY SCIENCE
(2022)
Article
Multidisciplinary Sciences
Rajaduraipandian Subramanian, Amutha Eswaran, Sabeena G. Kathirason, Sivagurusundar Ramar, Gandhimathi Sivasubramanian, Hisham A. Alhadlaq, Raja Mohan, Annadurai Gurusamy, Maqusood Ahamed
Summary: This study synthesized chitosan-modified platinum-doped silver nanocomposites using a green method, and demonstrated their excellent biological and photocatalytic activities, which suggest their potential applications in environmental and biomedical fields.
JOURNAL OF KING SAUD UNIVERSITY SCIENCE
(2022)
Article
Multidisciplinary Sciences
M. Sivakavinesan, M. Vanaja, Rashid Lateef, Hisham A. Alhadlaq, Raja Mohan, G. Annadurai, Maqusood Ahamed
Summary: This study focuses on the green synthesis of gold nanoparticles using peel extract of sweet lime. The bioactive components in the extract act as reducing and capping agents for the synthesis process. The gold nanoparticles demonstrate excellent antioxidant and catalytic activities, highlighting the potential of utilizing bio-waste for noble metal nanoparticle production.
JOURNAL OF KING SAUD UNIVERSITY SCIENCE
(2022)
Review
Biochemistry & Molecular Biology
Ganesh Gollavelli, Gangaraju Gedda, Raja Mohan, Yong-Chien Ling
Summary: Carbon neutrality is aimed at reducing global warming, and batteries are seen as the best alternatives to fossil fuels, with lithium-ion and lithium-air batteries having the potential to meet the increasing demands of the energy sector. However, lithium-air batteries face challenges in achieving high power capacity, which can be improved through the use of materials like graphene.
Article
Nanoscience & Nanotechnology
Deepa Gangaraju, A. M. Shanmugharaj, Vadahanambi Sridhar, Hyun Park
Summary: This article reports a method for synthesizing nano meter-sized Ni-MOF/CNT and evaluates its morphological characteristics and chemical changes. The results show the potential applications of this material as an electro-catalyst in urea oxidation reactions and in the removal of arsenic from contaminated water, and demonstrate the applicability of a similar method for synthesizing nano meter-sized Fe-MOF/CNT.
ACS APPLIED NANO MATERIALS
(2022)
Article
Chemistry, Physical
Srinivas Billakanti, Anjana K. Othayoth, Heeralal Vignesh Babu, Andikkadu M. Shanmugharaj, Prachuritha Bantumelli, Krishnamurthi Muralidharan
Summary: This paper presents the synthesis, characterization, and Li-ion conductivity of catechol-based copolymer of polyphosphates (P1-P4) for solid polymer electrolyte (SPE) applications in Li-ion batteries. The results show that the Li-ion conductivity of the synthesized polymers is highest at 80 degrees C compared to previous literature. Galvanostatic charge-discharge cycling studies on the coin cells fabricated using one of the SPEs demonstrate stable cycling behavior for about 2000 cycles.
ACS APPLIED ENERGY MATERIALS
(2023)
Review
Polymer Science
Raja Mohan, Fathilah Ali
Summary: MXenes-based TENGs have shown exciting potential in various applications, such as wearable sensors and electrochemical energy storage, and further research is needed to evaluate their performance and suitability.
POLYMERS FOR ADVANCED TECHNOLOGIES
(2023)
Article
Chemistry, Multidisciplinary
S. Panimalar, T. Kamatchi, P. Kumaresan, S. Nithiyanantham, R. Mohan
Summary: Analyzing dissymmetric molecules of semi-organic dyes doped thiourea barium chloride (TBC) single crystals has been conducted to improve the SHG frequency and utilize it in casting NLO devices. Germination and transformation of dyes doped TBC crystals were achieved through slow vaporization and vapor diffusion methods, respectively. Characterization techniques such as PXRD, UV-vis spectra, and FT-IR analysis were used to examine the lattice parameters, optical transmission, and functional groups of the grown crystals. The NLO and SHG studies showed that the doped TBC exhibited higher efficiency than the pure one.
CHEMISTRY AFRICA-A JOURNAL OF THE TUNISIAN CHEMICAL SOCIETY
(2022)