Article
Energy & Fuels
Lianyang Zhang, Yue Meng, Jianming Yang, Hui Shen, Chunfang Yang, Bo Xie, Shengjie Xia
Summary: The dry reforming of methane reaction on Cu12M (M = Cu, Fe, Co, Ni) core-shell bimetallic nanoclusters was studied by density functional theory (DFT) in this paper. The results show that Cu12Ni is the most potential DRM catalyst due to the highest electronic activity.
Article
Energy & Fuels
Maryam Ostadebrahim, Omran Moradlou
Summary: A comparative study was conducted on the effect of transition metal cations in LaMO3 perovskite-type structures on their electrochemical hydrogen sorption/storage process. LaFeO3 nanoparticles showed the highest discharge capacity of 13,500 mAh/g due to their higher surface reactivity and faster electron transfer. The electrode demonstrated superior cycling stability and could be a potential candidate for battery applications.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Materials Science, Multidisciplinary
Lei Wang, Reza Darvishi Kamachali
Summary: This research utilized a density-based model to calculate multi-component grain boundary phase diagrams and studied the Fe-Mn-Cr, Fe-Mn-Ni, Fe-Mn-Co, Fe-Cr-Ni, and Fe-Cr-Co alloy systems. The study found that despite solute segregation enrichment, a grain boundary may have a lower solubility limit than the bulk, promoting interfacial chemical decomposition.
Article
Chemistry, Physical
D. Mejia-Burgos, S. A. Berrios, J. Mazo-Zuluaga, J. Mejia-Lopez
Summary: In this study, an extensive molecular dynamics investigation was conducted on the thermomechanical properties of cylindrical Fe, Ni, and Fe/Ni core/shell nanowires under uniaxial tensile strain. The nanowires were found to be elastically softer than bulk iron, with a weakening effect observed as sample diameter increased. Additionally, shape memory effect was observed in Fe/Ni core/shell systems grown along specific crystal directions, making them potentially attractive for technical applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Minglei Yan, Zhiyang Zhao, Peixin Cui, Kun Mao, Chi Chen, Xizhang Wang, Qiang Wu, Hui Yang, Lijun Yang, Zheng Hu
Summary: In this study, a porous core-shell heterojunction NiFe sulfide catalyst was demonstrated for efficient water electrolysis, showing excellent performance with low overpotential, small Tafel slope, and high durability. The construction of advanced earth-abundant OER electrocatalysts through heterojunctions between metal and corresponding metal-compounds via post treatments provides an effective way for further exploration in this field.
Article
Nanoscience & Nanotechnology
Geng Liu, Jie Su, Ao Wang, Zhuoyue Yang, Yali Ding, Jing Ning, Qi Gao
Summary: Metastable austenite is crucial for improving the cryogenic impact toughness of maraging steels, although a large volume fraction results in decreased yield strength. To address the strength-toughness trade-off in maraging steels, a core-shell structure with specific composition and volume fraction of austenite is designed. The core region contains retained austenite, while the shell region consists of reverted austenite with high Ni content. The results show that the thin austenite shell layers contribute to the impact toughness and, combined with nanoprecipitates, the alloy exhibits high yield strength and good cryogenic impact toughness.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2023)
Article
Chemistry, Physical
Mingxuan Fu, Guyang Ning, Jiaxian Liu, Qi Zhang, Yuena Sun, Xinyu Fan, Haiyang Wang, Haijun Lu, Yufan Zhang, Huan Wang
Summary: The study focused on developing high-activity and durable dual-functional electrocatalysts for hydrogen and oxygen evolution reactions. By preparing core-shell structured nanocubes, the catalyst showed enhanced catalytic activity and stability.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Aya Fathy, Ashour M. Ahmed, Mohamed A. Ghanem, Hany Hamdy, Mohamed Shaban, Khaled M. H. Mohammed, Mohamed Rabia
Summary: Poly(m-toluidine) (PmT) is used as a high-performance electrode material in a supercapacitor with a PmT/(Co-Ni) core/shell composite as the electrode. The Co-Ni nanoneedles are prepared via a hydrothermal process and PmT nanoplatelets are grown on them through in-situ oxidation polymerization. The PmT/(Co-Ni) electrode exhibits a high specific capacitance of 308F/g at a current density of 0.6 A/g, as well as good stability with 98% retention of its initial capacitance after thousand cycles. The unique nanoplatelets/nanoneedles architecture and conductive PmT polymer contribute to the excellent electrochemical performance of the electrode.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Engineering, Environmental
Thanh Hai Nguyen, Phan Khanh Linh Tran, Duy Thanh Tran, Thanh Ngoc Pham, Nam Hoon Kim, Joong Hee Lee
Summary: We propose a novel catalyst that meets the reaction kinetics demands of metal-air battery and demonstrates excellent performance in both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). By enhancing the synergistic effects of OER and ORR, we have successfully developed high-performance zinc-air and aluminum-air batteries with exceptional cell voltage, power density, and durability, surpassing most existing materials.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Mechanics
A. El Ghazrani, K. Htoutou, S. Harir, L. B. Drissi
Summary: By performing atomistic simulations using the Monte Carlo method, we studied the behavior of the classical Heisenberg model. First, we investigated the magnetic and thermal properties of a core-shell nanosphere model and analyzed the temperature-dependent magnetization, magnetic susceptibility, and phase diagrams for different exchange interactions. The results revealed diverse behaviors in the Neel classification nomenclature. Furthermore, we applied the same method to study the (Fe, Ni) nanostructure using experimental magnetic parameters, and observed a compensation phenomenon consistent with experimental studies.
JOURNAL OF STATISTICAL MECHANICS-THEORY AND EXPERIMENT
(2023)
Article
Engineering, Mechanical
Le Li, Zhenghao Chen, Koretaka Yuge, Kyosuke Kishida, Haruyuki Inui, Martin Heilmaier, Easo P. George
Summary: The plastic deformation behavior of equiatomic Cr-Fe-Co-Ni medium-entropy alloy was investigated through compression and tension experiments. The critical resolved shear stress (CRSS) for {111}<1((1)over bar)0> slip was found to be 44-45 MPa at room temperature without significant tension-compression asymmetry. The CRSS increased rapidly with decreasing temperature, but the temperature dependence dulled below 77 K due to the inertia effect. The 0 K CRSS was determined to be 200 MPa, higher than Cr-Mn-Fe-Co-Ni high-entropy alloy but lower than Cr-Co-Ni medium-entropy alloy.
INTERNATIONAL JOURNAL OF PLASTICITY
(2023)
Article
Engineering, Environmental
Kobra Pourabdollah
Summary: Core-shell microspheres of graphitized carbon are produced in ultra-high temperature ethane steam crackers, surrounded by a porous CrNi-Fe shell. A study was conducted on the environmental remediation process for extraction of coke microspheres, investigating the effect of dissolved ions on zeta potential and electrical double layer compression, as well as the role of polymer bridging mechanism.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Guohui Wang, Dong-Sang Kim, Matthew J. Olszta, Mark E. Bowden, Daniel K. Schreiber, Sarah A. Saslow, Wooyong Um, Brian J. Riley, Jing Wang, Albert A. Kruger
Summary: This study demonstrates that Ni doping during the transformation of Fe(OH)(2)(s) into iron spinel can enhance the sequestration of Tc in aqueous solutions, resulting in the formation of metallic Tc and achieving nearly complete Tc removal.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Chemistry, Physical
Bo Jiang, Zhe Wan, Yunqing Kang, Yanna Guo, Joel Henzie, Jongbeom Na, Hexing Li, Shengyao Wang, Yoshio Bando, Yoshio Sakka, Yusuke Yamauchi
Summary: Researchers have developed a new type of porous metallic aerogels with a core-shell structure, exhibiting high conductivity and surface area for catalysis. By utilizing an auto-programmed synthesis method, they successfully generated a trimetallic core-shell Cu@Fe@Ni metallic aerogel with highly active catalytic properties.
Article
Chemistry, Inorganic & Nuclear
Yang Dingfeng, Tang Yurou, Yang Hengquan, Li Wensheng, Zhang Bin, Yao Wei, Wang Guoyu, Zhou Xiaoyuan
Summary: This study reports the optimization of thermoelectric performance in CoSbS compound by tuning the distortion of Co octahedra. The substitution of M elements on Co sites remarkably reduces the lattice thermal conductivity, with Cr substitution showing the strongest effect. Furthermore, the contribution of Ni-3d orbitals increases the carrier concentration and power factor. The maximum zT value of 0.52 was achieved in the Ni0.10Co0.90SbS0.85Se0.15 sample, demonstrating the improved thermoelectric performance.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Nanoscience & Nanotechnology
Haodong Liu, Danna Qian, Michael G. Verde, Minghao Zhang, Loic Baggetto, Ke An, Yan Chen, Kyler J. Carroll, Derek Lau, Miaofang Chi, Gabriel M. Veith, Ying Shirley Meng
ACS APPLIED MATERIALS & INTERFACES
(2015)
Article
Physics, Applied
Ahmed A. El-Gendy, Massimo Bertino, Dustin Clifford, Meichun Qian, Shiv N. Khanna, Everett E. Carpenter
APPLIED PHYSICS LETTERS
(2015)
Article
Materials Science, Multidisciplinary
Dustin M. Clifford, Carlos E. Castano, Amos J. Lu, Everett E. Carpenter
JOURNAL OF MATERIALS CHEMISTRY C
(2015)
Article
Chemistry, Multidisciplinary
Kyler J. Carroll, Thomas Burger, Lukas Langenegger, Steven Chavez, Sean T. Hunt, Yuriy Roman-Leshkov, Fikile R. Brushett
Article
Physics, Applied
Brent Williams, Dustin Clifford, Ahmed A. El-Gendy, Everett E. Carpenter
JOURNAL OF APPLIED PHYSICS
(2016)
Article
Nanoscience & Nanotechnology
Mai Abdeen, Soraya Sabry, Hanan Ghozlan, Ahmed A. El-Gendy, Everett E. Carpenter
JOURNAL OF NANOMATERIALS
(2016)
Article
Chemistry, Multidisciplinary
Sarah E. Smith, Ali R. Siamaki, B. Frank Gupton, Everett E. Carpenter
Article
Materials Science, Multidisciplinary
Brent Williams, Ahmed A. El-Gendy, Everett E. Carpenter
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2017)
Article
Nanoscience & Nanotechnology
Tasneem Salih, Steven M. Brown, Chaerin Kim, Kyler J. Carroll, Fikile R. Brushett, Ali Bumajdad
SCIENCE OF ADVANCED MATERIALS
(2017)
Article
Chemistry, Multidisciplinary
Sarah E. Smith, Zachary J. Huba, Fahad Almalki, J. R. Regalbuto, John Monnier, Everett E. Carpenter
JOURNAL OF FLOW CHEMISTRY
(2017)
Article
Nanoscience & Nanotechnology
C. S. M. Hunt, R. Barua, E. E. Carpenter
Article
Biochemistry & Molecular Biology
Thi Kim Hoang Trinh, Weihua Qiu, Meg Thornton, Everett E. Carpenter, Youzhong Guo
Summary: A novel CHOL alternative called CHEAPS has been developed for studying membrane proteins, which can be easily solubilized in detergents and membrane-active polymers. It has potential applications in MP structural biology.
BIOCHIMICA ET BIOPHYSICA ACTA-GENERAL SUBJECTS
(2021)
Article
Chemistry, Physical
Vaibhav Sharma, Lilly Balderson, Rachel Heo, Omar Bishop, Caitlin S. M. Hunt, Everett E. Carpenter, Ravi L. Hadimani, Hong Zhao, Radhika Barua
Summary: This study develops a novel additive manufacturing method to 3D print microchanneled magnetocaloric structures, addressing the challenge in manufacturing magnetic refrigeration devices. By adding magnetocaloric powders, a polymer binder, and solvents in the printing ink, a stable printing process is achieved. The results indicate that the 3D printed samples have comparable performance to the precursor powders.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Meeting Abstract
Chemistry, Multidisciplinary
Brent Williams, Melissa Tsui, Everett Carpenter
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2018)
Article
Chemistry, Inorganic & Nuclear
Dustin M. Clifford, Carlos E. Castano, Melissa H. M. Tsui, Jessika V. Rojas, Everett E. Carpenter
DALTON TRANSACTIONS
(2017)