4.8 Article

Fast Water Thermo-pumping Flow Across Nanotube Membranes for Desalination

Journal

NANO LETTERS
Volume 15, Issue 6, Pages 3664-3668

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/nl504236g

Keywords

Water pumping; nanotube; membrane; temperature difference; desalination; molecular dynamics

Funding

  1. National Natural Science Foundation of China [51376130, 50925624]
  2. National Basic Research Program of China (973 Program) [2012CB720404]
  3. Science and Technology Commission of Shanghai Municipality [12JC1405100]

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Development of high-efficiency and low-cost seawater desalination technologies is critical to meet global water crisis. Here we report a fast water pumping method in which the water molecules in seawater are continuously pumped across nanotube membranes driven by a small temperature difference, opening the possibility of high-throughput small-scale desalination devices driven by low-grade thermal energy. Using molecular dynamics simulations, we show that an equivalent driving pressure of 5.3 MPa is achieved with a temperature difference of only 15 K. The remarkable water pumping ability is attributed to the asymmetric thermal fluctuation of water molecules. With this method, a 10 cm(2) nanotube membrane with 1.5 x 10(13) pores per cm(2) will produce freshwater with a flow rate of 7.77 L/h under a small temperature difference of 15 K.

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