Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 118, Issue 1, Pages 165-172Publisher
WILEY
DOI: 10.1002/app.30125
Keywords
dyes/pigments; initiators; kinetics (polym.); photopolymerization
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Funding
- The Ministry of Science and Higher Education [N N204 219734, BS-13/2006]
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Results of kinetic studies of two-component photoinitiator systems used in the visible-light photoid uced polymerization of 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate are presented. Nine different styrylquinolinum dyes coupled with n-butyltriphenylborate as a coinitiator have been used as photoinitiating systems. Reactive radicals that initiate the polymerization are formed by the well-known mechanism of photoinduced electron transfer between dye cations acting as electron acceptors and borate anions acting as electron donors. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 118: 165-172, 2010
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