Journal
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
Volume 279, Issue 2-3, Pages 147-155Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.ijms.2008.10.022
Keywords
Multipole ion trap; 22-Pole trap; Numerical simulation; Ion temperature; Buffer gas cooling
Funding
- Deutsche Forschungsgemeinschaft (DFG) [SFB494]
- European QUASAAR network
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This work presents numerical simulations of the kinetic temperature of ions stored in a linear multipole RF trap (22-pole trap) under the influence of elastic collisions with buffer gas. Small distortions, as for example those caused by the trapping endelectrodes, space charges, or noise on the RF signal, can be included into the model. The dependence of the resultant ion temperature on all storage parameters is systematically investigated. In particular, it is found that an unfavourable ion-to-neutral mass ratio and high trapping endelectrode voltages can lead to ion heating far above the trap temperature. (C) 2008 Elsevier B.V. All rights reserved.
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