Article
Chemistry, Multidisciplinary
Mengxia Qiu, Wanli Yang, Peiran Xu, Tiantian Huang, Xin Chen, Ning Dai
Summary: This study presents polymorphous VO2 thin films with coexistent VO2 (M) and VO2 (B) phases and phase-dependent insulator-metal transition (IMT) behaviors. The presence of VO2 (B) phases may induce lattice distortions in VO2 (M), resulting in widened plane spacing of (011)(M) in the VO2 (M) phase and shifted V-V and V-O vibrations. The coexisting VO2 (B) phases promote the IMT temperature of the polymorphous VO2 thin films.
Article
Materials Science, Multidisciplinary
Yongchang Ma, Rui Chen, Yajun Li, Cuimin Lu, Chenguang Zhang
Summary: We propose a model to estimate the energy barrier responsible for the hysteresis of the thermally driven Mott phase transition and validate the model with experimental data. For heating, the resistance in VO2 films exhibits step-like changes, forming multiple nonvolatile states, while no significant changes occur during cooling. The memory ability is attributed to the structure of the metal and insulator domains.
Article
Physics, Applied
Shingo Genchi, Mahito Yamamoto, Takuya Iwasaki, Shu Nakaharai, Kenji Watanabe, Takashi Taniguchi, Yutaka Wakayama, Hidekazu Tanaka
Summary: In this study, the relationship between the metallic domain size and the device-size-dependent MIT property of VO2 thin films grown on hBN was investigated. The results showed that VO2/hBN microwires exhibit multi-level step-like resistivity changes in the micrometer scale due to the confined metallic domains.
APPLIED PHYSICS LETTERS
(2022)
Article
Chemistry, Physical
Wenqiang Xiang, Boris Le Drogoff, Mohamed Chaker
Summary: Depositing high-quality VO2 thin films on a large area has been a challenge. This study presents an improved technique called sputtering oxidation coupling (SOC) using VN as intermediate material. VN films are first deposited on quartz by magnetron sputtering and then annealed in oxygen to obtain VO2 films with good performance in terms of transition properties. The proposed method is comparable to Pulsed Laser Deposition (PLD) in producing high-quality VO2 films.
APPLIED SURFACE SCIENCE
(2023)
Article
Materials Science, Coatings & Films
Chengyang Zhang, Ravindra Singh Bisht, Amin Nozariasbmarz, Arnob Saha, Chan Su Han, Qi Wang, Yifan Yuan, Abhronil Sengupta, Shashank Priya, Shriram Ramanathan
Summary: VO2 thin films were successfully grown on different substrates and their crystal structure and chemical composition were analyzed using X-ray diffraction and X-ray photoelectron spectroscopy. The films exhibited metal-insulator transition under temperature and electric field, which is of great importance for the application of phase transition devices.
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A
(2022)
Article
Chemistry, Multidisciplinary
Xitao Guo, Yonghao Tan, Yupei Hu, Zainab Zafar, Xin Liu, Lin Feng, Jijun Zou
Summary: VO2 thin films composed of irregularly shaped microplates have been successfully synthesized using V2O5 as a precursor via vapor transport technique. These films exhibit high crystal quality of monoclinic VO2 phase and show interesting phase transition behavior and infrared response.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Multidisciplinary Sciences
Xitao Guo, Yonghao Tan, Yupei Hu, Zainab Zafar, Jun Liu, Jijun Zou
Summary: The vapor transport method was used to synthesize high quality VO2 thin films on SiO2/Si substrate, exhibiting good near-infrared response and high stability. SEM and Raman spectroscopy were utilized to investigate the morphological and structural evolutions of intermediate phases during nucleation and growth processes, revealing a mechanism dominated by melting-evaporation-nucleation-growth.
SCIENTIFIC REPORTS
(2021)
Article
Engineering, Electrical & Electronic
Zhaorui Zou, Zhenhua Zhang, Jing Xu, Guoqiang Li, Rui Xiong, Yong Liu, Jing Shi
Summary: Investigated the thermochromic performance of Si-doped VO2 thin films, showing simultaneous control of transmittance in visible and near-infrared regions and superior thermochromic performance compared to undoped VO2 films. This study provides a novel method for tuning the optical and electrical characteristics of VO2 thin films.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Chemistry, Multidisciplinary
Jyrki Lappalainen, Matti Kangaspuoskari
Summary: The metal-insulator transition (MIT) of VO2 has attracted significant attention for its potential applications in nanostructured devices. The dynamics of the MIT phase transition play a crucial role in determining the feasibility of VO2 material properties in various applications. A new model is proposed to accurately predict the MIT effect in VO2 thin films by considering the interface structure and strain energy.
Article
Chemistry, Physical
Hyuk Jin Kim, Young Hwan Choi, Dongkyu Lee, In Hak Lee, Byoung Ki Choi, Soo-Hyon Phark, Young Jun Chang
Summary: Thermal stealth and camouflage have been extensively studied in order to blend objects with their surroundings against remote thermal image detection; Passive modulation of emissivity remains a great challenge requiring precise engineering over wide temperature range; The use of a vanadium dioxide layer with gradient tungsten concentration allows for self-adaptive thermal stealth without feedback control, improving passive camouflage materials.
APPLIED SURFACE SCIENCE
(2021)
Article
Physics, Applied
G. M. Hunt, J. A. Miragliotta, J. Ginn, A. P. Warren, D. B. Shrekenhamer
Summary: This article introduces a passive and adaptive thermal management system that utilizes the properties of VO2 material to provide insulation at low temperatures and heat dissipation at high temperatures, thereby reducing energy consumption. By doping VO2 with high valence tungsten, the transition temperature can be close to room temperature. By carefully engineering the thickness and doping of the VO2 layer in the multilayer film, a 50% emissive contrast was maintained across the 8-13 μm spectral region.
APPLIED PHYSICS LETTERS
(2023)
Article
Engineering, Electrical & Electronic
Mohammadreza Farjadian, Majid Shalchian
Summary: A comprehensive model is proposed for describing the insulator to metal phase transition in vanadium dioxide thin film under external electrical stimulus. By dividing the film layer into segments and solving relevant equations, the model successfully replicates experimental results, providing a useful tool for designing and analyzing vanadium dioxide structures with different electrode distances.
IEEE TRANSACTIONS ON ELECTRON DEVICES
(2021)
Article
Physics, Applied
Laura Diebold, Thomas Maroutian, Ludovic Largeau, Nicolas Guiblin, Romain Bude, Guy Garry, Olga M. Ishchenko, Pascal Aubert
Summary: This study compares the structural and RF properties of VO(2) thin films grown on c-cut and r-cut sapphire substrates. The results indicate that the films grown on r-cut sapphire have simpler structures and a narrower temperature range for the structural transition compared to those grown on c-cut sapphire. Although the structural differences have little influence on the dc resistivity, the transmission of RF signals through the metallic phase is found to be much lower on c-cut sapphire than on r-cut sapphire.
APPLIED PHYSICS LETTERS
(2023)
Article
Materials Science, Ceramics
Xuanchi Zhou, Yong Wu, Fengbo Yan, Tanzhao Zhang, Xinyou Ke, Kangkang Meng, Xiaoguang Xu, Zhipeng Li, Jun Miao, Jikun Chen, Yong Jiang
Summary: In this study, the sensitivity of vanadium charge and MIT properties of VO2 thin films to deposition temperature were demonstrated, highlighting the need to eliminate temperature distribution inhomogeneity during the deposition process. Additionally, high thermoelectric power factor in the metallic phase of VO2 thin films was achieved, enriching the potential functionality in thermoelectric energy conversions beyond current electronic applications.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Jingxin Sang, Tan Zheng, Liu Xu, Xin Zhou, Shijian Tian, Jiatong Sun, Xiaofeng Xu, Jianqiang Wang, Shuguang Zhao, Yang Liu
Summary: This study discusses the effects of surface topology change on metal-insulator transition behaviors of VO2/Al2O3 thin films prepared by DC sputtering. It is found that grain size and lattice strain play significant roles in improving the metal-insulator transition, with increasing crystalline size enhancing sheet conductivity and lattice strain modulating T-MIT.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Electrical & Electronic
Zheng Yang, Shriram Ramanathan
IEEE PHOTONICS JOURNAL
(2015)
Article
Nanoscience & Nanotechnology
Zhizhong Chen, Yiping Wang, Yuhan Shi, Bo Hsu, Zheng Yang, Jian Shi
ADVANCED ELECTRONIC MATERIALS
(2016)
Article
Chemistry, Multidisciplinary
Ziao Tian, Borui Xu, Bo Hsu, Liliana Stan, Zheng Yang, Yongfeng Mei
Article
Nanoscience & Nanotechnology
Changhyun Ko, Zheng Yang, Shriram Ramanathan
ACS APPLIED MATERIALS & INTERFACES
(2011)
Review
Materials Science, Multidisciplinary
Zheng Yang, Changhyun Ko, Shriram Ramanathan
ANNUAL REVIEW OF MATERIALS RESEARCH, VOL 41
(2011)
Article
Materials Science, Multidisciplinary
Zheng Yang
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
(2013)
Article
Physics, Applied
Zheng Yang, Shriram Ramanathan
APPLIED PHYSICS LETTERS
(2011)
Article
Physics, Applied
Mikhail A. Kats, Deepika Sharma, Jiao Lin, Patrice Genevet, Romain Blanchard, Zheng Yang, M. Mumtaz Qazilbash, D. N. Basov, Shriram Ramanathan, Federico Capasso
APPLIED PHYSICS LETTERS
(2012)
Article
Engineering, Electrical & Electronic
You Zhou, Zheng Yang, Shriram Ramanathan
IEEE ELECTRON DEVICE LETTERS
(2012)
Article
Engineering, Electrical & Electronic
You Zhou, Xiaonan Chen, Changhyun Ko, Zheng Yang, Chandra Mouli, Shriram Ramanathan
IEEE ELECTRON DEVICE LETTERS
(2013)
Article
Physics, Applied
Zheng Yang, You Zhou, Shriram Ramanathan
JOURNAL OF APPLIED PHYSICS
(2012)
Article
Crystallography
Z. Yang, Z. Zuo, H. M. Zhou, W. P. Beyermann, J. L. Liu
JOURNAL OF CRYSTAL GROWTH
(2011)
Article
Optics
Mikhail A. Kats, Romain Blanchard, Patrice Genevet, Zheng Yang, M. Mumtaz Qazilbash, D. N. Basov, Shriram Ramanathan, Federico Capasso
Article
Chemistry, Physical
Adita Das, Bo Hsu, Armen Shamirian, Zheng Yang, Preston T. Snee
CHEMISTRY OF MATERIALS
(2017)
Article
Nanoscience & Nanotechnology
Wei Zhang, Joseph Sklenar, Bo Hsu, Wanjun Jiang, Matthias B. Jungfleisch, Jiao Xiao, Frank Y. Fradin, Yaohua Liu, John E. Pearson, John B. Ketterson, Zheng Yang, Axel Hoffmann