4.7 Article

Room-temperature ferromagnetism in Ti1-xVxO2 nanocrystals synthesized from an organic-free and water-soluble precursor

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 499, Issue 2, Pages 160-165

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2010.01.023

Keywords

Dilute magnetic semiconductor; Ti1-xVxO2 nanocrystals; Ferromagnetism; Oxygen vacancies and interstitials; Bound magnetic polaron model

Funding

  1. National 973 Program of China [2007CB936704, 2009CB939903]
  2. National Science Foundation of China [50772123, 50821004]
  3. Science and Technology Commission of Shanghai [0752nm016, 0952nm06500, 08JC1420200]

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Ti1-xVxO2 nanocrystals were prepared by employing a novel and water-soluble precursor via hydrothermal method, and the microstructure and magnetic properties have been investigated. All the samples belong to a pure anatase structure and exhibit room-temperature ferromagnetism (RTFM) without any trace of vanadium oxides or clusters. After V doping, the anatase structure is retained, while crystal growth is restrained. The homogenous distribution of V, in V4+ chemical state, in TiO2 lattice is confirmed by X-ray powder diffraction (XRD), energy-dispersive X-ray spectra (EDS), Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analyses. Ferromagnetism in Ti1-xVxO2 is revealed to be highly dependent on the V content and defect concentrations. Furthermore, the annealing study in various atmospheres indicates that the oxygen vacancies and interstitials play a crucial role in inducing ferromagnetism in Ti1-xVxO2 system, and the origin of RTFM can be explained by bound magnetic polaron model. (C) 2010 Elsevier B.V. All rights reserved.

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