Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 454, Issue 1-2, Pages 483-490Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2007.01.006
Keywords
hydrogen absorbing materials; metal hydrides; titanium; Ti-6Al-4V; temperature programmed desorption
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We report the results of a study using temperature programmed desorption (TPD) and a volumetric sorption technique to measure the hydrogen storage capacity of the Ti-6Al-4V alloy. Samples of various sizes and surface treatments were studied to obtain a statistically meaningful value for the maximum hydrogen storage capacity, as well as to understand the effect of sample size, sample oxidation, and hydrogen charging conditions on the measured capacity. We find a maximum reversible hydrogen storage capacity of similar to 3.76 wt% with hydrogen exposures near ambient temperature and pressure. This value is higher than any reported in the literature previously, possibly due to the utilization of very small particles and rapid hydrogen exposures, which allow for equilibration times of approximately I h. Comparison of a variety of samples indicates that the measured hydrogen capacity is affected by surface oxidation. Samples generated in a strongly oxidizing environment exhibit decreased hydrogen uptake. The implications of these results are discussed with regards to previously reported capacity values in the literature. (C) 2007 Elsevier B.V. All rights reserved.
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