Article
Chemistry, Physical
A. Bandyopadhyay, B. J. Sarkar, S. Sutradhar, J. Mandal, P. K. Chakrabarti
Summary: By incorporating Gd3+ ions instead of Ce4+ ions in cerium oxide lattice, improvements were made in its magneto-dielectric properties. Nonlinearity due to magnetic ordering was introduced in the doped sample Ce0.90Gd0.10O2-delta, indicating a transition to ferromagnetic phase. Transmission electron microscopy study revealed important morphological behavior.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Multidisciplinary
Emily Siska, Dean Smith, Ashkan Salamat, Keith V. Lawler, Barbara Lavina, Frederic Poineau, Paul M. Forster
Summary: The synthesis and phase stability of TcN, Tc2N, and a substoichiometric TcNx were demonstrated under high pressure and temperature conditions, with a previously unpredicted structure identified for TcN through crystal structure prediction.
CHEMICAL COMMUNICATIONS
(2021)
Article
Materials Science, Ceramics
Amine Bendahhou, Karim Chourti, Soufian El Barkany, Mohamed Abou-Salama
Summary: Ba-4(Nd1-xSmx)(28/3)(Ti0,95Zr0,05)(18)O-54 ceramics with varying Nd/Sm ratio were studied for their structure and dielectric behavior. The crystal structure was found to belong to the tungsten bronze type, with dense microstructure and significant temperature-dependent dielectric properties.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Ana Cotai, Bogdan Viorel Neamtu, Florin Popa, Traian Florin Marinca, Olivier Isnard, Ionel Chicinas
Summary: This study compares HITPERM type alloys prepared by wet and dry mechanical alloying, finding that amorphization occurred after 40 hours of milling in wet conditions, but not after 100 hours in dry conditions. Various analyses were performed to investigate the thermal stability and crystallization kinetics of the amorphous powders.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Kemryn Allen-Perry, Weston Straka, Danielle Keith, Shubo Han, Lewis Reynolds, Bhoj Gautam, Daniel E. Autrey
Summary: Two-dimensional materials based on transition metal carbides, such as MXenes, have unique properties and great potential in various applications. This study investigated the magnetic properties of Ti-based MXenes and found that the magnetic properties can be tuned by chemical etching conditions, which is beneficial for designing spintronic devices.
Article
Engineering, Chemical
R. Ostapenko, K. Ivanenko, A. Kuryliuk, O. Nakonechna, N. Belyavina
Summary: In this study, the mechanical alloying of Ni-carbon nanotubes (CNT) and Ni-Graphite equiatomic powder mixtures was comprehensively investigated. Regardless of the type of carbon used, a novel nanoscale fcc NiC monocarbide was synthesized. XRD analysis revealed that the formation of this phase occurred in two stages, suggesting a two-step carbide formation mechanism. The synthesized carbides exhibited weak ferromagnetic properties at room temperature, with a Curie temperature range of 670-725 K.
ADVANCED POWDER TECHNOLOGY
(2022)
Article
Materials Science, Ceramics
Marcin Godzierz, Piotr Olesik, Lukasz Otulakowski, Tomasz Pawlik, Karolina Olszowska, Pawel Chaber, Olha Masiuchok, Hanna Myalska-Glowacka, Jakub Smolen, Bartlomiej Toron, Piotr Szperlich, Urszula Szeluga, Slawomira Pusz
Summary: In this study, a novel, facile, and highly efficient reverse co-precipitation method was used to synthesize nanocrystalline bismuth ferrite (BFO) powder. The proposed method is cost-efficient and environmentally friendly. X-ray diffraction and scanning electron microscopy were used to analyze the crystal structure, phase composition, and morphology of the synthesized powders. The obtained materials showed excellent piezoelectric properties, comparable to those of praseodymium, samarium, or europium doped BiFeO3 ceramic.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Physical
Khalid Mujasam Batoo, Ritesh Verma, Ankush Chauhan, Rajesh Kumar, Muhammad Hadi, Omar M. Aldossary, Y. Al-Douri
Summary: This study reported the synthesis of Gd and Nb co-doped BT ceramic oxides and investigated their structural and electrical properties. Various analysis techniques were used to characterize the samples, revealing the influence of Gd and Nb doping on the electrical properties of the ceramic materials, which were found to improve with increasing dopant concentration.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Joshua P. Smith, Kurt E. Sickafus, Claudia J. Rawn, Cordell Delzer, Ching-Fong Chen, Charles Melcher
Summary: Li-containing garnet compounds have potential as transparent ceramic dual-mode scintillators, with Li5La3Ta2O12 showing promise due to its properties. This study focused on establishing thermal processing conditions for a sol-gel method and consolidating powders to form high-density ceramics. The experiments showed the presence of two cubic Li5La3Ta2O12 garnet phases with different lattice parameters, indicating a remaining excess of Li in the ceramics.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Ceramics
N. Lenin, A. Karthik, S. R. Srither, M. Sridharpanday, S. Surendhiran, M. Balasubramanian
Summary: Cr-doped zinc-lanthanum nanoferrites were successfully synthesized using sonochemical reactors, with a cubic spinel structure and small crystallite size confirmed. The addition of chromium was found to enhance the optical, electrical, and magnetic properties of the nanoferrites, as observed through various characterization techniques. The study sheds light on the potential applications of these nanoferrites in various technological fields.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Nadezhda S. Smirnova, Evgeny Khramov, Igor P. Stolarov, Ilya A. Yakushev, Galina N. Baeva, Galina O. Bragina, Ekaterina Belova, Arcady Ishchenko, Anna S. Popova, Yan Zubavichus, Michael N. Vargaftik, Aleksander Y. Stakheev
Summary: This study thoroughly investigates the phase transformations of a newly synthesized heterobimetallic acetate in a chemically reductive atmosphere, with a focus on optimizing conditions for the formation of nanostructured PtZn intermetallic compound. Through a two-stage process, the formation of ordered PtZn intermetallic compound with a tetragonal structure is achieved in a narrow temperature range. The results provide insight into the optimum reduction temperature for the preparation of supported bimetallic Pt?Zn/Al2O3 catalyst.
Article
Physics, Applied
I. I. Aliyev, S. Sh. Ismailova, R. M. Rzayev, A. N. Mamedov, Kh. M. Gashimov, N. K. Karimova
Summary: Alloys of the As2Se3-CuCr2Te4 system were synthesized and their physico-chemical properties were investigated. The phase diagram of the system was found to be quasi-binary of the eutectic type, with small single-phase fields and solid solution areas based on the original components.
MODERN PHYSICS LETTERS B
(2022)
Article
Polymer Science
Aleksandra Radko, Sebastian Lalik, Aleksandra Deptuch, Teresa Jaworska-Golab, Robert Ekiert, Natalia Gorska, Katarzyna Makyla-Juzak, Jacek Niziol, Monika Marzec
Summary: The study investigated DNA complexes with different surfactants using Fourier transform middle infrared spectroscopy, X-ray diffraction and dielectric spectroscopy methods, confirming electrostatic interactions in complex formation. A packing model for the complex molecules, depending on the type of surfactant, was proposed based on SAXS results. The dielectric process in low frequency range was interpreted as oscillation of surfactant ions, similar to ions in pure DNA solutions.
Article
Materials Science, Multidisciplinary
Shrabani Paul, Umapada Pal, Swapan Kumar Pradhan
Summary: This study investigates the synthesis and thermoelectric performance of Bi2Te3 nanocrystals. The thermoelectric properties of the nanocrystals are significantly improved through thermal annealing treatment.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Materials Science, Multidisciplinary
Maryam Hajipour, Hossein Raanaei, Saeid Zarei
Summary: This research investigated the structural, magnetic, and thermal properties of a cobalt-based alloy produced by mechanical alloying. The results showed that after milling, a solid solution with an iron-based structure was achieved, and both the crystallite size and coercivity increased.
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
C. Venkataraju, G. Sathishkumar, K. Sivakumar
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2010)
Article
Materials Science, Multidisciplinary
C. Venkataraju, G. Sathishkumar, K. Sivakumar
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2011)
Article
Engineering, Electrical & Electronic
G. Sathishkumar, C. Venkataraju, K. Sivakumar
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2011)
Article
Engineering, Electrical & Electronic
C. Venkataraju, G. Satishkumar, K. Sivakumar
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2012)
Article
Engineering, Electrical & Electronic
G. Sathishkumar, C. Venkataraju, R. Murugaraj, K. Sivakumar
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2012)
Article
Engineering, Electrical & Electronic
G. Sathishkumar, C. Venkataraju, K. Sivakumar
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2013)
Article
Chemistry, Physical
A. Titus Samuel Sudandararaj, G. Sathish Kumar, M. Dhivya, R. D. Eithiraj, I. B. Shameem Banu
JOURNAL OF ALLOYS AND COMPOUNDS
(2019)
Article
Chemistry, Physical
A. Titus Samuel Sudandararaj, G. Sathish Kumar, M. Dhivya, R. D. Eithiraj, I. B. Shameem Banu
JOURNAL OF ALLOYS AND COMPOUNDS
(2020)
Article
Materials Science, Multidisciplinary
N. Karthikeyan, B. Kavin Kumar, G. Sathish Kumar, R. Akilan
Summary: In this study, the effect of Se doping on the beta-Zn4Sb3 system was investigated. The sample was found to crystallize in a hexagonal rhombohedral structure. The electrical conductivity of the sample exhibited typical metallic to semiconductor transition behavior. The dominant charge carriers in the sample were found to be holes (p-type). The power factor of the sample increased linearly with temperature. The total thermal conductivity of the sample decreased linearly with temperature and showed a low value at 610K. The ZT value of the sample reached 0.3 at 610K, which is competitive with current thermoelectric materials.
BULLETIN OF MATERIALS SCIENCE
(2023)
Article
Chemistry, Physical
J. Zamora, T. Bautista, N. S. Portillo-Velez, A. Reyes-Montero, H. Pfeiffer, F. Sanchez-Ochoa, H. A. Lara-Garcia
Summary: Experimental and DFT studies were conducted on the structural, magnetic, and optical properties of RFeO3 perovskites. The perovskites exhibited an orthorhombic crystal structure and weak ferromagnetic behavior. They were confirmed to be semiconductors with a bandgap of approximately 2.1 eV.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xianxiang Lv, Jing Jin, Weiguang Yang
Summary: By depositing TiN and TiO2 surface layers on AlSi films, the electrochemical performance of silicon-based anodes can be significantly improved, suppressing volume expansion and promoting the formation of a stable SEI layer.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Sharafat Ali, Haider Ali, Syedul Hasnain Bakhtiar, Sajjad Ali, Muhammad Zahid, Ahmed Ismail, Pir Muhammad Ismail, Amir Zada, Imran Khan, Huahai Shen, Rizwan Ullah, Habib Khan, Mohamed Bououdina, Xiaoqiang Wu, Fazal Raziq, Liang Qiao
Summary: The construction and optimization of redox-heterojunctions using a bifunctional phosphate as an electron-bridge demonstrated significant improvements in photo catalytic activity, including enhanced dispersion, reduced interfacial migration resistance, and increased abundance of active-sites.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ren-Ni Luan, Na Xu, Chao-Ran Li, Zhi-Jie Zhang, Yu-Sheng Zhang, Jun Nan, Shu-Tao Wang, Yong-Ming Chai, Bin Dong
Summary: Extensive research has revealed that oxygen evolution reaction (OER) in alkaline conditions involves dynamic surface restructuring. The development and design of sulfide/oxide pre-catalysts can reasonably adjust the composition and structure after surface reconstruction, which is crucial for OER. This study utilized a simple two-step hydrothermal method to achieve in situ S leaching and doping, inducing the composition change and structure reconstruction of CoFe oxides. The transformed FeOOH and CoOOH exhibited excellent OER activity and could be easily mass-produced using low-cost iron based materials and simple methods.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jun'an Lai, Daofu Wu, Peng He, Kang An, Yijia Wang, Peng Feng, WeiWei Chen, Zixian Wang, Linfeng Guo, Xiaosheng Tang
Summary: Zero-dimensional organic-inorganic metal halides (OMHs) are gaining attention in the fabrication of light-emitting diodes due to their broad emission band and high photoluminescence quantum yield. This work synthesized a zero-dimensional organic tetraphenylphosphonium bismuth chloride (TBC) that showed efficient blue light emission, with the emission mechanism attributed to the transition of Bi3+ ions. White light-emitting diodes (WLEDs) were fabricated using TBC, along with green-emitting and red-emitting single crystals, achieving single-component white emissions. These findings demonstrate the different emission mechanism of ns2 ions-based OMHs and highlight the potential of bismuth-based OMHs in WLEDs applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xuewei Liang, Yunhai Su, Taisen Yang, Zhiyong Dai, Yingdi Wang, Xingping Yong
Summary: The revolutionary design concept of high-entropy alloys has brought new opportunities and challenges to the development of advanced metal materials. In this work, AlCrCuFe2NiTix high-entropy flux cored wires were prepared by combining the design idea of a high-entropy alloy with the characteristics of flux cored wire. AlCr-CuFe2NiTix high-entropy surfacing alloys were prepared using gas metal arc welding technology. The wear properties of the alloys were analyzed, and the phase composition, microstructure, strengthening mechanism, and wear mechanism were discussed. The results show that the alloys exhibit a dendritic microstructure with BCC/B2 + FCC phases. Increasing Ti content leads to the precipitation of Laves phase. The alloys show improved microhardness and wear resistance due to the precipitation of coherent B2 and Laves phases. However, excessive Ti addition results in the increase of Laves phase and reduced wear resistance of the alloys.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
M. Vadivel, M. Senthil Pandian, P. Ramasamy, Qiang Jing, Bo Liu
Summary: This work presents the enhanced photocatalytic and electrochemical performance of g-C3N4 assisted PAA on CoFe2O4 ternary nanocomposites. The incorporation of PAA and g-C3N4 improves the separation efficiency of photogenerated charge carriers, resulting in superior photocatalytic degradation and high specific capacitance values.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Vibhu T. Sivanandan, Ramany Revathy, Arun S. Prasad
Summary: In this study, pure and doped cobalt ferrite nanoparticles were prepared using the sol-gel auto-combustion method with the aid of lemon juice as eco-fuel. The crystal structure, lattice parameter, crystallite size, microstrain, optical parameters, and room temperature magnetic properties of the samples were analyzed. The effect of doping on the magnetic properties was also investigated.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qing Guo, Bowen Zhang, Benzhe Sun, Yang Qi
Summary: This study prepared ZnO films with various nonpolar preferred orientations using conventional chemical bath deposition method and characterized their growth process and mechanism. It was found that the type and concentration of nitrate could control the preferred orientation and surface roughness of ZnO films. Additionally, ZnO films with different preferred orientations exhibited different optical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Chong Zhang, Yan Liu, Zhaoyan Wang, Hang Yang
Summary: In this study, six bimetallic FeCo particles were synthesized via the hydrothermal method at different Fe:Co ratios. The Fe:Co ratio not only modulates the composition of the particles but also influences their structure and magnetic properties. The FeCo alloys showed a transformation from an Fe-based structure to a Co-based structure with increasing Co content. The Fe:Co ratio of 1:1 and 3:1 resulted in particles with the highest and lowest saturation magnetization, respectively.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jianning Zhang, Jing Li, Yiren Wang, Xiaodong Mao, Yong Jiang
Summary: We conducted a study on the formation of ultra-fine Y-Ti-Ta-O nano-oxides in Ta+B micro-alloyed 13CrWTi-ODS alloys using electron microscopy and first-principles calculations. The Y-Ti-Ta-O nano-oxides were found to be mainly Y2(Ti,Ta)2O7, with an average size of 7 nm and a number density of 6.8 x 1023 m-3. Excess boron was found to enhance the adhesion of some low-sigma grain boundaries but weaken the Fe/Y2Ti2O7 interface, while excess tantalum enhanced the Fe/Y2Ti2O7 interface but caused serious degradation of grain boundaries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Yirong Fang, Pei Cheng, Hang Yuan, Hao Zhao, Lishu Zhang
Summary: A new composite system of nitrogen-doped reduced graphene oxide and black phosphorus quantum dots has been developed for tumor therapy, showing improved electrochemical properties and stability. The system generates hydrogen peroxide and hydroxyl radical to effectively kill tumor cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xiufang Qin, Yuanli Ma, Hui Zhang, Ting Zhang, Fang Wang, Xiaohong Xu
Summary: The structure and magnetism of cobalt ferrites after Mn2+-Tb3+ co-doping were studied. Co-doped samples exhibited cubic spinel structure and spherical shape of ferrite nanoparticles. The redistribution of Co2+ and Fe3+ ions between octahedral and tetrahedral sites was observed due to Mn2+-Tb3+ co-doping. The coercivity and magnetization saturation of co-doped samples were significantly improved, leading to a maximum energy product that is 190% higher than that of the un-doped sample.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ho Yeon Lee, Wonjong Yu, Yoon Ho Lee
Summary: Recently, there has been an increasing interest in developing ultra-fine nanostructured electrodes with extensive reaction areas to enhance the performance and low-temperature operation of solid oxide fuel cells. The use of a refined approach involving co-sputtering metal alloys and oxide targets has demonstrated the feasibility of nano-columnar structures in perovskite-based electrodes, expanding the temperature range of thin film electrodes. This study systematically examines the effects of chamber pressure control in the co-sputtering process and identifies the intricate relationship between sputtering pressure and film structure. By fine-tuning the columnar growth in the electrode, significant improvements in performance and thermo-mechanical properties were achieved, resulting in high-performance all-sputtered solid oxide fuel cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qianyun Bai, Xiaoxiao Yan, Da Liu, Kang Xiang, Xin Tu, Yanhui Guo, Renbing Wu
Summary: This study proposes a simple method to develop a non-precious transition metal-based electrocatalyst with high catalytic activity and robustness for the hydrogen evolution reaction. The as-synthesized electrode exhibits a low overpotential and high current density, indicating its potential in energy conversion.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)