Article
Materials Science, Multidisciplinary
Haixing Cao, Xianming Ren, Meibing Ma, Xin Yin, Yemei Han, Kai Hu, Zheng Sun, Fang Wang, Kailiang Zhang
Summary: The study presented a single-phase multiferroic spinel CoFe1.6Al0.4O4 with ferrimagnetic and ferroelectric properties at room temperature. The CoFe1.6Al0.4O4 films exhibit a spinel structure with Fd (3) over bar m space group, showing typical ferroelectric hysteresis and significant piezoresponse displacement at room temperature. The ferroelectric order likely originates from possible atomic orderings in cationic sublattices and local deformation induced by the substitution of Al ions at the sublattices of CoFe2O4 in the CoFe1.6Al0.4O4 spinel.
Article
Chemistry, Multidisciplinary
Shanquan Chen, Shuai Yuan, Zhipeng Hou, Yunlong Tang, Jinping Zhang, Tao Wang, Kang Li, Weiwei Zhao, Xingjun Liu, Lang Chen, Lane W. Martin, Zuhuang Chen
Summary: The paper explores recent advances in the study of topological spin/polarization structures in ferroic materials, including the evolution of topological spin structures and exotic polar topologies in magnetic thin films and ferroelectric oxide films. It discusses the control of these structures and emergent phenomena through factors such as epitaxial strain, layer thickness, electric fields, and magnetic fields. Additionally, the paper provides a brief overview and prospectus for the future development of the field in the coming years.
ADVANCED MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Amit Kumar, Piyush K. Patel, K. L. Yadav, Yogendra Singh, Naveen Kumar, Abdullah, G. Sharma, Satyendra Singh
Summary: The effect of grain boundary resistance (G(BR)) and grain resistance (G(R)) on the magnetoelectric coupling in multiferroic composite thick films of BiFeO3 (BFO) nanocrystalline powder and poly vinylidene-fluoride (PVDF) polymer is significant. The study shows that grain boundary resistance plays an important role in strengthening the magnetoelectric effect in the BFO-PVDF system, with the BFO50 sample demonstrating promising results for device and sensor applications.
MATERIALS RESEARCH BULLETIN
(2022)
Article
Materials Science, Ceramics
Jingwei Zhao, Zhonghua Yao, Zhijian Wang, Ning Zhang, Hua Hao, Minghe Cao, Hanxing Liu
Summary: By employing microstructural engineering, an optimized lead-free Zr-modified BiMg0.5Zr0.04Tix-0.04O3 composition was developed to enhance energy storage behavior, achieving superior energy properties and high efficiency. Rapid annealing and excess Ti source doping effectively increased polarization and dielectric breakdown levels.
CERAMICS INTERNATIONAL
(2021)
Review
Chemistry, Multidisciplinary
Oksana Tananaiko, Alain Walcarius
Summary: Sol-gel-derived silica thin films have attracted great interest for their applications as platforms for electrochemical sensors and biosensors. This review summarizes the major advances made with composite silica-based films in electroanalysis, including non-ordered composite films, vertically oriented mesoporous membranes, sol-gel bioencapsulation, and spectroelectrochemical sensors.
Article
Materials Science, Multidisciplinary
Zohra Nazir Kayani, Ifra Sheri, Salma Waseem, Saira Riaz, Shahzad Naseem
Summary: Ba-doped TiO2 thin films were fabricated using the sol-gel dip-coated method. X-ray diffraction confirmed the formation of the anatase phase. With the increase of Ba doping, the size of the crystallite decreased. The bandgap of pure TiO2 and Ba-doped TiO2 thin films was in the range of 3.15-2.94 eV, which is beneficial for enhancing solar cell efficiency and water treatment. Ba-doped TiO2 thin films exhibited low dielectric constant suitable for high-frequency devices and showed ferromagnetism. The antibacterial activity of Ba-doped TiO2 was higher than that of pure TiO2, making it suitable for application in nanomedicine.
MATERIALS RESEARCH BULLETIN
(2024)
Article
Chemistry, Physical
Katarzyna Gas, Gerd Kunert, Piotr Dluzewski, Rafal Jakiela, Detlef Hommel, Maciej Sawicki
Summary: Investigation of trilayer structures composed of nominally 45 nm GaN:Mg / 5 nm (Ga,Mn)N / 45 nm GaN:Mg prepared by molecular beam epitaxy on GaN-buffered Al2O3 substrates reveals that the indirect co-doping by holes from the cladding layers may not significantly alter the spin-spin interaction in (Ga,Mn)N, possibly due to the presence of residual Mn in the cladding layers. More technological efforts are suggested to promote the carrier-mediated ferromagnetic coupling in Mn-enriched GaN, particularly at elevated temperatures.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Electrical & Electronic
O. F. Goktas, N. E. Koksal, O. Kaplan, A. Yildiz
Summary: The sol-gel method was used to fabricate Al-doped ZnO (AZO) thin films on p-Si substrates with smooth surfaces and highly oriented crystal structures. The analysis revealed that the AZO/Si heterojunctions exhibited nonideal diode behavior, with the 80 nm thick AZO layer demonstrating good rectifying properties.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Chemistry, Physical
Maria Covei, Dana Perniu, Cristina Bogatu, Anca Duta, Ion Visa
Summary: This work investigates the self-cleaning and optical properties of composite thin films based on titanium dioxide (TiO2), tungsten oxide (WO3), and reduced graphene oxide (rGO) sprayed on glass substrates. The results show that the films have high photocatalytic efficiency in removing pollutants and excellent transmittance and reflectance properties in the UV-VIS region.
SURFACES AND INTERFACES
(2022)
Article
Materials Science, Ceramics
Wenyue Zhao, Zhao Wang, Ze Li, Yazhou Peng, Lei Shi, Wenjing Hua, Lidong Wang, Wei-Dong Fei, Yu Zhao
Summary: In this paper, the effect of defect dipoles on the ferromagnetic and ferroelectric properties of Ca3Mn2O7 improper ferroelectric thin films is reported. Both Mn3+-V···O and Li+-Al3+ defect dipoles can introduce ferromagnetism in the films, and Li+-Al3+ defect dipole can also improve ferroelectricity. The local lattice distortion plays a crucial role in the multiferroic properties of the film.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Multidisciplinary
A. Harres, T. A. Mallmann, M. Gamino, M. A. Correa, A. D. C. Viegas, R. B. da Silva
Summary: This study experimentally investigates the magnetization reversal processes in amorphous CoFeB thin films of different thicknesses. It concludes that domain wall displacement is the dominant reversal mechanism for films with 200 nm and 300 nm, while coherent rotation becomes important near the hard axis for the thinnest sample even when the external magnetic field is applied away from it.
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2022)
Article
Engineering, Electrical & Electronic
Shuokun Sun, Shichuang Cui, Fei Wang, Mingrui Gao, Wei Wei, Jinxiu Dong, Xiaoyan Xia, Quanyao Zhu, Jinyong Zhang
Summary: This study presents a vanadium pentoxide (V2O5)-cellulose composite electrochromic film with remarkable cycling stability and a wide range of color options. Flexible reflective electrochromic devices were successfully assembled using the prepared composite films, allowing for free switching between yellow and blue. The devices showed a low drive voltage and rapid switching response time after 1000 cycles.
ACS APPLIED ELECTRONIC MATERIALS
(2022)
Article
Materials Science, Ceramics
V Deepthi, Anju Sebastian, B. Vidhya
Summary: Sol-gel spin coating method was used to prepare ZnO and ZnO:GO composite films, and the effect of GO incorporation on film morphology and photocatalytic activity was investigated. The results showed that GO was evenly dispersed on the film surface, and the incorporation of GO improved the effectiveness of dye removal.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Lena Meyniel, Cedric Boissiere, Natacha Krins, Sophie Carenco
Summary: In this study, thin films of lanthanide oxysulfide were developed that are compatible with flexible substrates and retain the robustness advantages of inorganic compounds. The films, made using a low-temperature dip coating method, maintained the optical quality of the materials. The thickness of the films could be adjusted in a wide range, and thermal treatment was optimized to remove organic ligands while preserving the integrity of the nanoparticles.
Article
Chemistry, Physical
Huihuang Xu, Hua Hao, Yanjiang Xie, Xin Wang, Jianlu Geng, Minghe Cao, Zhonghua Yao, Hanxing Liu
Summary: Lead-free BaZr0.25Ti0.75O3 films grown via a sol-gel method on Pt/Ti/SiO2/Si substrates exhibit good microstructure and energy storage performance, with moderate polarization and high breakdown strength, as well as excellent temperature stability.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
J. Zamora, T. Bautista, N. S. Portillo-Velez, A. Reyes-Montero, H. Pfeiffer, F. Sanchez-Ochoa, H. A. Lara-Garcia
Summary: Experimental and DFT studies were conducted on the structural, magnetic, and optical properties of RFeO3 perovskites. The perovskites exhibited an orthorhombic crystal structure and weak ferromagnetic behavior. They were confirmed to be semiconductors with a bandgap of approximately 2.1 eV.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xianxiang Lv, Jing Jin, Weiguang Yang
Summary: By depositing TiN and TiO2 surface layers on AlSi films, the electrochemical performance of silicon-based anodes can be significantly improved, suppressing volume expansion and promoting the formation of a stable SEI layer.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Sharafat Ali, Haider Ali, Syedul Hasnain Bakhtiar, Sajjad Ali, Muhammad Zahid, Ahmed Ismail, Pir Muhammad Ismail, Amir Zada, Imran Khan, Huahai Shen, Rizwan Ullah, Habib Khan, Mohamed Bououdina, Xiaoqiang Wu, Fazal Raziq, Liang Qiao
Summary: The construction and optimization of redox-heterojunctions using a bifunctional phosphate as an electron-bridge demonstrated significant improvements in photo catalytic activity, including enhanced dispersion, reduced interfacial migration resistance, and increased abundance of active-sites.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ren-Ni Luan, Na Xu, Chao-Ran Li, Zhi-Jie Zhang, Yu-Sheng Zhang, Jun Nan, Shu-Tao Wang, Yong-Ming Chai, Bin Dong
Summary: Extensive research has revealed that oxygen evolution reaction (OER) in alkaline conditions involves dynamic surface restructuring. The development and design of sulfide/oxide pre-catalysts can reasonably adjust the composition and structure after surface reconstruction, which is crucial for OER. This study utilized a simple two-step hydrothermal method to achieve in situ S leaching and doping, inducing the composition change and structure reconstruction of CoFe oxides. The transformed FeOOH and CoOOH exhibited excellent OER activity and could be easily mass-produced using low-cost iron based materials and simple methods.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jun'an Lai, Daofu Wu, Peng He, Kang An, Yijia Wang, Peng Feng, WeiWei Chen, Zixian Wang, Linfeng Guo, Xiaosheng Tang
Summary: Zero-dimensional organic-inorganic metal halides (OMHs) are gaining attention in the fabrication of light-emitting diodes due to their broad emission band and high photoluminescence quantum yield. This work synthesized a zero-dimensional organic tetraphenylphosphonium bismuth chloride (TBC) that showed efficient blue light emission, with the emission mechanism attributed to the transition of Bi3+ ions. White light-emitting diodes (WLEDs) were fabricated using TBC, along with green-emitting and red-emitting single crystals, achieving single-component white emissions. These findings demonstrate the different emission mechanism of ns2 ions-based OMHs and highlight the potential of bismuth-based OMHs in WLEDs applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xuewei Liang, Yunhai Su, Taisen Yang, Zhiyong Dai, Yingdi Wang, Xingping Yong
Summary: The revolutionary design concept of high-entropy alloys has brought new opportunities and challenges to the development of advanced metal materials. In this work, AlCrCuFe2NiTix high-entropy flux cored wires were prepared by combining the design idea of a high-entropy alloy with the characteristics of flux cored wire. AlCr-CuFe2NiTix high-entropy surfacing alloys were prepared using gas metal arc welding technology. The wear properties of the alloys were analyzed, and the phase composition, microstructure, strengthening mechanism, and wear mechanism were discussed. The results show that the alloys exhibit a dendritic microstructure with BCC/B2 + FCC phases. Increasing Ti content leads to the precipitation of Laves phase. The alloys show improved microhardness and wear resistance due to the precipitation of coherent B2 and Laves phases. However, excessive Ti addition results in the increase of Laves phase and reduced wear resistance of the alloys.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
M. Vadivel, M. Senthil Pandian, P. Ramasamy, Qiang Jing, Bo Liu
Summary: This work presents the enhanced photocatalytic and electrochemical performance of g-C3N4 assisted PAA on CoFe2O4 ternary nanocomposites. The incorporation of PAA and g-C3N4 improves the separation efficiency of photogenerated charge carriers, resulting in superior photocatalytic degradation and high specific capacitance values.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Vibhu T. Sivanandan, Ramany Revathy, Arun S. Prasad
Summary: In this study, pure and doped cobalt ferrite nanoparticles were prepared using the sol-gel auto-combustion method with the aid of lemon juice as eco-fuel. The crystal structure, lattice parameter, crystallite size, microstrain, optical parameters, and room temperature magnetic properties of the samples were analyzed. The effect of doping on the magnetic properties was also investigated.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qing Guo, Bowen Zhang, Benzhe Sun, Yang Qi
Summary: This study prepared ZnO films with various nonpolar preferred orientations using conventional chemical bath deposition method and characterized their growth process and mechanism. It was found that the type and concentration of nitrate could control the preferred orientation and surface roughness of ZnO films. Additionally, ZnO films with different preferred orientations exhibited different optical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Chong Zhang, Yan Liu, Zhaoyan Wang, Hang Yang
Summary: In this study, six bimetallic FeCo particles were synthesized via the hydrothermal method at different Fe:Co ratios. The Fe:Co ratio not only modulates the composition of the particles but also influences their structure and magnetic properties. The FeCo alloys showed a transformation from an Fe-based structure to a Co-based structure with increasing Co content. The Fe:Co ratio of 1:1 and 3:1 resulted in particles with the highest and lowest saturation magnetization, respectively.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jianning Zhang, Jing Li, Yiren Wang, Xiaodong Mao, Yong Jiang
Summary: We conducted a study on the formation of ultra-fine Y-Ti-Ta-O nano-oxides in Ta+B micro-alloyed 13CrWTi-ODS alloys using electron microscopy and first-principles calculations. The Y-Ti-Ta-O nano-oxides were found to be mainly Y2(Ti,Ta)2O7, with an average size of 7 nm and a number density of 6.8 x 1023 m-3. Excess boron was found to enhance the adhesion of some low-sigma grain boundaries but weaken the Fe/Y2Ti2O7 interface, while excess tantalum enhanced the Fe/Y2Ti2O7 interface but caused serious degradation of grain boundaries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Yirong Fang, Pei Cheng, Hang Yuan, Hao Zhao, Lishu Zhang
Summary: A new composite system of nitrogen-doped reduced graphene oxide and black phosphorus quantum dots has been developed for tumor therapy, showing improved electrochemical properties and stability. The system generates hydrogen peroxide and hydroxyl radical to effectively kill tumor cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xiufang Qin, Yuanli Ma, Hui Zhang, Ting Zhang, Fang Wang, Xiaohong Xu
Summary: The structure and magnetism of cobalt ferrites after Mn2+-Tb3+ co-doping were studied. Co-doped samples exhibited cubic spinel structure and spherical shape of ferrite nanoparticles. The redistribution of Co2+ and Fe3+ ions between octahedral and tetrahedral sites was observed due to Mn2+-Tb3+ co-doping. The coercivity and magnetization saturation of co-doped samples were significantly improved, leading to a maximum energy product that is 190% higher than that of the un-doped sample.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ho Yeon Lee, Wonjong Yu, Yoon Ho Lee
Summary: Recently, there has been an increasing interest in developing ultra-fine nanostructured electrodes with extensive reaction areas to enhance the performance and low-temperature operation of solid oxide fuel cells. The use of a refined approach involving co-sputtering metal alloys and oxide targets has demonstrated the feasibility of nano-columnar structures in perovskite-based electrodes, expanding the temperature range of thin film electrodes. This study systematically examines the effects of chamber pressure control in the co-sputtering process and identifies the intricate relationship between sputtering pressure and film structure. By fine-tuning the columnar growth in the electrode, significant improvements in performance and thermo-mechanical properties were achieved, resulting in high-performance all-sputtered solid oxide fuel cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qianyun Bai, Xiaoxiao Yan, Da Liu, Kang Xiang, Xin Tu, Yanhui Guo, Renbing Wu
Summary: This study proposes a simple method to develop a non-precious transition metal-based electrocatalyst with high catalytic activity and robustness for the hydrogen evolution reaction. The as-synthesized electrode exhibits a low overpotential and high current density, indicating its potential in energy conversion.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)