4.7 Article

Kinetics of Carotenoids Degradation during the Storage of Einkorn (Triticum monococcum L. ssp monococcum) and Bread Wheat (Triticum aestivum L. ssp aestivum) Flours

Journal

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
Volume 56, Issue 23, Pages 11300-11305

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jf802448t

Keywords

Bread wheat; carotenoids; einkorn; kinetics; storage; Triticum

Funding

  1. MonICA-Monococco per I'innovazione agricola e colturale
  2. Regione Lombardia, Italy

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To evaluate the effect of storage temperature, the degradation kinetics of carotenoids in wholemeal and white flour of einkorn cv. Monlis and bread wheat cv. Serio, stored at -20, 5, 20, 30, and 38 degrees C, was assessed by normal-phase high-performance liquid chromatography. In Monlis, the carotenoids content (8.1 and 9.8 mg/kg for wholemeal and white flour, respectively) was 8-fold higher than in Serio (1.0 and 1.1 mg/kg). Only lutein and zeaxanthin were detected in bread wheat, while significant quantities of (alpha and beta)-carotene and beta-cryptoxanthin were observed in einkorn. Carotenoids degradation was influenced by temperature and time, following first-order kinetics. The degradation rate was similar in wholemeal and white flour; however, loss of lutein and total carotenoids was faster in Serio than in Monlis. The activation energy E-a ranged from 35.2 to 52.5 kJ/mol. Temperatures not exceeding 20 degrees C better preserve carotenoids content and are recommended for long-term storage.

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