4.3 Article

New Thermally Stable Poly(Ester-Imide)s Containing Phenoxymethyl Moieties as Flexible Groups in the Main Chain: Synthesis and Characterization

Journal

INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS
Volume 60, Issue 8, Pages 505-517

Publisher

TAYLOR & FRANCIS AS
DOI: 10.1080/00914037.2010.531817

Keywords

flexible group; high performance polymers; poly(ester-imide)s; thermal properties

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Several new poly(ester-imide)s were prepared by direct polycondensation reaction of 1,1-bis[4-(trimellitimido)phenoxy]methane 6 with various aromatic diols 7a-f in a system of tosyl chloride (TsCl), pyridine (Py), and N,N-dimethylformamide (DMF). The reactions with TsCl were significantly promoted by controlling alcoholysis with diols, in the presence of catalytic amounts of DMF, to give a series of poly(ester-imide)s. The resulted polymers were characterized by FTIR and 1H-NMR spectroscopy. Also, thermal properties of the PEIs 8a-f were investigated using thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC).

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