Nitrogenous emissions from the catalytic pyrolysis of waste rigid polyurethane foam

In this paper, we focus on the release of nitrogenous species from waste rigid polyurethane foam (WRPUF) during thermal conversion. Pyrolysis of WRPUF was experimentally studied to determine the effects of four operational parameters, temperature, particle size, sweeping gas flow rate and catalyst supplied, on the partitioning of the fuel nitrogen among nitrogen species. Experiments were performed using a bench-scale fixed-bed reactor and the important findings of this research include the following. (1) Five nitrogen-containing species, N-2, NH3, HCN, NO2 and NO, were found in gas-phase product and N-2 is dominant. (2) Tar N is retained as heterocyclic compounds, nitrile, or amine functional groups bonded to aromatic rings, and 4-[(4-aminophenyl)methyljaniline is the main nitrogen-containing compound. (3) CaO has a good performance on increasing N-2 production and decreasing NOx precursors. (4) The sweeping gas (Ar) flow rate and catalyst supplied were the most important parameters on affecting the N-containing species release. Whatever gaseous nitrogen, tar N or char N, they were significantly affected by sweeping gas flow rate, catalyst supplied or their interaction. (C) 2014 Elsevier B.V. All rights reserved.