Article
Materials Science, Multidisciplinary
Hongpo Wang, Peng Yu, Xiaoqing Zhou, Yu Wang, Xuewei Lv
Summary: Stability diagrams are crucial for studying deoxidation equilibrium and controlling inclusions in molten steel. Three-dimensional stability diagrams can visually show phase boundaries and transformation trends among phases. An interesting transformation of inclusions was observed in the Fe-Al-Mg-O system, where the equilibrium products of aluminum-magnesium composite deoxidation can transition between MgO, MgO·Al2O3, and Al2O3.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Review
Metallurgy & Metallurgical Engineering
Lei Cao, Li-guang Zhu, Zhi-hong Guo
Summary: Non-metallic inclusions have a significant impact on the fatigue life and quality stability of high-quality bearing steel. The research progress of inclusion formation, removal, and modification was discussed, and the feasibility of non-alloy deoxidation process using C or H-2 as deoxidizer for high-quality bearing steel was proposed. The non-alloy deoxidation process is of great importance for reducing oxygen content and improving cleanliness of high-quality bearing steel.
JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL
(2023)
Article
Metallurgy & Metallurgical Engineering
Angshuman Podder, Kenneth S. Coley, Andre B. Phillion
Summary: Complex deoxidation with Si and Mn is beneficial for certain steel long products, but the introduction of Al through steel-slag reactions can lead to unwanted inclusion formation and nozzle clogging. In this study, a kinetic model is developed to simulate steel-slag-inclusion reactions and investigate the effect of slag-metal reactions on inclusions.
STEEL RESEARCH INTERNATIONAL
(2022)
Article
Materials Science, Multidisciplinary
Zhe Rong, Hongbo Liu, Peng Zhang, Feng Wang, Geoff Wang, Baojun Zhao, Fengqiu Tang, Xiaodong Ma
Summary: This study investigates the formation mechanisms and evolution of complex inclusions in Ti-Ca deoxidized offshore structural steel. The number density of total inclusions generally decreases during the refining process, except for Ti and Ca addition. The major inclusions identified were CaO-Al2O3-SiO2-(MgO)-TiOx and CaO-Al2O3-SiO2. These inclusions originate from the combination of CaO-SiO2-(MgO) in refining slag or refractory and deoxidization product Al2O3 and TiO2. With the refining process and Ca addition, the composition of these inclusions changes, resulting in the promotion of intragranular acicular ferrite.
Article
Materials Science, Multidisciplinary
Huaizhuang Luan, Jie Chen, Rutie Liu, Xiang Xiong, Fangping Ouyang, Junhao Yang
Summary: Pre-sintered Fe-WC-Mo2C-Cr3C2-VC-C alloy was studied for its microstructure and evolution of internal pores during the exhaust process. The gas produced by deoxidation significantly affected the densification process, resulting in expansion and shrinkage of the pre-sintered sample. The oxygen content was significantly reduced after the carbothermal reaction.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2022)
Article
Materials Science, Multidisciplinary
Shen-yang Song, Jing Li, Wei Yan
Summary: The mechanism of carryover slag on steel during tapping was investigated, and the major reaction equations were confirmed. It was found that the increase of carryover slag amount led to a decrease in sulfur distribution but an increase in the number of inclusions.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2022)
Article
Metallurgy & Metallurgical Engineering
Ming Li, Huajie Wu, Yanhui Sun
Summary: The study showed that steel deoxidized using Zr-Ti had lower inclusion densities and more globular inclusions compared to steel deoxidized using Al. Zr-Ti-killed steel had smaller grain diameters, higher impact toughness, and higher yield strength than Al-killed steel. The use of Zr-Ti deoxidizer positively affected the ductility of the steel.
IRONMAKING & STEELMAKING
(2022)
Article
Chemistry, Physical
Taeheon Kim, Jae-Won Lim
Summary: Ca vapor deoxidation is important for ensuring the quality of Ti and its alloys by reducing oxygen content and improving surface properties. It results in the formation of Ca oxide layer and increased surface roughness, which further promotes oxygen diffusion and reactions with Ti/Al elements.
APPLIED SURFACE SCIENCE
(2022)
Article
Engineering, Environmental
Dan Yu, Fei Liu, Changdong Zou, Xiao Yang
Summary: Shortage of soluble Fe in seawater can limit the growth of benthic seaweeds. This study proposes the use of steelmaking slag and municipal green wastes as a cost-effective method to provide Fe for seaweeds. By adding tangerine peel, which contains flavonoids, to the mixture of slag and green wastes, the release of Fe was significantly improved. The formation of stable flavonoid-Fe (II) chelates changes the thermodynamic property of Fe(II) in water, promoting its release from slag. These results demonstrate the feasibility of developing a technology for Fe supply in seawater.
RESOURCES CONSERVATION AND RECYCLING
(2023)
Article
Engineering, Chemical
Viktor Udachin, Lienhard Wegewitz, Maik Szafarska, Sebastian Dahle, Rene Gustus, Wolfgang Maus-Friedrichs
Summary: This study investigates the reduction of natively oxidized iron surfaces using a dielectric barrier discharge plasma in an Ar/H-2 atmosphere at atmospheric pressure. It is found that the plasma reduction efficiency at 200℃ and 300℃ is approximately 88% and 91% respectively, and the plasma-thermal reduction method is more effective than the thermal reduction method.
PLASMA CHEMISTRY AND PLASMA PROCESSING
(2023)
Article
Materials Science, Multidisciplinary
Hidehiro Sekimoto, Kenta Sato
Summary: The study proposed two fabrication processes for titanium films and plates utilizing the interface between liquid rare-earth metals and molten salts, and successfully demonstrated the fabrication of a 40-mu m-thick titanium film.
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Hadeel Saad, F. A. Nour El-Dien, Nadia E. A. El-Gamel, Ahmed S. Abo Dena
Summary: Water contamination is a serious global issue due to the depletion of water resources suitable for drinking and agriculture. Researchers have developed a magnetic adsorbent nanomaterial for removing the anionic dye bromocresol green from wastewater. The adsorbent has high adsorption capacity and can be easily removed using a strong magnetic field.
Article
Metallurgy & Metallurgical Engineering
Katsuyoshi Okumoto, Kengo Kato, Hideki Ono, Yoshihiko Higuchi
Summary: The demand for cleanliness of high chromium steel is increasing due to the formation of inclusions such as alumina and spinel in the steel refining process. The stability of MgO in high chromium steel is higher compared to plain steel, and the interaction between chromium and magnesium plays a role in shifting the boundary of stable conditions of inclusions. The variations of inclusions in molten Fe-Cr steel can be explained by considering the stable conditions of MgO and MgO center dot Al2O3.
ISIJ INTERNATIONAL
(2021)
Article
Metallurgy & Metallurgical Engineering
X. Wen, M. Shevchenko, E. Jak
Summary: The phase equilibria of the PbO-CuO0.5 and PbO-CuO0.5-FeO1.5 slag systems in equilibrium with solid metallic copper and/or liquid metallic lead-copper alloy were studied. The compositions in the liquid slag, solid oxide, and metallic phases were directly measured. Phase equilibria data on several primary phases were obtained, and it was discovered that the copper plumbite phase melted incongruently contradicting previous studies.
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
(2023)
Article
Materials Science, Ceramics
Milena Ribeiro Gomes, Tim Leber, Tobias Tillmann, Dorothea Kenn, Daniela Gavagnin, Thorsten Tonnesen, Jesus Gonzalez-Julian
Summary: The iron and steelmaking industry accounts for 7-9% of global anthropogenic CO2 emissions. Efforts are being made to reduce these emissions, and hydrogen is emerging as a key solution. Hydrogen is projected to replace reducing agents in the direct reduction processes and can be used as a more sustainable fuel in industrial furnaces. However, the effects of hydrogen exposure on refractory lining are not fully understood.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2024)