Article
Nanoscience & Nanotechnology
Hongyu Lu, Deqi Yi, Haisheng Feng, Boyou Hou, Jianwei Hao
Summary: In this study, the influence of crystal structure difference of melamine trimetaphosphate (MAP) on the application performance of its polymer composites was explored. An intumescent flame retardant with the optimal crystal type, I-MAP and II-MAP, was synthesized and used to improve the mechanical properties and flame retardancy of polyamide 6 (PA6). The comprehensive characterization of morphology, chemical composition, and thermal stability was conducted, and the dispersion, mechanical properties, and flame retardancy of PA6/I-MAP and PA6/II-MAP were evaluated. The results showed that PA6/II-MAP exhibited significantly improved tensile strength, flame rating, and PHRR compared to PA6/I-MAP.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Polymer Science
Feiyue Wang, Jiahao Liao, Long Yan, Mengtao Cai
Summary: In this study, a unique mono-component intumescent flame retardant PPy-MAPP was synthesized and applied to epoxy resin to obtain flame-retarded EP composites. The results demonstrate that PPy-MAPP greatly improves the flame retardancy and smoke suppression properties of EP. The mechanical test shows that PPy-MAPP has a minimal negative effect on the tensile strength and elastic modulus of epoxy resin.
Article
Thermodynamics
Tao Chen, Xin-Ya Liu, Ting Wang, Lei He, Jin-Ni Deng, Zhi-Cheng Fu, Tian-Bao Zhao, Chang-Lin Xia, Zhi-hui Liu, Ming-Jun Chen
Summary: In this study, hydroxylated melamine (MOH) was synthesized and used as a charring and blowing agent in combination with ammonium polyphosphate (APP) to develop an intumescent flame retardant for epoxy resin. The resulting APP/MOH system significantly improved the flame retardancy of epoxy resin, achieving a LOI value of 32.5% and reaching UL 94 V-0 standards. Compared to other flame retardant systems, such as APP/PER, the APP/MOH system exhibited lower peak heat release rate and peak smoke production rate.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2023)
Article
Polymer Science
Chung-Hyok Jo, Yong-Man Jang, Dae-Hyok Mun, Chol-Jun Yu, Chung-Guk Choe, Song-Guk Ri
Summary: Organic phosphorus-nitrogen flame retardant was synthesized and used in coatings to enhance the flame retardancy. The addition of titanium dioxide further improved the flame retardancy of the coatings.
POLYMER DEGRADATION AND STABILITY
(2023)
Article
Polymer Science
Florian Tomiak, Angelina Schoeffel, Klaus Rathberger, Dietmar Drummer
Summary: Expandable graphite (EG), aluminum (diethyl)polyphosphinate (AlPi), and melamine polyphosphate (MPP) were used as flame retardant multi-material additives in a polyamide 6 (PA6) matrix. The study found that there was a synergistic effect between EG and AlPi/MPP, leading to an increase in oxygen index and mechanical residue stability. The synergy was attributed to the CO2 evolution during decomposition stages and the solid decomposition products of AlPi/MPP acting as glue between expanded graphite.
Article
Polymer Science
Wentao He, Huahui Xu, Pingan Song, Yushu Xiang, Shuhao Qin
Summary: P, N-decorated halloysite nanotubes were prepared and incorporated into polyamide 6/aluminum diethylphosphinic acid composite, leading to improved flame retardancy. The flame retardant mechanism involves the formation of intumescent char and enhanced barrier effect for heat and mass transfer.
POLYMER DEGRADATION AND STABILITY
(2022)
Article
Thermodynamics
Zhongwei Chen, Yuan Yu, Qingwu Zhang, Zhiquan Chen, Tingting Chen, Changxin Li, Juncheng Jiang
Summary: Surface-modified ammonium polyphosphate, when incorporated with other compounds, significantly enhances the flame retardancy and thermal stability of unsaturated polyester resin, leading to the formation of materials with good carbonization ability.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2021)
Article
Engineering, Manufacturing
Feng-Ming He, Bo-Wen Liu, Li Chen, De-Ming Guo, Xiao-Min Ding, Yan-Fang Xiao, Hai-Bo Zhao, Wen-Da Li, Yu-Zhong Wang
Summary: Two Schiff-base containing phosphonate oligomers, PSA and POSC, were designed as novel flame retardants for PA 6, achieving improved flame retardancy without sacrificing mechanical properties. The different flame-retardant mechanisms of these two additives were comprehensively studied, leading to the development of efficient flame-retardant polyamide composites with excellent performance.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2021)
Article
Polymer Science
Xuejun Shi, Baoting Wei, Yongjun Han, Xiangxiang Du, Guoxu He
Summary: Silicon carbide (SiC) modified by melamine polyphosphate (MPP)-modified silicone was incorporated into epoxy resin (EP) to develop thermally resistant composites with improved thermal conductivity and flame retardancy. The composites exhibited enhanced flame retardancy and thermal conductivity compared to pure epoxy.
Article
Materials Science, Multidisciplinary
Thomas J. Kolibaba, Aman Nigam, Bruce L. Tai, Jaime C. Grunlan
Summary: FR composite filament composed of PA6, ammonium polyphosphate, and aluminum phosphate shows a significant increase in char yield and decreases in peak heat release rate and total heat release. This unique FR additive system represents an important improvement in the safety and utility of 3D printed parts.
MACROMOLECULAR MATERIALS AND ENGINEERING
(2021)
Article
Polymer Science
Tao Zheng, Wengui Wang, Yaochi Liu
Summary: In this study, a novel phosphorus-nitrogen flame retardant CN-DOPO was successfully synthesized and applied in PA6 composites, showing an increase in LOI value and passing UL-94 rating without significant deterioration in mechanical properties of PA6. The morphological analysis revealed that CN-DOPO formed a highly integrated char layer during combustion, while decomposed gases could dilute flammable volatiles, indicating a special gas-condensed phase synergistic flame-retardant mechanism in PA6/CN-DOPO composites.
POLYMERS FOR ADVANCED TECHNOLOGIES
(2021)
Article
Polymer Science
Wen-Jie Jin, Wei-Lin He, Liang Gu, Xian-Wei Cheng, Jin-Ping Guan
Summary: This study developed an eco-friendly intumescent flame retardant coating for polyamide 6 fabric. The coated fabric exhibited excellent flame retardancy with reduced heat release rate and eliminated dripping. The mechanical properties of the fabric were minimally affected by the coating.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Polymer Science
Yanlu Sun, Zhengqi Wang, Dequn Wu, Xueli Wang, Jianyong Yu, Ruchao Yuan, Faxue Li
Summary: The lack of flame retardants with suitable thermal properties and high flame retardancy hinders the development of flame-retardant polyamide 6 (PA6). In this study, a phosphorus-containing flame retardant (CBPB) with flame-responsive nitrile groups was synthesized, and its properties matched those required for flame retardancy in PA6. PA6/CBPB composites (FR-PA6s) were prepared by blending CBPB into the PA6 matrix, resulting in materials with V-0 UL-94 rating and a limiting oxygen index (LOI) of 32.0% when 8 wt% of CBPB was added. FR-PA6-6, a representative composite with 6 wt% CBPB, exhibited good mechanical properties and self-extinction in 4 seconds during vertical burning tests, with minimal dripping.
POLYMER DEGRADATION AND STABILITY
(2022)
Article
Engineering, Environmental
Haisheng Feng, Dinghua Li, Bo Cheng, Tinglu Song, Rongjie Yang
Summary: This study investigates the combustion behaviors of OPS/ADP/PA6, demonstrating the synergistic effect of OPS and ADP in reducing heat, smoke, and CO release rates in PA6. The use of a cross-linked charring strategy significantly mitigates the smoke and heat hazards of PA6.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Jing Gao, Wentao He, Yushu Xiang, Lijuan Long, Shuhao Qin
Summary: The study demonstrated that DOPO-NH2 showed superior thermal, flame retardant, and mechanical performances to PA6 composites, mainly due to the existence of amino terminal group which improved the compatibility between the flame retardant and PA6 matrix.
FRONTIERS IN CHEMISTRY
(2022)