4.7 Article

The effect of particle size on acid mine drainage generation: Kinetic column tests

Journal

MINERALS ENGINEERING
Volume 76, Issue -, Pages 154-167

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.mineng.2014.10.002

Keywords

Acid mine drainage; Environmental pollution; Kinetic column test; Particle size

Funding

  1. Mineral Research & Exploration General Directorate (MTA) [2012-37-14-01-9]

Ask authors/readers for more resources

The rate of acid mine drainage (AMD) generation is directly proportional to the surface area and so to the particle size distribution of acid-forming minerals exposed to oxidation. Materials in various particle sizes are subject to weathering processes at field condition; however, the particle size dependent oxidation rate has not been investigated for understanding entire geochemical behavior at a mining site. Therefore, a comprehensive research program was aimed to investigate the effect of particle size on pH variation and acid mine drainage generation using kinetic column tests, and then to find convenient methodologies for upscaling laboratory-based results to the field condition. For this purpose, ore samples collected from Murgul Damar open-pit mining were grinded in three different particle size distributions that are coarse (minus 22.5 mm), medium (minus 3.35 mm) and fine (minus 0.625 mm) sizes, 34 columns were designed in different dimensions for kinetic column tests. It was found that the cumulative concentration of the many constituents measured from medium particles (minus 3.35 mm) are higher than coarser samples due to decreasing specific surface area with increasing particle size. Similarly, because of decreasing of hydraulic conductivity with increasing the fine content, the cumulative concentration of constituents measured from medium particles (minus 3.35 mm) are also higher than finer particles (minus 0.625 mm). Based on statistical and analytical analyses of the results of kinetic column tests, the time required to initiate acid formation at field condition varied between 489 and 1002 days depending on particle size distribution. In addition, considering the effect of particle size and the results of related statistical analysis, main oxidation (SO42-) and neutralization (Ca2+, Mg2+, Mn2+ etc.) products were also successfully upscaled to the field condition. (C) 2014 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Engineering, Environmental

Evaluation of micro-structural damage caused by needle penetration testing

D. J. M. Ngan-Tillard, H. K. Engin, W. Verwaal, A. Mulder, R. Ulusay, Z. A. Erguler

BULLETIN OF ENGINEERING GEOLOGY AND THE ENVIRONMENT (2012)

Article Engineering, Geological

Relative contribution of various climatic processes in disintegration of clay-bearing rocks

Z. A. Erguler, A. Shakoor

ENGINEERING GEOLOGY (2009)

Article Engineering, Geological

Field-based experimental determination of the weathering rates of the Cappadocian tuffs

Zeynal Abiddin Erguler

ENGINEERING GEOLOGY (2009)

Article Engineering, Environmental

Quantification of Fragment Size Distribution of Clay-Bearing Rocks after Slake Durability Testing

Zeynal Abiddin Erguler, Abdul Shakoor

ENVIRONMENTAL & ENGINEERING GEOSCIENCE (2009)

Article Engineering, Geological

Water-induced variations in mechanical properties of clay-bearing rocks

Z. A. Erguler, R. Ulusay

INTERNATIONAL JOURNAL OF ROCK MECHANICS AND MINING SCIENCES (2009)

Article Engineering, Chemical

The effect of column dimensions and particle size on the results of kinetic column test used for acid mine drainage (AMD) prediction

Guzide Kalyoncu Erguler, Zeynal Abiddin Erguler, Hamdi Akcakoca, Ali Ucar

MINERALS ENGINEERING (2014)

Article Engineering, Geological

ISRM Suggested Method for the Needle Penetration Test

Resat Ulusay, Oemer Aydan, Zeynal A. Erguler, Dominique J. M. Ngan-Tillard, Takafumi Seiki, Wim Verwaal, Yasuhito Sasaki, Akira Sato

ROCK MECHANICS AND ROCK ENGINEERING (2014)

Article Geosciences, Multidisciplinary

Assessment of design parameters and the slope stability analysis of weak clay-bearing rock masses and associated spoil piles at Tuncbilek basin

Zeynal Abiddin Erguler, Huseyin Karakus, I. Goktay Ediz, Cem Sensogut

ARABIAN JOURNAL OF GEOSCIENCES (2020)

Article Geosciences, Multidisciplinary

The evaluation of acid mine drainage by kinetic procedures and empirical models for field scale behaviour

Guzide Kalyoncu Erguler, Zeynal Abiddin Erguler

ARABIAN JOURNAL OF GEOSCIENCES (2020)

Article Engineering, Geological

The effect of initial water content on the swelling pressure of soils

Ali Samet Ongen, Zeynal Abiddin Erguler

Summary: Swelling soils pose a worldwide problem for engineering structures and cause serious damage. The water content fluctuation is a crucial factor that leads to soil swelling pressure, especially in arid and semi-arid regions. This study focuses on investigating the effect of variations in initial water content on soil swelling behavior. The results show a statistically significant linear relationship between initial water content and swelling pressure, with predictive empirical models obtained. Additionally, a new approach called swelling pressure designation (SPD) is recommended for predicting the swelling pressure of soils with any water content.

QUARTERLY JOURNAL OF ENGINEERING GEOLOGY AND HYDROGEOLOGY (2022)

Article Environmental Sciences

Assessment of environmental and engineering geological problems for the possible re-use of an abandoned rock-hewn settlement in Urgup (Cappadocia), Turkey

Resat Ulusay, Candan Gokceoglu, Tamer Topal, Harun Sonmez, Ergun Tuncay, Zeynal Abiddin Erguler, Ozgu Kasmer

ENVIRONMENTAL GEOLOGY (2006)

Article Engineering, Environmental

Swelling properties of Ankara (Turkey) clay with carbonate concretions

E Avsar, R Ulusay, ZA Erguler

ENVIRONMENTAL & ENGINEERING GEOSCIENCE (2005)

Article Engineering, Chemical

Novel technique for the preparation and analysis of powder-based polished sections by automated optical mineralogy: Part 2-Use of deep learning approach for transparent mineral detection

Benjamin De Castro, Mostafa Benzaazoua, Soumali Roychowdhury, Aurelie Chopard, Francis Quintal Lauzon, Benoit Plante

Summary: This study proposes an innovative method using deep learning algorithm and reflected light optical imaging to automatically detect all particles and minerals in acrylic resin polished sections. The experimental results show that this method can accurately detect all mineral particles, including transparent minerals, under reflected light optical microscopy, and provide unbiased mineralogical quantification.

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

Effect of magnetic stirring on microstructure of Co deposit in electrowinning

Qiushi Song, Xinyu Du, Changlu Shan, Hongwei Xie, Zhiqiang Ning, Kai Yu

Summary: This study investigated the effect of magnetic stirring on the microstructure of Co deposits during electrowinning in a chloride solution. It was found that magnetic stirring effectively reduced the negative influence of H2 bubbles on the structure of Co deposits and changed their nucleation and growth behavior, resulting in the preparation of high-quality columnar Co crystals.

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

Efficient extraction of platinum(IV) using tertiary-amine groups functionalized thiacalix[4]arene as extractant

Tao Ge, Xiaowei Zhou, Liang Xu, Yan Sun, Cheng Yang, Yongpan Tian, Zhuo Zhao

Summary: In this study, the extraction performance and complexation mechanism of p-di-ethyl-amino-methylthiacalix[4]arene (L) towards Pt(IV) were investigated. The results indicated that L had excellent complexation ability towards Pt(IV) and could selectively extract it from a solution containing multiple competing ions.

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

Study on segregation-impacted hindered settling of fine copper tailings using a modified Kynch's approach

Yuan Li, Dirk van Zyl

Summary: This paper presents a modified Kynch's approach to explain the hindered settling behavior of suspensions impacted by segregation. The experimental data and predicted results confirm the effectiveness of the proposed method.

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

Ball Milling-Enabled mechanochemical reduction of Cr(VI) using sponge iron over an extensive pH range

Yi Fang, Aurora Robledo-Cabrera, Changsheng Peng, Shan Huang, Qi Xiao, Alejandro Lopez-Valdivieso

Summary: With the assistance of mechanical ball milling, the partially oxidized micro-sponge iron (micro-Fe0@Fe2O3) achieves significantly improved removal of Cr(VI) across a broad pH range. Mechanical force eliminates the surface oxide layer and exposes the Fe0 core, leading to sustained reduction of Cr(VI). The efficiency of micro-Fe0@Fe2O3 is strongly influenced by dissolved oxygen, with higher DO resulting in the generation of stable reductant Fe(II) under acidic conditions, while DO consumption hinders the reduction of Cr(VI) under alkaline conditions due to increased pH. Parameters of ball milling operation, especially rotation speed, have a significant impact on the removal of Cr(VI).

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

Flocculating fine cuttings particles suspended within partially hydrolysed polyacrylamide (PHPA) solutions used as drilling fluids in mineral exploration

Alton F. Grabsch, Phillip D. Fawell, Michael G. Davies

Summary: High molecular weight partially hydrolysed polyacrylamide (PHPA) is commonly used in mineral exploration drilling to increase fluid viscosity and help maintain the suspension of fine particles. However, clarifying these suspensions can be difficult, and previous studies have found that anionic flocculants are ineffective. This study confirmed that nonionic flocculants can successfully aggregate the particles, indicating that the charged tails of adsorbed PHPA prevent anionic flocculants from accessing the particle surfaces.

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

Particle-based characterization and process modeling to comprehend the behavior of iron ores in drum-type wet low-intensity magnetic separation

J. S. Guiral-Vega, L. Perez-Barnuevo, J. Bouchard, A. Ure, E. Poulin, C. Du Breuil

Summary: This paper introduces an approach that combines particle properties and process modeling to describe the behavior of iron ore in a laboratory-scale drum-type magnetic separator. Early information on iron ore processing behavior can be obtained through laboratory testing, automated mineralogy analysis, and process modeling.

MINERALS ENGINEERING (2024)

Review Engineering, Chemical

Coarse particle flotation: A review

Sayed Janishar Anzoom, Ghislain Bournival, Seher Ata

Summary: This review discusses the benefits and challenges of coarse particle flotation, as well as recent developments in improving the process. Coarse particle flotation has various applications and offers advantages in technical, economic, and sustainability aspects. However, it also faces challenges such as particle detachment, transfer between phases, and persistence in the froth phase. Technological advancements, such as fluidized-bed flotation and processes enhancing bubble-particle attachment, have shown promising results in efficiently recovering larger particles.

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

The combination of calcium hypochlorite and fulvic acid as an efficient arsenopyrite depressant in Cu-As separation

Yimei Xiao, Jinchan Feng, Bingqiao Yang, Huihua Luo, Fang Zhou

Summary: In this study, the use of fulvic acid as a depressant for the flotation separation of chalcopyrite from arsenopyrite was investigated. It was found that fulvic acid strongly depressed arsenopyrite while having little influence on chalcopyrite flotation. The addition of calcium hypochlorite facilitated the adsorption of fulvic acid on arsenopyrite surface.

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

Molecular-level study of hydrophobic interactions during low-rank coal particle-bubble attachment

Bo Hao, Minqiang Fan

Summary: Particle-bubble attachment is crucial in coal and mineral flotation processes. In this study, the attachment process of low-rank coal particles to the bubble surface was simulated, revealing the important role of water film rupture in particle attachment.

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

Study on productivity of eccentric roll crusher based on theory and experiment

Shuwei Wu, Shuai Wang, Guoqiang Wang, Longfei Fan, Jianbo Guo, Zhengbin Liu, Haoyan Zhang, Wei Guan, Yukuan Wang, Yewei Wu

Summary: This study analyzes the motion mode of eccentric roller crushers and proposes a calculation method for productivity. Through laboratory experiments, the results indicate that the proposed method can effectively estimate the productivity of eccentric roll crushers.

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

The effects of indigenous microorganisms and water treatment with ion exchange resin on Cu-Ni flotation performance

Hanna Miettinen, Malin Bomberg, Ozlem Bicak, Zafir Ekmekci, Paivi Kinnunen

Summary: Mineral processing requires large amounts of water, and reducing water consumption through recirculation and closing water loops is important. However, this can lead to the accumulation of contaminants in the process water, which can negatively affect the process performance. In this study, the impact of microorganisms on flotation performance was investigated, and ion exchange was evaluated for removing dissolved sulfur species and microorganisms from water. The results showed that adding microorganisms had a positive effect on flotation selectivity, especially for nickel. Different water types, process water and final tailings water, behaved slightly differently. Ion exchange proved to be effective in removing sulfur species and microorganisms, and dissolved air flotation was a successful pretreatment for ion exchange in removing microorganisms.

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

Ultrasonic pretreatment for enhancing flotation separation of elemental sulfur and silver-bearing lead minerals from an oxidative pressure leaching residue of zinc sulfide

Canneng Chen, Song Zhang, Quanjun Liu, Luzheng Chen, Yongjun Xian, Yijie Wang

Summary: This study introduces the use of ultrasonic pretreatment to enhance the flotation separation of elemental sulfur and silver-bearing lead minerals from ultrafine residue. The results show that ultrasonic pretreatment effectively liberates associated sulfur and improves the separation of sulfur and silver-bearing lead minerals. Under optimized conditions, ultrasonic pretreatment significantly improves the recovery and grade of sulfur in the concentrate, as well as the recovery of lead and silver in the tailings.

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

Stress-based approach for predicting and improving large-scale HIG mill performance

Genzhuang Li, Fisher Wang, Bern Klein, Michael Deal, Aaron Wright, Hector Mezquita

Summary: This paper presents a stress-based approach for predicting and improving large-scale HIG mill performance through experimental testing and model calibration.

MINERALS ENGINEERING (2024)

Article Engineering, Chemical

Experimental and molecular dynamics simulation study on DDA/DDTC mixed collector co-adsorption on sulfidized smithsonite surfaces

Runpeng Liao, Shuming Wen, Jian Liu, Shaojun Bai, Qicheng Feng

Summary: This study demonstrates that the use of a DDA/DDTC mixed collector system can significantly improve the flotation performance of smithsonite. The synergistic effect between DDA and DDTC is confirmed, and the mixed collector system contributes to a decrease in solution surface tension. The use of FT-IR and XPS confirms the simultaneous physisorption and chemisorption of DDA and DDTC on the smithsonite surface, and contact angle measurements show that the mixed collector effectively enhances the hydrophobicity of smithsonite. Molecular dynamics simulations reveal the multilayer adsorption of DDTC and DDA on the smithsonite surface, with DDTC promoting the adsorption of DDA.

MINERALS ENGINEERING (2024)