Journal
MOLECULES
Volume 20, Issue 6, Pages 9906-9914Publisher
MDPI AG
DOI: 10.3390/molecules20069906
Keywords
palladium; polymer-support; hydrodechlorination; seawater
Funding
- International Research Hub project of the Faculty of Science, University of the Ryukyus
- Okinawa Science and Technology Promotion Center
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A polymer-supported terpyridine palladium complex was prepared. The complex was found to promote hydrodechlorination of aryl chlorides with potassium formate in seawater. Generally, reductive cleavage of aryl chlorides using transition metal catalysts is more difficult than that of aryl bromides and iodides (reactivity: I > Br > Cl); however, the results obtained did not follow the general trend. Therefore, we investigated the reaction inhibition agents and found a method to remove these inhibitors. The polymeric catalysts showed high catalytic activity and high reusability for transfer reduction in seawater.
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