4.6 Article

Effects of the Dispersion State and Aspect Ratio of Carbon Nanotubes on Their Electrical Percolation Threshold in a Polymer

Journal

JOURNAL OF APPLIED POLYMER SCIENCE
Volume 128, Issue 1, Pages 735-740

Publisher

WILEY-BLACKWELL
DOI: 10.1002/app.37554

Keywords

carbon nanotubes; polymer blends; nanocomposites; modeling

Funding

  1. National Natural Science Foundation of China [50973053]
  2. Specialized Research Fund for the Doctoral Program of Higher Education [20090002110072]

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The electrical percolation threshold of carbon nanotubes (CNTs) is correlated with their dispersion state and aspect ratio through modeling. An analytical percolation model based on excluded volume theory and developed for systems containing two types of fillers is used. CNTs are modeled as two types of fillers: single CNT and m-CNT bundle, and a variable P representing the dispersion state of CNTs is introduced. An equation showing the effects of the dispersion state and aspect ratio on the electrical percolation threshold of CNTs is established and verified with some of the published experimental data. It is useful for predicting the conductive behavior of polymer/CNT composites and for the design of their processing conditions. (C) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 128: 735-740, 2013

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