Article
Multidisciplinary Sciences
Valerio Di Lisio, Isabella Gallino, Sascha Sebastian Riegler, Maximilian Frey, Nico Neuber, Golden Kumar, Jan Schroers, Ralf Busch, Daniele Cangialosi
Summary: The glass transition temperature of metallic glasses can be depressed by up to 40 K by reducing the sample size to below 10 & mu;m, allowing the attainment of glasses with low energy states. The properties of bulk metallic glasses are profoundly affected by reducing the sample size. By systematically reducing the length scale of gold and platinum-based metallic glasses, the vitrification behavior and atomic mobility were studied, revealing size-dependent vitrification kinetics in micrometer-sized glasses.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Qi An, William L. Johnson, Konrad Samwer, Sydney L. Corona, Yidi Shen, William A. Goddard
Summary: The study reveals a similar L-G transition and heterogeneous G-phase in simulations of liquid Cu-Zr bulk glass, with the G-phase having icosahedrally ordered cores. The transition is associated with the emergence of elastic rigidity in metallic liquids, leading to a core-shell nano-composite structure likely formed to accommodate strain mismatch between stiff core regions and more compliant liquid-like medium.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Article
Chemistry, Physical
Y. S. Luo, J. J. Li, Z. Wang, M. Zhang, J. W. Qiao
Summary: Based on a simple mean-field model, two distinct types of slip avalanches in serrated plastic flows of bulk metallic glasses were identified to differentiate the slipping modes of shear bands under various strain rates. Small avalanches propagate progressively, while large avalanches follow a simultaneous propagation. By defining a weakening parameter and critical size, researchers were able to characterize the completely disparate shearing modes, with larger weakening and lower critical sizes indicating more activated shear transformation zones, offering a new method to explore plasticity in bulk metallic glasses.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Ceramics
H. Haouas, A. Khmich, A. Samiri, L. El Atouani, K. Sbiaai, A. Hasnaoui
Summary: Binary Re-W metallic glasses have shown promise in various applications due to their excellent mechanical properties, with molecular dynamics simulations revealing their intricate atomic structures. Increasing W content has been found to promote vitrification of the metallic glasses, while the determination of glass transition temperature T-g remains a key focus of research.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2021)
Article
Nanoscience & Nanotechnology
Chandra Sekhar Meduri, Jerzy Blawzdziewicz, Golden Kumar
Summary: With decreasing sample size and testing temperature, the fracture morphology of metallic glass specimens transitions from vein-pattern to completely smooth fracture surface to necking.
The size-temperature equivalence in the entire length scale can be described by considering the thermal effects in shear localization of metallic glasses.
Plastic deformation in nanoscale samples is spatially localized in embryonic shear bands, which do not mature to the propagation stage due to lack of heat content.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2021)
Article
Nanoscience & Nanotechnology
Chandra Sekhar Meduri, Jerzy Blawzdziewicz, Golden Kumar
Summary: The study revealed that the fracture morphology of metallic glass specimens changes with size and temperature, possibly due to thermal effects. An empirical model based on shear band heating and velocity formulations can qualitatively describe the effects of size and temperature on fracture morphology. Plastic deformation in nanoscale samples is spatially localized and does not progress to the propagation stage due to lack of heat content.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2021)
Article
Materials Science, Multidisciplinary
X. Yuan, D. Sopu, J. Eckert
Summary: The local stress state in metallic glasses can be modulated without affecting their structure, leading to enhanced ductility and strain hardening during loading. The stress heterogeneity in metallic glasses results in shear band multiplication, ultimately enhancing their macroscopic ductility. Additionally, residual compressive stress significantly increases the strength of the glass and contributes to observed strain hardening.
Article
Nanoscience & Nanotechnology
Jiacheng Zhang, Mao Zhang, Xinyun Wang, Mo Li
Summary: Making composites with crystalline inclusions can improve plasticity in brittle metallic glasses. In this study, a new metallic glass matrix composite with a gradient network architecture was demonstrated. The unique microstructure of the composite leads to significant strain delocalization, delaying the generation of catastrophic shear bands. This is achieved by forming diffuse embryonic shear bands in the thin crystalline network interface and hindering/guiding their formation and movement in thick crystalline network regions.
SCRIPTA MATERIALIA
(2023)
Article
Materials Science, Ceramics
Kuo-Hao Lee, Yongjian Yang, Linfeng Ding, Benedikt Ziebarth, Mark J. Davis, John C. Mauro
Summary: The addition of alkali ions lowers the yield stress and changes the pressure dependence of shear modulus in multicomponent borosilicate glasses. Shear-induced densification is observed in both glasses, with 5-coordinated Si being the dominant mechanism for densification at high pressures. Boron atoms tend to experience plastic deformation in Borofloat 33, while plastic deformation occurs around alkali-rich regions in N-BK7, indicating different atomic-scale deformation mechanisms in these two glasses.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2021)
Article
Materials Science, Multidisciplinary
Sree Harsha Nandam, Ruth Schwaiger, Aaron Kobler, Christian Kuebel, Chaomin Wang, Yulia Ivanisenko, Horst Hahn
Summary: By introducing nanoscale heterogeneities, including both crystalline and amorphous, significant improvements in plasticity of metallic glasses can be achieved. Nanoglass exhibits higher yield strength compared to conventional metallic glasses.
JOURNAL OF MATERIALS RESEARCH
(2021)
Article
Polymer Science
Peiru Liu, Yongfeng Men
Summary: Temperature-dependent form II to I transition was investigated in low-molar-mass polybutene-1 using fast scanning calorimetry. The crystals formed in the as-crystallized sample had wide distributions of lamellar thickness and intercrystalline link densities, with the well-crystallized form II crystals showing mobility of chain segments even below the glass transition temperature. The transition from form II to form I occurred over a wide temperature range, with form I crystals transformed below the glass transition temperature having higher melting points.
Article
Materials Science, Multidisciplinary
Solene Comby-Dassonneville, Gabrielle Tiphene, Alejandro Borroto, Gaylord Guillonneau, Lucian Roiban, Guillaume Kermouche, Jean-Francois Pierson, Jean-Luc Loubet, Philippe Steyer
Summary: This study reports the use of a new high-temperature scanning indentation technique to monitor the physical changes in thin-film metallic glasses in situ during heat treatment. The mechanical evolution and physical evolutions of ZrCu TFMG were successfully characterized, including the metallic glass-to-supercooled liquid transition and crystallization process. The HTSI results showed excellent agreement with other analytical methods and provided key kinetic information on small-scale systems.
APPLIED MATERIALS TODAY
(2021)
Article
Chemistry, Physical
A. Sharma, S. S. Hirmukhe, Sree Harsha Nandam, Horst Hahn, I. Singh, R. Lakshmi Narayan, K. Eswar Prasad
Summary: The strain rate sensitivity of a binary Cu60Zr40 nanoglass and metallic glass was studied using nanoindentation. The metallic glass exhibited noticeable displacement bursts at low loading rates, while the nanoglass showed a near homogeneous plastic flow. Both materials displayed a decrease in hardness with increasing loading rate, indicating negative strain rate sensitivity. The nanoglass had a higher strain rate sensitivity than the metallic glass.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Craig M. Tenney, Zachary F. Croft, Jeffrey M. McMahon
Summary: This study explores the possibility of liquid superconductivity in metallic hydrogen, investigating the critical temperature under different pressures and suggesting that the solid phase may melt into liquid phase at higher pressures. Results indicate that liquid atomic hydrogen may indeed exist in a superconducting state, providing the pressure and temperature conditions for further research.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Multidisciplinary Sciences
Minguk Jo, Ye-Won Seo, Hyojin Yoon, Yeon-Seo Nam, Si-Young Choi, Byung Joon Choi, Junwoo Son
Summary: Embedded metallic nanoparticles enhance the metastability and memory effects of metallic domains in VO2 switches. Control of percolative dynamics of metal and insulator domains during electrically triggered insulator-metal transition underlies applications in energy-efficient switches and non-Boolean computing.
NATURE COMMUNICATIONS
(2022)
Article
Materials Science, Multidisciplinary
Zida Zhang, Pengcheng Che, Jian Zhang, Hongbo Fan, Zhiliang Ning, Jianfei Sun, Yongjiang Huang
Summary: The effect of H+-ion irradiation on the structure and properties of a Cu50Zr50 metallic glass (MG) is investigated. The results show that the glass maintains its amorphous nature after ion irradiation, and the ion fluence increases shorten the atomic bond length, increase the nanohardness and Young's modulus, and enhance the corrosion resistance of the MG.
ADVANCED ENGINEERING MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Hangboce Yin, Jun-Qiang Wang, Yongjiang Huang, Hongxian Shen, Shu Guo, Hongbo Fan, Juntao Huo, Jianfei Sun
Summary: The new high-entropy metallic-glasses (HE-MGs) are designed using Dy and Ho instead of Gd in the Gd36Tb20Co20Al24 alloy based on the binary eutectic clusters method. The non-equiatomic RE36Tb20Co20Al24 (RE = Gd, Dy, or Ho) alloys show improved glass-forming ability compared to the equiatomic Gd25Tb25Co25Al25 alloy. The Ho36Tb20Co20Al24 alloy exhibits an extreme value of magnetic entropy change, indicating its potential for magnetocaloric applications.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Materials Science, Ceramics
Lu Li, Lina Hu, Lunyong Zhang, Yongjiang Huang, Kaikai Song, Hongxian Shen, Sida Jiang, Zheng Wang, Xi Zhao, Jianfei Sun
Summary: The research on liquid-liquid transition (LLT) has greatly enhanced the understanding of the liquid structure and evolution, with significant implications for glass formation. However, the impact of LLT on vitrification and glass structures is still unclear due to experimental challenges in exploring LLT in high-temperature melts. This study examines LLT in Zr-Cu-Ni-Al melts and reveals that superheated fragility is closely related to glass-forming ability. The competition between crystal-like and icosahedral-like clusters affects the crystallization behavior and changes in both medium-range order structure and short-range order structure indicate LLT.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2023)
Article
Mathematics, Applied
Usman Younas, Jingli Ren, Lanre Akinyemi, Hadi Rezazadeh
Summary: This research focuses on the nonlinear dynamics of DNA and obtains various nonlinear dynamical solitary wave structures using different integration methods. These findings are significant for a better understanding of the properties and behaviors of DNA.
MATHEMATICAL METHODS IN THE APPLIED SCIENCES
(2023)
Article
Multidisciplinary Sciences
Wencheng Hu, Jingli Ren, Yury Stepanyants
Summary: This article investigates the approximate, exact, and numerical solutions to the cylindrical Korteweg-de Vries equation. The existence of different types of solitary waves and their parameter dependence on distance are demonstrated. Additionally, the interaction between solitary waves of different types is studied.
Article
Materials Science, Multidisciplinary
Zhishuai Jin, Fuyang Cao, Guanyu Cao, Chaojun Zhang, Ziao Qiu, Lunyong Zhang, Hongxian Shen, Sida Jiang, Yongjiang Huang, Mingzhen Ma, Eckert Juergen, Jianfei Sun
Summary: This study investigates the solidification dynamics during casting of a Zr41.2-Ti13.8Cu12.5Ni10Be22.5 BMG by measuring temperature evolution and constructing distance-time curves. The results show that the casting temperature plays a crucial role in the cooling rate and the formation of nanocrystal phases in BMG components, emphasizing the importance of optimizing the casting temperature for fabrication of BMG components.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Engineering, Multidisciplinary
Lei Zhang, Shuang Su, Wujing Fu, Jianfei Sun, Zhiliang Ning, Alfonso H. W. Ngan, Yongjiang Huang
Summary: The structural evolution near the crystalline/matrix interface in CuZr-based metallic glass composite (MGC) was investigated using in situ transmission electron microscope (TEM) tensile straining and molecular dynamics (MD) simulation. Plastic deformation of the crystalline phase occurred before the amorphous phase, involving recoverable martensite transformation, dislocation accumulation at the interface, and local amorphization between grains. Fracture did not occur along the interphase interface, but within the crystalline phase near the interface, indicating a strong interface and high work hardening rate of the crystalline phase. MD simulations revealed that the amorphous phase was marginally metastable compared to the stable B2 phase, while the B19' martensitic phase was metastable with higher energy, explaining the easy mutual transformation between B2 and amorphous phase, and the less frequent transformation product of B19' phase from B2 during straining.
COMPOSITES PART B-ENGINEERING
(2023)
Article
Chemistry, Physical
Yaxin Gao, Xilei Bian, Xingbao Qiu, Yandong Jia, Jun Yi, Gang Wang
Summary: This study systematically investigated the effects of minor additions of Sb, In, Ni, and Bi on the microstructure, thermal and mechanical properties of Sn-1 wt.%Ag-0.5 wt.%Cu (SAC105) alloy. It was found that the addition of Sb, In, and Ni can refine the microstructure and distribute intermetallic compounds (IMCs) more evenly in the Sn matrix, leading to improved tensile strength through a combined strengthening mechanism. When Ni is substituted by Bi, the tensile strength is further enhanced with higher tensile ductility above 25%, while reducing the melting point, improving wettability, and enhancing creep resistance. The SAC105-2Sb-4.4In-0.3Bi alloy shows the optimized properties with the lowest melting point, the best wettability, and the highest creep resistance at room temperature, indicating the significant role of element alloying in improving the performance of SAC105 solders.
Article
Chemistry, Multidisciplinary
Yongyang Zhu, Shaoyang Shen, Xu-Sheng Yang, Liming Zeng, Gary Tsui, Zheng-Long Xu, Qing Zhou, Renheng Tang, K. C. Chan
Summary: This study proposes a cost-effective method to regenerate LiBH4 by ball milling hydrous lithium metaborate with low-cost Mg-based alloys. The introduction of light rare-earth metals into Mg improves the regeneration kinetics of LiBH4 by facilitating the breakage of B-O and conversion of H+ into H-. A yield of 40% can be achieved for LiBO2 center dot 2H(2)O-CeMg12 system with a relatively short ball milling duration of 10 hours. The optimized regeneration of LiBH4 is believed to be efficient and economical, utilizing an intrinsic hydrogen source in LiBO2 center dot 2H(2)O and cheap reducing agents. This finding is expected to promote the widespread use of LiBH4 for hydrogen storage.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Engineering, Multidisciplinary
Lei Zhang, Jianfei Sun, Alfonso H. W. Ngan, Zhiliang Ning, Hongbo Fan, Yongjiang Huang
Summary: Amorphous alloy composites (AACs) with reinforcing crystalline phases exhibit superior mechanical properties compared to their base amorphous alloy counterparts. A study on Cu-Zr based AACs reveals that the B2 phase particles embedded in the amorphous matrix are actually heterogeneous at the sub-micron scale, and the amorphous phase exhibits a gradient in free volume content towards the interface. This research provides valuable insights into the crystallization mechanism of the iso-stoichiometric B2 phase in Cu-Zr based AACs.
COMPOSITES PART B-ENGINEERING
(2023)
Article
Materials Science, Multidisciplinary
Guanying Wei, Jesper Byggmastar, Junzhi Cui, Kai Nordlund, Jingli Ren, Flyura Djurabekova
Summary: This study investigates the effect of lattice parameter difference and mass difference on primary radiation damage in W-Ta and W-Mo alloys through atomistic simulations. The results show that the available interatomic potential and Gaussian approximation potential yield different predictions, but the trend of alloy composition on surviving defects is similar in W-Mo alloys, while it differs significantly in W-Ta alloys.
JOURNAL OF NUCLEAR MATERIALS
(2023)
Article
Mathematics, Applied
Ying Xu, Jingli Ren, Xueping Li, Dandan Zhu
Summary: This paper focuses on the Schnakenberg model with crucial reversible reactions, under Neumann boundary conditions. The existence and uniqueness of strong solutions are proven based on semigroup theory. It is discovered that the proposed system has four possible positive constant steady states, and explicit conditions for stability, Turing instability, steady-state bifurcation, and Hopf bifurcation are determined. In addition, numerical simulations are conducted to demonstrate the theoretical results and depict the spatiotemporal patterns.
MATHEMATICAL METHODS IN THE APPLIED SCIENCES
(2023)
Article
Engineering, Environmental
Yongyang Zhu, Xubo Li, Xu-Sheng Yang, Pengyun Chen, Gary Chi-Pong Tsui, Zheng-Long Xu, Renheng Tang, Fangming Xiao, Kangcheung Chan
Summary: Researchers have developed a low-cost BCC solid solution alloy with excellent activation performance and high effective hydrogen desorption capacity by using a new compositionally complex doping strategy. The synergistic effect of Nb, Fe, Co, Ni, and Mn elements has been confirmed to improve hydrogen storage performance.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Thermodynamics
Chaojun Zhang, Lunyong Zhang, Fuyang Cao, Zhishuai Jin, Guanyu Cao, Ruishuai Gao, Ziao Qiu, Hongxian Shen, Yongjiang Huang, Jianfei Sun
Summary: This study proposes a full-scale coupling simulation model for understanding the melting process of metallic glass components during induction skull melting (ISM) using finite element method. Through experimental and numerical investigation, the distribution of physical fields and melt homogeneity in the melting process are analyzed.
INTERNATIONAL JOURNAL OF THERMAL SCIENCES
(2024)
Article
Mathematics, Applied
Qigang Yuan, Zhibo Cheng, Jingli Ren
Summary: This paper analyzes the pumping effect in a rigid 1 pipe-2 tanks flow configuration and studies the dynamic behaviors of the periodic solutions. A sufficient condition for the existence of harmonic solutions is established using topological degree theory. The stability of the solutions and the existence and stability of second-order subharmonic solutions are examined using regular perturbation and averaging methods. Numerical bifurcation analysis presents bifurcation diagrams of the periodic solutions.
JOURNAL OF MATHEMATICAL ANALYSIS AND APPLICATIONS
(2024)