Article
Chemistry, Analytical
Mengmeng Du, Tiemei Li, Wenjuan Zhu, Yueyue Shi, Xinxin Chen, Chen Wang, Jing Fan
Summary: A new liquid-liquid microextraction strategy was developed for the quantitative determination of trace triclosan, using high performance liquid chromatography, showing to be effective and practical.
MICROCHEMICAL JOURNAL
(2022)
Article
Pharmacology & Pharmacy
Yingzheng Zhao, Jiawei Xu, Jianxun Shangguan, Hanxiao Pan, Kaili Lu, Sunkuan Hu, Helin Xu
Summary: An in-situ oil-based gel has been developed as a rectal delivery vehicle for hydrophobic therapeutics in patients with ulcerative colitis. The gel quickly transforms into a semi-solid state upon contact with colonic fluids, forming a protective barrier on the inflamed colon mucosa and improving clinical symptoms of ulcerative colitis.
INTERNATIONAL JOURNAL OF PHARMACEUTICS
(2023)
Article
Chemistry, Multidisciplinary
Wei Liu, Claudius Lupfer, Avik Samanta, Aritra Sarkar, Andreas Walther
Summary: Synthetic cell models help us understand living cells and the origin of life by studying the crowded interiors and the formation of secondary structures. The study introduces a crowded all-DNA protocell with a temperature-switchable DNA b-polymer block copolymer, which can form artificial organelle structures through thermoreversible phase segregation. The formation of hydrophobic compartments enhances the reactivity of bimolecular reactions. This study provides insights into phase segregation and the formation of organelles and microreactors in response to environmental stress.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Analytical
Abolghasem Jouyban, Mir Ali Farajzadeh, Mohammad Reza Afshar Mogaddam, Fariba Khodadadeian, Mahboob Nemati, Maryam Khoubnasabjafari
Summary: A new microextraction procedure based on liquid-liquid microextraction using a deep eutectic solvent accelerated by microwave radiations was developed for the extraction of three beta-blockers from plasma samples. Low limits of detection, high extraction recovery, and good precision were achieved, making it an effective method for determination of the beta-blockers' concentrations in plasma samples.
MICROCHEMICAL JOURNAL
(2021)
Article
Polymer Science
Nikolay A. A. Belov, Aleksandr Yu. Alentiev, Dmitrii S. S. Pashkevich, Fedor A. A. Voroshilov, Edgar S. S. Dvilis, Roman Yu. Nikiforov, Sergey V. V. Chirkov, Daria A. A. Syrtsova, Julia V. V. Kostina, Igor I. I. Ponomarev, Igor P. P. Asanov, Yulia G. G. Bogdanova
Summary: In this study, a direct fluorination technique was used to treat the surface of PIM-1 films, and various instrumental techniques were employed to analyze the fluorinated samples. The results showed that fluorination mainly occurred in methylene- and methyl-groups, and cyano-groups, aromatic hydrogens, and the aromatic structure of PIM-1 were relatively stable under the fluorination conditions. Additionally, the fluorination time and film depth had an impact on the fluorine concentration and surface energy.
Article
Anatomy & Morphology
Xin Chen, Liyi Tan, Siyu Cheng, Yang Liu, Mengqin Zhu
Summary: This paper presents a real-time high-resolution and comprehensive characterization of Au nanoparticles and nanoparticle clusters using in situ liquid cell scanning electron microscopy (LC-SEM). The technique allows for the visualization of the chemical element distributions, particle stacking structure, and the distribution of molecules on the particle surfaces. Furthermore, liquid droplet growth and particle motions are observed.
MICROSCOPY RESEARCH AND TECHNIQUE
(2023)
Article
Chemistry, Physical
Henry S. Ashbaugh
Summary: By using simulations and theory, researchers have found that the enthalpy and entropy of hydrophobic hydration exhibit minima in supercooled water, which is contrary to traditional beliefs of a monotonically increasing temperature dependence. The shift in heat capacity from negative to positive at a size-dependent reversal temperature marks the enthalpy/entropy minima. A Gaussian fluctuation theory accurately explains this reversal temperature, linking it to water's distinct thermal expansivity and compressibility influenced by its metastable liquid-liquid critical point.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Biotechnology & Applied Microbiology
Thanachai Changcharoen, Thidsanu Apiphatnaphakul, Wasupon Watjanavarreerat, Kitsakorn Locharoenrat
Summary: This study investigates the optical functions of butterfly wing scales and their potential as a photonic sensor. It confirms the presence of metal oxide nanoparticles mixed with nicotine using optical microscopy and spectroscopy. The results show that the absorption intensities of ZnO and TiO2 mixed with nicotine on Danaus genutia are significantly enhanced. The study also suggests that this sensor could be a simple and effective method for the rapid test of ZnO content.
ARTIFICIAL CELLS NANOMEDICINE AND BIOTECHNOLOGY
(2022)
Article
Chemistry, Physical
Rong Ren, Daoping Xiang, Yue Cao, Yuhang Hu
Summary: SiC nanowhiskers were prepared from photovoltaic silicon waste, quartz sand, and coconut fiber, demonstrating a novel, clean, and sustainable method. This approach enables the recycling of valuable resources and high-value utilization of agricultural wastes.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Green & Sustainable Science & Technology
Yuxuan Zhang, Qi Qiao, Usman L. Abbas, Jun Liu, Yi Zheng, Christopher Jones, Qing Shao, Jian Shi
Summary: Solvent innovation is crucial for enhancing the sustainability of chemical processes. Deep eutectic solvents (DESs) have emerged as environmentally friendly alternatives to toxic and volatile solvents. In this study, hydrophobic DESs derived from lignin were synthesized and their physicochemical properties were characterized. The DESs showed promise as green solvents due to their low viscosity and environmentally friendly constituents. Liquid-liquid extraction experiments revealed high extraction efficiency for biofuel fermentation products using specific DES compositions. Molecular dynamic simulations provided insights into the DES molecular interactions and formation mechanism. This work highlights the potential of lignin-derived hydrophobic DESs as sustainable extraction media.
JOURNAL OF CLEANER PRODUCTION
(2023)
Article
Engineering, Environmental
Rong Zhou, Yong Jin, Yupeng Li, Hongyu Jin, Wenhua Zeng, Jiangyang Mei, Yuanqing Liu
Summary: Ionogels with excellent ionic conductivity, thermal stability, and non-volatility have garnered great attention as a promising alternative to hydrogels. In this study, a one-pot in-situ phase separation design strategy is proposed to construct robust hydrophobic ionogels through random copolymerization in a hydrophobic ionic liquid. The resultant ionogels exhibit a dual phase network structure, mechanical robustness, reversible interactions, high ionic conductivity, and various applications.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Materials Science, Multidisciplinary
Inas Issa, Christoph Gammer, Stefan Kolitsch, Anton Hohenwarter, Peter J. Imrich, Reinhard Pippan, Daniel Kiener
Summary: The study reports a Brittle-Ductile Transition in silicon controlled by length scale, leading to a significant increase in fracture toughness. In situ Transmission Electron Microscopy experiments show that below 250 nm, fracture toughness inversely increases with size, accompanied by nucleation and propagation of dislocations at the crack tip. The findings offer new strategies for strengthening and toughening brittle materials through geometric miniaturization.
Article
Biochemistry & Molecular Biology
Zihao Ma, Ying Han, Fuqiong Xu, Xing Wang
Summary: In this study, lignin-based hydrophobic deep eutectic solvents (LHDES) were synthesized via a one-step strategy and used as extraction solvent for the determination of Sudan red dyes. The practicality of LHDES was demonstrated by applying it to the detection of Sudan Red I in real water samples and foodstuffs, with an extraction rate of up to 98.62%. This method provides a simple and effective approach for the determination of Sudan Red in food.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Materials Science, Coatings & Films
Jiru Qin, Xiaorong Zhou, Michele Curioni
Summary: In this study, the growth of oxide during soft and hard anodizing was investigated using in-situ and ex-situ EIS measurements. It was found that in-situ EIS measurements accurately estimated the barrier layer thickness during soft anodizing, but became inaccurate during later stages of growth under hard anodizing conditions. This was attributed to the formation of a gradient in electrolyte composition, which resulted in a rough internal pore morphology.
SURFACE & COATINGS TECHNOLOGY
(2023)
Article
Chemistry, Physical
S. Meenakshi, Kapil Sonkar, Sachin Chugh, Rajesh Badhe, G. S. Kapur, S. S. V. Ramakumar
Summary: Membrane Electrode Assembly (MEA) in a Polymer Electrolyte Membrane Fuel Cell (PEMFC) is crucial for the performance of the fuel cell system. This study investigates the degradation of a stack operated MEA and characterizes it using electrochemical and physical methods. The results show that the MEA assembly decomposes at specific temperatures for the Nafion membrane, carbon-supported catalyst, and carbon-based GDL. The degradation is evidenced by the decrease of electrocatalyst surface area and the migration of catalyst particles.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Optics
R. K. Fakher Alfahed, Ahmed S. Al-Asadi, Hussain Ali Badran, Khalid I. Ajeel
APPLIED PHYSICS B-LASERS AND OPTICS
(2019)
Article
Biochemistry & Molecular Biology
Radislav A. Potyrailo, Jon Dieringer, Victoria Cotero, Yongjae Lee, Steve Go, Matthew Schulmerich, Gunnar Malmquist, Andreas Castan, Klaus Gebauer, Vincent Pizzi
BIOELECTROCHEMISTRY
(2019)
Article
Materials Science, Multidisciplinary
Ahmed S. Al-Asadi, Qusay M. A. Hassan, Amjed F. Abdulkader, Mohammed H. Mohammed, H. Bakr, C. A. Emshary
Article
Physics, Condensed Matter
Mohammed H. Mohammed, Ahmed S. Al-Asadi, Falah H. Hanoon
SUPERLATTICES AND MICROSTRUCTURES
(2019)
Article
Physics, Multidisciplinary
Jabbar H. Jebur, Qusay M. A. Hassan, Mohammed F. Al-Mudhaffer, Ahmed S. Al-Asadi, Rita S. Elias, Bahjat A. Saeed, C. A. Emshary
Article
Materials Science, Multidisciplinary
Qusay M. A. Hassan, H. A. Sultan, Ahmed S. Al-Asadi, Ayat Jawdat Kadhim, Nazar A. Hussein, C. A. Emshary
Article
Physics, Applied
Mahmoud Sh Hussain, Qusay M. A. Hassan, H. A. Sultan, Ahmed S. Al-Asadi, Hani T. Chayed, C. A. Emshary
MODERN PHYSICS LETTERS B
(2019)
Article
Optics
Burak Kadem, R. K. Fakher Alfahed, Ahmed S. Al-Asadi, Hussain A. Badran
Article
Materials Science, Multidisciplinary
Qingchen Shen, Shuai Ma, Zhen Luo, Shun An, Jiaqing He, Ruoxi Zhang, Peng Tao, Chengyi Song, Jianbo Wu, Radislav A. Potyrailo, Tao Deng, Wen Shang
ADVANCED OPTICAL MATERIALS
(2020)
Article
Engineering, Electrical & Electronic
Radislav A. Potyrailo, Steven Go, Daniel Sexton, Xiaxi Lie, Nasr Alkadi, Andrei Kolmakov, Bruce Amm, Richard St-Pierre, Brian Scherer, Majid Nayeri, Guang Wu, Christopher Collazo-Davil, Doug Forman, Chris Calvert, Craig Mack, Philip McConnell
NATURE ELECTRONICS
(2020)
Article
Physics, Condensed Matter
Anwar I. Habeeb, Ahmed S. Al-Asadi
Summary: A hybrid supercapacitor with graphene sheets/vanadium(V) oxide nanoparticles composite electrodes has been developed successfully, showing excellent electrochemical performance. The graphene sheets were obtained through liquid phase exfoliation technique. The composite exhibited a fabulous architecture with porous sphere shapes and rough surfaces, and possessed high capacitance value, energy density, and power density.
SOLID STATE COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
Colm Delaney, Jing Qian, Xia Zhang, Radislav Potyrailo, A. Louise Bradley, Larisa Florea
Summary: Arrays of optically responsive ionogel structures were fabricated using direct laser writing, showing visible color changes in the presence of different solvent vapours to demonstrate their responsive nature. This represents a new departure in photonic structural colouration, with the fabricating structure exhibiting programmable, controllable, and dynamic stimuli response.
JOURNAL OF MATERIALS CHEMISTRY C
(2021)
Article
Biochemical Research Methods
Brian Scherer, Christine Surrette, Hui Li, Peter Torab, Erik Kvam, Craig Galligan, Steven Go, Greg Grossmann, Tyler Hammond, Tammy Johnson, Richard St-Pierre, John R. Nelson, Radislav A. Potyrailo, Tejas Khire, Kuangwen Hsieh, Tza-Huei Wang, Pak Kin Wong, Chris M. Puleo
Summary: Single-molecule and single-cell analysis techniques provide new opportunities for studying heterogeneity within biological samples, with digital assays serving as the foundation for modern bioanalytical tools due to their ability to precisely detect and quantify individual targets. The utility of digital assays can be significantly enhanced by cost-efficient and portable electrical detection capabilities.
Editorial Material
Chemistry, Physical
Helen Clark, Bianca Datta, Leila Deravi, Carlos Fiorentino, Stefano Fornasaro, Mike Hardy, Amanda Holt, Christian Kuttner, Sebastien R. Mouchet, Laura Ospina, Andrew Parnell, Thomas G. Parton, Giuseppe Maria Paterno, Radislav Potyrailo, Alex Qiu, Giselle Rosetta, Franziska Schenk, Lukas Schertel, Doekele Stavenga, Ullrich Steiner, Gea Theodora van de Kerkhof, Bodo Wilts, Ming Xiao
FARADAY DISCUSSIONS
(2020)
Article
Chemistry, Physical
R. A. Potyrailo, J. Brewer, B. Cheng, M. A. Carpenter, N. Houlihan, A. Kolmakov
FARADAY DISCUSSIONS
(2020)