Article
Chemistry, Physical
S. A. Uporov, R. E. Ryltsev, V. A. Bykov, N. S. Uporova, S. Kh Estemirova, N. M. Chtchelkatchev
Summary: Magnetic cooling is a promising eco-friendly technology that requires the search for novel functional materials. Gd-based metallic glasses show potential as solid-state refrigerants, but their magnetic properties can be improved. Through element substitution in the alloy components, it is possible to enhance glass-forming ability and overall performance of the materials.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Multidisciplinary
Guannan Liu, Sungwoo Sohn, Sebastian A. Kube, Arindam Raj, Andrew Mertz, Aya Nawano, Anna Gilbert, Mark D. Shattuck, Corey S. O'Hern, Jan Schroers
Summary: Machine learning shows potential in addressing complex materials science problems, but physical insights are necessary to develop accurate and predictable models.
Article
Materials Science, Ceramics
Wenfei Lu, Jo-Chi Tseng, Aihan Feng, Jun Shen
Summary: The study aimed to clarify the structural origin of the enhancement in glass-forming ability of binary NiNb metallic glasses. Ni62.5Nb37.5 alloy exhibited the best glass-forming ability and the densest atomic-packing structure among the four components, with a larger fraction of full icosahedral clusters. The glass structure in Ni62.5Nb37.5 MG was a heterogeneous mixture of interpenetrating icosahedral clusters, forming a chain-like network structure in the matrix. These Ni-centered icosahedra polyhedra played an essential role in controlling GFA.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2021)
Article
Materials Science, Multidisciplinary
S. J. Wu, Z. Q. Liu, R. T. Qu, Z. F. Zhang
Summary: By establishing quantitative correlations among compositions, elastic constants, GFA, and mechanical properties of metallic glasses (MGs), it is possible to predict their performance in advance. Experimental data confirms the validity of this predictive approach. A strategy for designing MGs with optimal combinations of strength, toughness, and GFA is proposed to allow for high-throughput discovery of glass formers with excellent mechanical properties.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Materials Science, Multidisciplinary
Yimeng Zhao, Xuan Li, Xiaobin Liu, Jiazi Bi, Yang Wu, Ruijuan Xiao, Ran Li, Tao Zhang
Summary: The development of Co-Ta-B-Si bulk metallic glasses with high glass-transition temperature, large compressive plasticity, high strength, and high glass-forming ability was achieved by accurately tuning the metalloid element contents of Si and B in the parental alloy. The improvement in plastic deformation was attributed to the self-organization behaviors of high-density shear bands.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Physical
Jaskaran Singh Saini, John P. Miska, Fuqiong Lei, Nicholas AuYeung, Donghua Xu
Summary: Metallic glasses, especially Hafnium based MGs, have superior properties to conventional crystalline metals/alloys, with HBMGs having the additional advantage of high density. However, their glass-forming ability is limited. Our discovery of two HBMGs with a critical casting diameter significantly higher than the current record allows for the production of bigger products and easier manufacturing/processing.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Y. X. Zhang, G. C. Xing, Z. D. Sha, L. H. Poh
Summary: A new two-step fused machine learning approach is proposed to accurately predict metallic glasses with robust glass-forming ability. Utilizing alloy compositions as the only input, the method integrates data of both castable and non-castable alloys to achieve good prediction results.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Multidisciplinary
Lukasz Szczepanski, Markus Bambach, Felix Jensch, Andrzej Ambroziak, Tomasz Kurzynowski
Summary: In recent years, Fe-based metallic glasses have been extensively researched for their favorable mechanical and magnetic properties. Breakthroughs have been made in producing these materials in Laser Powder Bed Fusion technology, allowing the production of elements of any shape. The microstructure of the manufactured parts plays a crucial role in determining their properties.
MATERIALS & DESIGN
(2021)
Article
Materials Science, Ceramics
Aytekin Hitit, Ziya Ozgur Yazici, Pelin Ozturk, Bugrahan Eryesil, Nusrettin Barut, Hakan Sahin
Summary: The addition of tantalum up to 8 at.% increases the glass forming ability (GFA). The alloy with 8 at.% Ta has the highest GFA and its critical thickness is 1.5 mm. Thermal and mechanical properties of the alloys improve with tantalum additions.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2021)
Article
Chemistry, Physical
Shan Zhang, Chao Wei, Zhilin Shi, Haoran Zhang, Mingzhen Ma
Summary: Fe doping significantly improves the glass-forming ability, stability, and mechanical properties of Zr50Cu34-xFexAl8Ag8 metallic glasses. The addition of Fe inhibits the formation of crystalline phases, increases the glass-forming ability, and enhances the fracture strength and ultimate strain of the metallic glass samples.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Materials Science, Ceramics
Ting Zhang, Zhilin Long, Li Peng, Zhuang Li
Summary: In this paper, a convolutional neural network (CNN) model was used to investigate the glass forming ability (GFA) of bulk metallic glasses (BMGs). By training and testing with a large number of alloy compositions, the study shows that machine learning methods have great potential in guiding the design of new BMG materials.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2022)
Article
Materials Science, Multidisciplinary
Jie Xiong, San-Qiang Shi, Tong-Yi Zhang
Summary: This study successfully classified and predicted different levels of GFA in BMG materials using feature selection and machine learning algorithms, providing guidance for novel material design.
COMPUTATIONAL MATERIALS SCIENCE
(2021)
Article
Materials Science, Ceramics
Y. Tan, Y. W. Wang, X. W. Cheng, Q. Fu, Z. H. Xin, Z. Q. Xu, H. W. Cheng
Summary: The study found that appropriate Al substitution can improve the glass-forming ability, strength, and plasticity of amorphous alloys, but fracture strength decreases and no dynamic compression plasticity is observed during dynamic loading.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2021)
Article
Thermodynamics
A. S. Farid
Summary: Various glass stability criteria were presented in this work for the Se85Te15-xSbx (x = 2, 4, and 6 at. %) ternary alloy glassy system. These criteria were obtained by examining the interrelationship between typical temperatures using non-isothermal differential scanning calorimetry measurements. The K-GL criterion was found to be ineffective for discussing glass stability for the compositions studied due to its dependence on heating rate and composition. The results from various criteria indicate that Yuan et al.'s K-YL criterion is the best for assessing glass stability, and increasing the Sb content improves thermal stability.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2023)
Article
Materials Science, Multidisciplinary
Yicheng Wu, Bin Xu, Xuefeng Zhang, Pengfei Guan
Summary: Significant progress has been made in predicting the local structural instability of various disordered systems through supervised machine learning (ML) models. However, the generalization and interpretability of these models need to be addressed. By analyzing the weighting function of the ML prediction models and the radial distribution function (RDF) of the predicted system, a density-fluctuation model with good generalization ability is proposed based on static structure information. This model provides a more reliable prediction of structural instability for different systems.
Article
Chemistry, Physical
Zhiguang Shi, Ran Li, Tao Zhang
JOURNAL OF ALLOYS AND COMPOUNDS
(2019)
Article
Chemistry, Physical
Si-Xu Peng, Cheng Zhang, Chong Yang, Ran Li, Tao Zhang, Lin Liu, Hai-Bin Yu, Konrad Samwer
JOURNAL OF CHEMICAL PHYSICS
(2019)
Article
Chemistry, Physical
Yu Jin, Guoguo Xi, Ran Li, Zi-An Li, Xiao-Bo Chen, Tao Zhang
Summary: The high anode overpotential of the oxygen evolution reaction (OER) in water electrolysis has been successfully addressed through the design and preparation of a group of nanoporous (Fe-Ni-Co)-based metallic glasses (NP-FeNiCo-MGs). The composite electrodes exhibit high catalytic activity towards water oxidation in 1 M KOH solutions, showing great potential for clean energy applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Xiaobin Liu, Jiazi Bi, Ziyang Meng, Yubin Ke, Ran Li, Tao Zhang
Summary: This study focused on inhibiting the generation of microcracks in Co-based metallic glass amorphous coatings by increasing substrate temperature and adding toughened Fe powders, as well as investigating the neutron shielding performance of coatings with high B content. The results showed that these methods effectively suppressed the initiation and propagation of microcracks, while high B content coatings exhibited excellent neutron shielding performance.
Article
Chemistry, Physical
Ju Wang, Ivan Kaban, Volodymyr Levytskyi, Ran Li, Junhee Han, Mihai Stoica, Roman Gumeniuk, Kornelius Nielsch
Summary: Co-Ta-B bulk metallic glasses exhibit a good combination of ultra-high fracture strength, Vickers hardness, and plastic strain. The crystallization process reveals the formation of a novel crystalline phase upon glass annealing.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Multidisciplinary
Xiangguang Kong, Ying Yang, Shiyu Guo, Ran Li, Bo Feng, Daqiang Jiang, Meng Li, Changfeng Chen, Lishan Cui, Shijie Hao
Summary: By controlling the grain-size gradient, a novel shape memory behavior can be achieved in NiTi alloys, and the activating performance can be customized by controlling the pre-deformation strain to regulate the shape transition amplitude and speed.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Materials Science, Multidisciplinary
Guoguo Xi, Lei Zuo, Xuan Li, Yu Jin, Ran Li, Tao Zhang
Summary: A Ru-doped NiFe-based catalyst with a three-dimensional nanoporous surface was developed, meeting both performance and cost requirements for oxygen evolution reaction (OER) electrocatalysis. The novel material exhibited excellent OER performance due to its Ru-rich nanoporous architecture, multiple metal (hydro)oxides generated on the surface, and easy electron transfer facilitated by the firm bonding of nanoporous layer and the substrate.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Materials Science, Multidisciplinary
Yimeng Zhao, Xuan Li, Xiaobin Liu, Jiazi Bi, Yang Wu, Ruijuan Xiao, Ran Li, Tao Zhang
Summary: The development of Co-Ta-B-Si bulk metallic glasses with high glass-transition temperature, large compressive plasticity, high strength, and high glass-forming ability was achieved by accurately tuning the metalloid element contents of Si and B in the parental alloy. The improvement in plastic deformation was attributed to the self-organization behaviors of high-density shear bands.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Nanoscience & Nanotechnology
Mengmeng Meng, Ran Li, Lei Zuo, Xuekun Luo, Tao Zhang
Summary: Novel hierarchical porous metallic glasses decorated with Cu nanoparticles were synthesized using a one-pot pulse anodization method. The integrated electrode showed outstanding performance in non-enzymatic glucose catalysis, with high sensitivity and stability, making it suitable for practical applications.
SCRIPTA MATERIALIA
(2021)
Article
Engineering, Mechanical
Xiaobin Liu, Jiazi Bi, Ziyang Meng, Ran Li, Yan Li, Tao Zhang
Summary: In this study, a Co-based amorphous powder with high glass-forming ability was prepared by gas-atomization and used to fabricate a large-area amorphous coating through laser cladding. The effect of different laser parameters on the glass formation of the coating was investigated, and the resulting coating exhibited extremely high microhardness and wear resistance. Clarification of the wear-failure mechanism of the Co-based coating was achieved through microstructural and element-distribution analysis of various worn surfaces.
TRIBOLOGY INTERNATIONAL
(2021)
Article
Nanoscience & Nanotechnology
Jiazi Bi, Xinquan Wei, Xiaobin Liu, Ran Li, Ruijuan Xiao, Tao Zhang
Summary: A family of novel Os-Co-Ta-B high-temperature bulk metallic glasses (HTBMGs) with high glass transition temperature, Vickers microhardness, and compressive strength was fabricated by introducing high-modulus refractory metal Os and strong-covalent metalloid B. The impressive strength is attributed to the strong bond characteristics especially for Ta-Os and B-B bonds. The castable OsCo-based HTBMGs with superior mechanical properties and high thermal stabilities are significant for high-temperature applications as advanced structural materials.
SCRIPTA MATERIALIA
(2023)
Article
Chemistry, Physical
Chenlang Xie, Kaiyang Deng, Junfei Teng, Junying Fu, Ran Li, Tao Zhang
Summary: A family of novel Ni-based amorphous alloys with high W concentration was developed, and their crystallization and melting behaviors were evaluated. An optimal composition of Ni75W5B20 alloy, with high W concentration and near-eutectic melting behavior, was selected for brazing joint of GH3230 alloy. The effects of brazing temperature on microstructural evolution and mechanical properties of the joints were studied. The results showed that under the optimal brazing conditions, a homogeneous brazed seam with high tensile strength and dispersed Cr-rich borides can be obtained.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Metallurgy & Metallurgical Engineering
Bi Jiazi, Liu Xiaobin, Li Ran, Zhang Tao
Summary: Friction and wear in mechanical systems lead to energy loss and machine failure. Lubricants with additives, including nanoparticles and metallic glasses, are used to reduce friction and wear. While nanoparticles and metallic glasses show promise as lubricant additives, challenges such as aggregation in solutions and complex preparation processes limit their large-scale applications.
ACTA METALLURGICA SINICA
(2021)
Article
Materials Science, Multidisciplinary
Xuekun Luo, Mengmeng Meng, Ran Li, Zian Li, Ivan S. Cole, Xiao-Bo Chen, Tao Zhang
MATERIALS & DESIGN
(2020)
Article
Materials Science, Biomaterials
Xiao Wang, Ran Li, Zian Li, Ruijuan Xiao, Xiao-Bo Chen, Tao Zhang
JOURNAL OF MATERIALS CHEMISTRY B
(2019)
Article
Chemistry, Physical
J. Zamora, T. Bautista, N. S. Portillo-Velez, A. Reyes-Montero, H. Pfeiffer, F. Sanchez-Ochoa, H. A. Lara-Garcia
Summary: Experimental and DFT studies were conducted on the structural, magnetic, and optical properties of RFeO3 perovskites. The perovskites exhibited an orthorhombic crystal structure and weak ferromagnetic behavior. They were confirmed to be semiconductors with a bandgap of approximately 2.1 eV.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xianxiang Lv, Jing Jin, Weiguang Yang
Summary: By depositing TiN and TiO2 surface layers on AlSi films, the electrochemical performance of silicon-based anodes can be significantly improved, suppressing volume expansion and promoting the formation of a stable SEI layer.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Sharafat Ali, Haider Ali, Syedul Hasnain Bakhtiar, Sajjad Ali, Muhammad Zahid, Ahmed Ismail, Pir Muhammad Ismail, Amir Zada, Imran Khan, Huahai Shen, Rizwan Ullah, Habib Khan, Mohamed Bououdina, Xiaoqiang Wu, Fazal Raziq, Liang Qiao
Summary: The construction and optimization of redox-heterojunctions using a bifunctional phosphate as an electron-bridge demonstrated significant improvements in photo catalytic activity, including enhanced dispersion, reduced interfacial migration resistance, and increased abundance of active-sites.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ren-Ni Luan, Na Xu, Chao-Ran Li, Zhi-Jie Zhang, Yu-Sheng Zhang, Jun Nan, Shu-Tao Wang, Yong-Ming Chai, Bin Dong
Summary: Extensive research has revealed that oxygen evolution reaction (OER) in alkaline conditions involves dynamic surface restructuring. The development and design of sulfide/oxide pre-catalysts can reasonably adjust the composition and structure after surface reconstruction, which is crucial for OER. This study utilized a simple two-step hydrothermal method to achieve in situ S leaching and doping, inducing the composition change and structure reconstruction of CoFe oxides. The transformed FeOOH and CoOOH exhibited excellent OER activity and could be easily mass-produced using low-cost iron based materials and simple methods.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jun'an Lai, Daofu Wu, Peng He, Kang An, Yijia Wang, Peng Feng, WeiWei Chen, Zixian Wang, Linfeng Guo, Xiaosheng Tang
Summary: Zero-dimensional organic-inorganic metal halides (OMHs) are gaining attention in the fabrication of light-emitting diodes due to their broad emission band and high photoluminescence quantum yield. This work synthesized a zero-dimensional organic tetraphenylphosphonium bismuth chloride (TBC) that showed efficient blue light emission, with the emission mechanism attributed to the transition of Bi3+ ions. White light-emitting diodes (WLEDs) were fabricated using TBC, along with green-emitting and red-emitting single crystals, achieving single-component white emissions. These findings demonstrate the different emission mechanism of ns2 ions-based OMHs and highlight the potential of bismuth-based OMHs in WLEDs applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xuewei Liang, Yunhai Su, Taisen Yang, Zhiyong Dai, Yingdi Wang, Xingping Yong
Summary: The revolutionary design concept of high-entropy alloys has brought new opportunities and challenges to the development of advanced metal materials. In this work, AlCrCuFe2NiTix high-entropy flux cored wires were prepared by combining the design idea of a high-entropy alloy with the characteristics of flux cored wire. AlCr-CuFe2NiTix high-entropy surfacing alloys were prepared using gas metal arc welding technology. The wear properties of the alloys were analyzed, and the phase composition, microstructure, strengthening mechanism, and wear mechanism were discussed. The results show that the alloys exhibit a dendritic microstructure with BCC/B2 + FCC phases. Increasing Ti content leads to the precipitation of Laves phase. The alloys show improved microhardness and wear resistance due to the precipitation of coherent B2 and Laves phases. However, excessive Ti addition results in the increase of Laves phase and reduced wear resistance of the alloys.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
M. Vadivel, M. Senthil Pandian, P. Ramasamy, Qiang Jing, Bo Liu
Summary: This work presents the enhanced photocatalytic and electrochemical performance of g-C3N4 assisted PAA on CoFe2O4 ternary nanocomposites. The incorporation of PAA and g-C3N4 improves the separation efficiency of photogenerated charge carriers, resulting in superior photocatalytic degradation and high specific capacitance values.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Vibhu T. Sivanandan, Ramany Revathy, Arun S. Prasad
Summary: In this study, pure and doped cobalt ferrite nanoparticles were prepared using the sol-gel auto-combustion method with the aid of lemon juice as eco-fuel. The crystal structure, lattice parameter, crystallite size, microstrain, optical parameters, and room temperature magnetic properties of the samples were analyzed. The effect of doping on the magnetic properties was also investigated.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qing Guo, Bowen Zhang, Benzhe Sun, Yang Qi
Summary: This study prepared ZnO films with various nonpolar preferred orientations using conventional chemical bath deposition method and characterized their growth process and mechanism. It was found that the type and concentration of nitrate could control the preferred orientation and surface roughness of ZnO films. Additionally, ZnO films with different preferred orientations exhibited different optical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Chong Zhang, Yan Liu, Zhaoyan Wang, Hang Yang
Summary: In this study, six bimetallic FeCo particles were synthesized via the hydrothermal method at different Fe:Co ratios. The Fe:Co ratio not only modulates the composition of the particles but also influences their structure and magnetic properties. The FeCo alloys showed a transformation from an Fe-based structure to a Co-based structure with increasing Co content. The Fe:Co ratio of 1:1 and 3:1 resulted in particles with the highest and lowest saturation magnetization, respectively.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jianning Zhang, Jing Li, Yiren Wang, Xiaodong Mao, Yong Jiang
Summary: We conducted a study on the formation of ultra-fine Y-Ti-Ta-O nano-oxides in Ta+B micro-alloyed 13CrWTi-ODS alloys using electron microscopy and first-principles calculations. The Y-Ti-Ta-O nano-oxides were found to be mainly Y2(Ti,Ta)2O7, with an average size of 7 nm and a number density of 6.8 x 1023 m-3. Excess boron was found to enhance the adhesion of some low-sigma grain boundaries but weaken the Fe/Y2Ti2O7 interface, while excess tantalum enhanced the Fe/Y2Ti2O7 interface but caused serious degradation of grain boundaries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Yirong Fang, Pei Cheng, Hang Yuan, Hao Zhao, Lishu Zhang
Summary: A new composite system of nitrogen-doped reduced graphene oxide and black phosphorus quantum dots has been developed for tumor therapy, showing improved electrochemical properties and stability. The system generates hydrogen peroxide and hydroxyl radical to effectively kill tumor cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xiufang Qin, Yuanli Ma, Hui Zhang, Ting Zhang, Fang Wang, Xiaohong Xu
Summary: The structure and magnetism of cobalt ferrites after Mn2+-Tb3+ co-doping were studied. Co-doped samples exhibited cubic spinel structure and spherical shape of ferrite nanoparticles. The redistribution of Co2+ and Fe3+ ions between octahedral and tetrahedral sites was observed due to Mn2+-Tb3+ co-doping. The coercivity and magnetization saturation of co-doped samples were significantly improved, leading to a maximum energy product that is 190% higher than that of the un-doped sample.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ho Yeon Lee, Wonjong Yu, Yoon Ho Lee
Summary: Recently, there has been an increasing interest in developing ultra-fine nanostructured electrodes with extensive reaction areas to enhance the performance and low-temperature operation of solid oxide fuel cells. The use of a refined approach involving co-sputtering metal alloys and oxide targets has demonstrated the feasibility of nano-columnar structures in perovskite-based electrodes, expanding the temperature range of thin film electrodes. This study systematically examines the effects of chamber pressure control in the co-sputtering process and identifies the intricate relationship between sputtering pressure and film structure. By fine-tuning the columnar growth in the electrode, significant improvements in performance and thermo-mechanical properties were achieved, resulting in high-performance all-sputtered solid oxide fuel cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qianyun Bai, Xiaoxiao Yan, Da Liu, Kang Xiang, Xin Tu, Yanhui Guo, Renbing Wu
Summary: This study proposes a simple method to develop a non-precious transition metal-based electrocatalyst with high catalytic activity and robustness for the hydrogen evolution reaction. The as-synthesized electrode exhibits a low overpotential and high current density, indicating its potential in energy conversion.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)