4.7 Article

Effect of Ni doped BaTiO3 on the dielectric properties in the Ba(Ni1/3Nb2/3)xTi1-xO3 solid solution

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 481, Issue 1-2, Pages 559-562

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2009.03.081

Keywords

Dielectric; Ferroelectric; Perovskite; Ceramic

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New ferroelectric ceramics of ABO(3) perovskite type were synthesized in the Ba(Ni1/3Nb2/3)(x)Ti1-xO3 (0 <= x <= 0.2) system by solid state reaction technique. The effect of the replacement of titanium by nickel and niobium in the B site on structural and dielectric properties was investigated. For this, we have use X-ray diffraction and dielectric characterizations. Samples in cubic phase were generally obtained with a sintering temperature of 1350 degrees C. Dielectric measurements revealed that the very small change in composition by the substitution of titanium by nickel and niobium in the BaTiO3 has a strong influence on the dielectric proprieties: fast decreasing of T-C or T-m (for BaTiO3 T-C = 340 K, for x = 0.06, T-C = 270 K and for x = 0.16, T-m = 150 K). The evolution from classic ferroelectric behavior for (0 <= x < 0.1) to relaxor behavior for (0.1 <= x <= 0.2) is emphasized. (C) 2009 Published by Elsevier B.V.

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