Journal
MOLECULES
Volume 20, Issue 4, Pages 5276-5285Publisher
MDPI AG
DOI: 10.3390/molecules20045276
Keywords
microwave irradiation; solid-support; Glaser-Hay
Funding
- College of William Mary
- Jeffress Memorial Trust
Ask authors/readers for more resources
The translation of organometallic reactions into a microwave reactor has numerous advantages. Herein, we describe the application of a previously developed solid-supported Glaser-Hay reaction to microwave conditions. Overall, an array of diynes has been prepared demonstrating the ability to conduct chemoselective reactions in the microwave within 20 min compared to the 16 h thermal conditions. Moreover, non-microwave transparent alkynes have been found to react more quickly, preventing catalyst quenching, and resulting in higher yields.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available