Journal
ISRAEL JOURNAL OF CHEMISTRY
Volume 52, Issue 1-2, Pages 20-29Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.201100075
Keywords
cavitands; conformational analysis; container molecules; controllable encapsulation; fluorescence
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Funding
- Swiss National Science Foundation (SNF)
- NCCR Nano-scale Science, Basel
- German Fonds der Chemischen Industrie
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This review describes our recent developments in the field of resorcin[4]arene cavitands. We present the syntheses of cavitands bearing pyrene, anthracene, and BODIPY dyes as fluorophores on the cavitand walls. These systems have been used to examine the conformational switching process between the closed vase and the open kite forms that are characteristic for this class of cavitands. In a second research direction, we prepared top-covered resorcin[4]arene-based, switchable container molecules, and investigated their binding and switching properties.
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