Inducing and quantifying forbidden reactivity with single-molecule polymer mechanochemistry

Model studies of force-dependent kinetics of multi-barrier reactions

(2013) Yancong Tian et al.   Nature Communications

Tension Trapping of Carbonyl Ylides Facilitated by a Change in Polymer Backbone

(2012) Hope M. Klukovich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A backbone lever-arm effect enhances polymer mechanochemistry

(2012) Hope M. Klukovich et al.   Nature Chemistry

Force-Transformed Free-Energy Surfaces and Trajectory-Shooting Simulations Reveal the Mechano-Stereochemistry of Cyclopropane Ring-Opening Reactions

(2011) Przemyslaw Dopieralski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactive Cross-Talk between Adjacent Tension-Trapped Transition States

(2011) Jeremy M. Lenhardt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Competition between Orbitals and Stress in Mechanochemistry

(2010) Gurpaul S. Kochhar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular Stress Relief through a Force-Induced Irreversible Extension in Polymer Contour Length

(2010) Dong Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction dynamics in the formidable gap

(2010) Roman Boulatov   PURE AND APPLIED CHEMISTRY

Trapping a Diradical Transition State by Mechanochemical Polymer Extension

(2010) J. M. Lenhardt et al.   SCIENCE

Mechanochemistry: One Bond at a Time

(2009) Jian Liang et al.   ACS Nano

Understanding Covalent Mechanochemistry

(2009) Jordi Ribas-Arino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unravelling the Mechanism of Force-Induced Ring-Opening of Benzocyclobutenes

(2009) Jordi Ribas-Arino et al.   CHEMISTRY-A EUROPEAN JOURNAL

First Principles Dynamics and Minimum Energy Pathways for Mechanochemical Ring Opening of Cyclobutene

(2009) Mitchell T. Ong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

gem-Dichlorocyclopropanes as Abundant and Efficient Mechanophores in Polybutadiene Copolymers under Mechanical Stress

(2009) Jeremy M. Lenhardt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Power generation with laterally packaged piezoelectric fine wires

(2008) Rusen Yang et al.   Nature Nanotechnology