Article
Polymer Science
Krittameth Kiattipornpithak, Pornchai Rachtanapun, Sarinthip Thanakkasaranee, Pensak Jantrawut, Warintorn Ruksiriwanich, Sarana Rose Sommano, Noppol Leksawasdi, Thorsak Kittikorn, Kittisak Jantanasakulwong
Summary: A novel PLA composite with excellent mechanical properties, toughness, thermal stability, and water resistance was successfully developed using a reactive melt-blending technique. The addition of epoxy resin and bamboo pulp improved the reaction and mechanical properties, and reduced the gap between PLA and pulp. The toughness and thermal stability of the PLA/PULP composites were enhanced.
Article
Polymer Science
Zhaolei Li, Xinxin Ye, Chunfeng Meng, Haijun Zhou, Weijie Guo, Shangtao Chen, Jianming Zhang, Chao Yan, Alain Dufresne
Summary: Introducing a crosslinkable epoxy resin (EP) into poly(l-lactic acid)/poly(d-lactic acid) racemic blends was found to inhibit homo-crystals and promote stereocomplexation, although it delayed lamellar thickening of the stereocomplex crystals during heating due to constrained chain diffusion caused by the uniformly dispersed EP network. This approach shows promise for gaining deeper insights into poly(lactic acid) stereocomplexation.
POLYMER INTERNATIONAL
(2021)
Review
Materials Science, Composites
Ling Zhou, Kai Ke, Ming-Bo Yang, Wei Yang
Summary: This review summarizes recent research on the chemical modification strategies of cellulose in PLA/cellulose composites over the past five years, focusing on two major classifications: reactions of small molecules modified cellulose and reactions of polymers modified cellulose. The review discusses the relationship between the structure of grafted small molecules/polymers and the mechanical properties of PLA composites, and addresses common problems hindering the development of high-performance PLA/cellulose composites through chemical modification.
COMPOSITES COMMUNICATIONS
(2021)
Article
Multidisciplinary Sciences
Taksid Charasseangpaisarn, Chairat Wiwatwarrapan, Pasutha Thunyakitpisal, Viritpon Srimaneepong
Summary: This study aimed to investigate the optimal ratio of PMMA/PLA blends for potential dental applications. The results showed that increasing PMMA content in the blend increased the Tg, and the blend exhibited superior flexural properties compared to neat PMMA and neat PLA. The biocompatibility did not differ among different composition ratios.
SCIENTIFIC REPORTS
(2023)
Article
Chemistry, Multidisciplinary
Jiajie Yu, Yi Huang, Songting Yu, Zepeng Huang, Shujie Yu, Ling Zhou, Shaoxian Peng, Xipo Zhao
Summary: The preparation of low molecular weight polylactic acid (PLA) through melt polycondensation limits its application range, thus the introduction of branched structures and active groups has become an important means to expand its application. In this study, pentaerythritol and sorbitol were used as core molecules for melt polycondensation with l-lactic acid, resulting in the successful preparation of epoxy-functionalized star-shaped PLA.
REACTION CHEMISTRY & ENGINEERING
(2023)
Article
Materials Science, Multidisciplinary
Yunchuan Zeng, Qianqian Wang, Pengwu Xu, Weijun Yang, Martin Hoch, Piming Ma
Summary: This study improved the compatibility between solid rubber and epoxy resin by functionalizing solid rubber with carboxyl and amino groups, leading to better toughening effect in EP systems without sacrificing tensile strength and heat resistance. The novel approach of in situ constructing interfacial bonding and elastic segments into epoxy network resulted in EP-based thermosets with improved strength and toughness, broadening the application range of solid rubber in epoxy toughening.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Polymer Science
Yuanyuan Dou, Han Wu, Li Zhang, Zhenbo Ning, Ni Jiang, Zhihua Gan
Summary: Three types of spherulitic morphologies, including conventional ring-banded spherulites, special spherulites with a curve-like morphology, and composite spherulites, were found in PCL-b-PA6-b-PCL due to the wide crystallization temperature range of chemically jointed PA6 blocks. The formation conditions, internal factors, and lamellar orientation and assembly of different spherulites were studied in detail. The appearance of unusual spherulitic morphology may result from different internal stress induced by chemically jointed PA6 blocks under diverse crystallization conditions.
Article
Chemistry, Applied
Yaowalak Srisuwan, Yodthong Baimark
Summary: This paper reports a study on flexible polymer blends made from PLLA-PEG-PLLA and TPS. The addition of TPS suppressed crystallizability of PLLA and PLLA-PEG-PLLA matrices, while greatly increasing the thermal stability of PLLA-PEG-PLLA. The PEG middle-blocks enhanced phase compatibility between PLLA-PEG-PLLA and TPS, resulting in ductile and flexible blend films.
CARBOHYDRATE POLYMERS
(2022)
Article
Engineering, Multidisciplinary
Nashriq Jailani, Ahmad Nazrul Hakimi Ibrahim, Abdur Rahim, Norhidayah Abdul Hassan, Nur Izzi Md. Yusoff
Summary: This study investigated the feasibility and effects of poly(lactic) acid (PLA) on bitumen modification. The results showed that there is a chemical interaction between PLA and bitumen, leading to enhanced performance of modified bitumen in terms of consistency, storage stability, and prevention of phase segregation.
AIN SHAMS ENGINEERING JOURNAL
(2021)
Article
Polymer Science
Sudan Zhou, Maolin Guo, Yujuan Jin, Jianjian Sun, Huafeng Tian, Jing Hu
Summary: This study modified poly(lactic acid) (PLA) by melt blending it with epoxy-terminated hyperbranched polymer (EHBP) to improve its toughness and strength. The results showed that the epoxy groups within EHBP reacted with carboxyl and hydroxyl groups of PLA, creating chemical micro-crosslinking, and intermolecular hydrogen bonds were also formed between EHBP and PLA. The combination of these factors led to improved mechanical properties of PLA. The best modification effect was achieved when 2.5 phr of EHBP was added.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Materials Science, Characterization & Testing
Yuhao Liu, Ying Lin, Bin Cao, Kangning Wu, Liming Wang
Summary: The unclear molecule structures-compatibility relationship hinders the improvement of compatibility between polysiloxane and epoxy resins. By analyzing different terminal groups, it is found that the solubility and chemical bonding of polysiloxanes are mainly governed by van der Waals interaction, while electrostatic interaction is influenced by the number of terminal atoms. Based on this, a silicone prepolymer is synthesized to enhance compatibility by increasing the number of terminal atoms and introducing -NH2 groups.
Article
Agricultural Engineering
Qiu-yu Ge, Qiang Dou
Summary: Reactive additives were used to improve the interfacial compatibility, mechanical properties, and surface hydrophobicity of polyL-lactic acid/epoxidized soybean oil bio-based blends. The type and amount of additives significantly influenced the properties of the blends.
INDUSTRIAL CROPS AND PRODUCTS
(2022)
Article
Chemistry, Multidisciplinary
Ming Li, Shengnan Li, Bujin Liu, Tuanhui Jiang, Di Zhang, Lushuai Cao, Li He, Wei Gong
Summary: A random terpolymer was used to improve the foaming behavior of poly (lactic acid) (PLA) through chain extension reaction, forming a branched/micro-crosslinked structure to enhance the crystallization properties and dynamic rheological behavior of PLA. Increasing the content of EGMA accelerated crystal nucleation and growth rate of PLA, resulting in reduced cell size and increased cell density of PLA foams.
Article
Materials Science, Composites
Shuobing Yang, Ting Li, Yang Wang, Xuhui Zhang, Shibo Wang, Jing Huang, Weifu Dong
Summary: This study presents the preparation of bio-based recyclable epoxy composites with significantly improved thermal conductivity by utilizing poly(lipoic acid) modified liquid metal as the crosslinkers. The formation of a poly(lipoic acid) shell layer on the liquid metal droplet core facilitates thermal transport in the composites. Additionally, the composites exhibit reprocessability and degradability.
COMPOSITES COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Hafezeh Nabipour, Xin Wang, Lei Song, Yuan Hu
Summary: The study focused on the development of a fully bio-based epoxy thermoset from syringaldehyde and furfurylamine, which exhibited high glass transition temperature, mechanical strength, intrinsic flame resistance, and antibacterial properties. This bio-based epoxy thermoset showed superior performance compared to petroleum-based epoxy thermosets, making it a promising green substitute for high performance applications in fire safety.