Dehydration of clastic sediments in subduction zones: Theoretical study using thermodynamic data of minerals

Pseudosections for two sediments and one basalt calculated in the system K2O-Na2O-CaO-MgO-FeO-Fe2O3-Al2O3-TiO2-SiO2-H2O for the P-T range 10 to 35 kbar, 300 to 900 degrees C give useful insights into the amount of H2O released from oceanic crust in subduction zones. In cold subduction zones (20 kbar-300 degrees C to 35 kbar-500 degrees C) hydrous minerals storing 3 to 4 wt% H2O are still present in metasediments at depths of 120 km. In the same environment, metabasite releases 1 wt% H2O in the depth range 100 to 120 km, but 4.5 wt% H2O is transported to greater depths. In hot subduction zones (300 degrees C hotter than the cold subduction zone at 100 km depth), dehydration events of metasediments in the depth range 50 to 80 km correspond to the breakdown of chlorite and paragonite. In the calculations no further water is released at greater depths because the modal content of phengite, the only hydrous mineral phase at these depths, remains almost constant. For the same P-T path, metabasite shows continuous dehydration between 40 and 80 km releasing almost 3 wt% H2O. At 120 km depth less than 0.4 wt% of H2O remains. In an average modern subduction zone (similar to 6 degrees C/km) most dehydration of sediments occurs at depths of 70 to 100 km and that of basalts at depths of 80 to 120 km. Only 1.3 wt% H2O in metasediments and 1.6 wt% H2O in metabasalt has the potential to be subducted to depths greater than 120 km. The dehydration behavior of sediments concurs with the generally held idea that subduction zone fluids are most effectively transported to great depths by cold subduction. In hot subduction zones, such as those characteristic of early Earth, most H2O carried by oceanic crust is liberated at depths less than 120 km and, thus, would not contribute to island-arc magmatism.