Review
Materials Science, Multidisciplinary
Yike Huang, Yun Zheng, Jianding Li, Xiaozhi Bao, Junpo Guo, Jingjun Shen, Yan Guo, Qi Zhang, Jing Li, Wen Lei, Huaiyu Shao
Summary: The article summarizes the research progress on the use of LiBH4 and Mg(BH4)2 as hydrogen storage materials and solid-state electrolytes, and proposes effective strategies to improve their performances. It discusses the changes in the phase, structure, and thermal properties of Li/Mg-based borohydrides induced by methods such as milling, ion substitution, coordination, adding additives/catalysts, and hydrides. The similarities and differences between the strategies used for the two applications are also discussed. This review provides insights into the future development of Li/Mg-based borohydrides for hydrogen storage and solid-state electrolytes.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Engineering, Environmental
Yongxi Zhang, Yuan Li, Guanjiu Wu, Chenfeng Fan, Lu Zhang, Shumin Han
Summary: Rare earth-Mg-Ni based alloys with increased Mg content show phase transformation and improved stability and hydrogen absorption properties.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Gamze Atalmis, Mehmet Demiralp, Nebi Yelegen, Yuksel Kaplan
Summary: This study investigates the process parameters that affect the improvement of hydrogen storage material properties. The thermal conductivity of the storage materials has been improved to accelerate the hydrogen charge/discharge processes and obtain the required hydrogen at desired flow rates in a short time. The experimental results show that coating the storage material with copper increases heat transfer, reduces the hydrogen charging time, and improves stable discharge time in the metal hydride reactor.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Review
Nanoscience & Nanotechnology
Li Ren, Yinghui Li, Ning Zhang, Zi Li, Xi Lin, Wen Zhu, Chong Lu, Wenjiang Ding, Jianxin Zou
Summary: With the urgent need to find green, low-cost, and high-efficiency energy resources due to the depletion of fossil fuels and global warming, hydrogen has been considered as a potential alternative. However, effective and safe hydrogen storage techniques are now becoming a bottleneck for the hydrogen economy. Magnesium-based hydrogen storage materials have garnered interest due to their high storage capacity, low cost, and excellent reversibility. Nano-structuring has proven to be an effective strategy to enhance the thermodynamic and kinetic properties of these materials.
NANO-MICRO LETTERS
(2023)
Article
Materials Science, Ceramics
A. Al-Ojeery, E. Ibrahim, E. Shalaan, A. Inoue, F. Al-Marzouki
Summary: A nano-porous glassy Zr60Al5Ni30Pd5 skeleton structure alloy was prepared by electrochemical etching treatment, showing enrichment of Ni and Pd elements on the nano-porous surface, leading to enhanced reaction activity and corrosion resistance.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2021)
Article
Energy & Fuels
Xuehong Wu, Maotiao Gao, Kai Wang, Qiangwei Wang, Chuanxiao Cheng, Youjian Zhu, Fangfang Zhang, Qi Zhang
Summary: Paraffin composite phase change materials with graphene nano-platelets (GNPs) and carbon nanotubes (CNTs) showed stable thermal conductivity at room temperature for 20 days and 40 days, respectively. The thermal conductivity of the composites increased the most when the mass fraction of GNPs or CNTs was 5%. The DSC curves of the GNPs/paraffin composites moved forward compared to those of pure paraffin and CNTs/paraffin composites, indicating higher thermal conductivity and more accurate experimental operation procedure.
JOURNAL OF ENERGY STORAGE
(2021)
Review
Chemistry, Physical
Dianchen Feng, Dongsheng Zhou, Zhiyuan Zhao, Tingting Zhai, Zeming Yuan, Hao Sun, Huiping Ren, Yanghuan Zhang
Summary: Mg-based hydrogen storage alloys are attracting attention due to their high storage capacity and reversibility, but their stability and kinetics limit their practical application. Graphene as a catalyst has been studied extensively, showing potential to enhance the performance of Mg-based hydrogen storage alloys.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Multidisciplinary
Yan Li, Hongrui Zhu, Junbo Duan, Youshen Wu, Daocheng Wu
Summary: This study prepared BMPA modified Fe3O4 nanoparticle aggregates with the photoexcited audible sound (PEAS) effect using laser-induced irradiation. The aggregates showed strong PEAS signals under weak laser irradiation and fast heat transfer rate, possibly resulting in the observed audible sound phenomenon.
Article
Energy & Fuels
Xiangyang Liu, Zeyang Kang, Jiahao Zhao, Shaoxuan Huang, Ying Zhang, Maogang He
Summary: Coupling with supercritical power cycle can improve the thermal efficiency of the concentrated solar system. Designing a suitable thermal storage medium is critical to the new coupling system. A new low-cost ternary eutectic salt composed of NaCl, Na2CO3, and Na2SO4 was developed based on phase diagram calculation methods, meeting the requirements for solar energy storage. The designed salt exhibits high specific heat capacity and phase-change enthalpy, as well as a low cost, indicating its good thermal storage capacity.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2023)
Article
Electrochemistry
Emmanuel Boateng, Antony R. Thiruppathi, Chi-Kai Hung, Darren Chow, Deepak Sridhar, Aicheng Chen
Summary: Graphene and its derivatives have the potential to be solid-state candidates for next-generation energy and hydrogen storage technologies. However, materials that meet all targets set by the US Department of Energy have not yet been identified. This review provides an overview of recent developments in functionalized graphene-based nanomaterials for energy and hydrogen storage systems. Various synthetic approaches, effects of functionalization strategies, and recent advances in energy applications are discussed.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Multidisciplinary
Xi Chen, Xuelin Huang, Tong-Yu Shi, Jia-Xin Wang, Xin-Ru Yuan, Hao Huang, Jiahong Wang, Rui He, Xue-Feng Yu
Summary: Triallyl isocyanurate (TAIC) was modified with hydrogen silicone oil to form a shape-stabilized phase change material (PCM) with a three-dimensional network structure. This PCM effectively prevents leakage during phase transition and exhibits excellent thermal and structural stability.
Review
Materials Science, Multidisciplinary
Yaxiong Yang, Xin Zhang, Lingchao Zhang, Wenxuan Zhang, Huifeng Liu, Zhenguo Huang, Limei Yang, Changdong Gu, Wenping Sun, Mingxia Gao, Yongfeng Liu, Hongge Pan
Summary: The storage of hydrogen in a compact, safe and cost-effective manner is crucial for a more sustainable society. Magnesium hydride (MgH2) has attracted attention as a hydrogen carrier but its practical use is limited due to high temperatures and slow kinetics. Catalysis plays a crucial role in enhancing hydrogen cycling kinetics, and research has focused on designing and optimizing catalysts for Mg/MgH2.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Jingjing Guo, Huiyan Zhao, Jing Wang, Ying Liu
Summary: A stable core-shell B12@Ca20C12 cluster with Ih symmetry, featuring a icosahedral Ih-B12 core surrounded by a dodecahedral Ca20C12 shell, has been discovered. This cluster shows excellent stability, with no destruction at high frequencies, and has the ability to store a large amount of hydrogen, making it a potential high-capacity hydrogen storage material.
APPLIED SURFACE SCIENCE
(2023)
Article
Energy & Fuels
Banumathi Munuswamy Swami Punniakodi, Ramalingam Senthil
Summary: This review discusses the effects of different additives on improving the performance of nano-enhanced PCM, which helps address the heat storage issue in solar thermal systems by improving thermal conductivity and maintaining energy storage density.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2022)
Article
Chemistry, Physical
Yichao Xie, Guanjiu Wu, Yuan Li, Yongxi Zhang, Qing Wang, Lu Zhang, Shumin Han
Summary: This study used a low-cost YFe0.85 master alloy to improve the cycling stability of La-Mg-Ni-based hydrogen storage alloys. The prepared alloys showed good cycling stability, higher capacity, and satisfactory kinetics.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Nanoscience & Nanotechnology
Xueqing Yu, Junpo Guo, Bo Li, Jincheng Xu, Peng Gao, Kwan San Hui, Kwun Nam Hui, Huaiyu Shao
Summary: This study successfully synthesized Pt/NixFe LDHs catalysts, demonstrating superior trifunctional electrocatalytic activity and durability for applications in sustainable energy conversion and storage systems such as water-alkali electrolyzers and hybrid sodium-air batteries.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Review
Chemistry, Multidisciplinary
Junpo Guo, Dongqi Dong, Jun Wang, Dan Liu, Xueqing Yu, Yun Zheng, Zhaorui Wen, Wen Lei, Yonghong Deng, Jie Wang, Guo Hong, Huaiyu Shao
Summary: Lithium-ion batteries have been dominated by silicon-based materials as promising alternatives to graphite anodes due to their high theoretical capacities, but face challenges such as volume changes and side reactions. Solutions like preparation methods, structure optimizations, and development of new electrolytes, binders, and separators have been proposed. The introduction of pre-lithiation technology shows potential in improving energy densities and lifetime of Si-based full cells.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Engineering, Environmental
Chunyan Cao, Huilong Dong, Fanghua Liang, Yu Zhang, Wei Zhang, Hailou Wang, Huaiyu Shao, Hongchao Liu, Kai Dong, Yuxin Tang, Yuekun Lai, Mingzheng Ge
Summary: This study proposes an interfacial reinforcement structure design for MoS2-based electrodes, which effectively stabilizes the solid electrolyte interface and enhances electrical conductivity. The use of TiO2 as a mechanical support suppresses reaggregation of MoS2 nanosheets, while carbon coating improves Li ion adsorption and enhances electrode performance.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Materials Science, Multidisciplinary
Cheng Lin, Liuzhang Ouyang, Renzong Hu, Jun Liu, Lichun Yang, Huaiyu Shao, Min Zhu
Summary: The SeP2/C composite synthesized by plasma-assisted milling method shows excellent lithium and sodium storage performances, with fast ion transfer kinetics and volume expansion inhibition mechanism, indicating great potential as a new type of anode material.
PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
Zhenjiang Liu, Haiyan Zhang, Shangshang Zhang, Jiale Yu, Shengkai Li, Huaiyu Shao, Yudie Tang, Daofeng Wen, Zhenghui Li
Summary: The well-dispersed MoP nanoparticles confined in a carbon nanofiber skeleton with the introduction of titania exhibited superior cycling stability and performance. This design provides a simple and efficient way for the preparation of phosphides.
MATERIALS RESEARCH LETTERS
(2021)
Article
Chemistry, Inorganic & Nuclear
Yongyang Zhu, Hao Zhong, Liuzhang Ouyang, Jiangwen Liu, Hui Wang, Huaiyu Shao, Min Zhu
Summary: In this study, an energy-saving and cost-efficient process for the (re)generation of NaBH4 was reported by ball milling hydrated borax with a Mg-Al alloy under ambient conditions. The introduction of abundant and readily available Al can increase air stability of the reducing agent, and a high yield up to 85.2% could be achieved by using Mg17Al12 due to its hardness and brittleness.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Energy & Fuels
Jianding Li, Yun Zheng, Xiaozhi Bao, Liqing He, Haiyan Zhang, Yuxin Tang, Huaiyu Shao
Summary: In this study, a honeycombed ZnO@N-doped carbon composite with improved performances was successfully prepared. The composite exhibits excellent energy storage properties in both lithium-ion batteries and sodium-ion batteries.
Review
Materials Science, Multidisciplinary
Dan Chan, Yunfei Liu, You Fan, Huibo Wang, Shi Chen, Tianwei Hao, Heng Li, Zhengshuai Bai, Huaiyu Shao, Guichuan Xing, Yanyan Zhang, Yuxin Tang
Summary: Separators or electrolyte membranes are crucial for ion transport in rechargeable batteries, and the increasing applications of battery systems for diverse working environments pose new challenges. The design of advanced battery membranes with high thermal stability, mechanical strength, and voltage tolerance is highly desirable. Janus separators or electrolyte membranes, with distinct chemical/physical properties, offer promising solutions through rational design to overcome these challenges. This review provides an overview of the current challenges, state-of-the-art developments, and future potential directions of Janus membranes for advanced battery applications, aiming to guide the development of functional separators or electrolyte membranes.
ENERGY & ENVIRONMENTAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ping Liang, Yihao Zheng, Fengru Liu, Huaiyu Shao, Chaofan Hu, Bingfu Lei, Xuejie Zhang, Yingliang Liu, Jianle Zhuang, Xingcai Zhang
Summary: In this study, a new kind of carbon dot-based luminescent material was successfully synthesized and combined with a YF3 substrate to achieve multimode luminescence and high stability. This material exhibited blue fluorescence, green room-temperature phosphorescence, and upconversion luminescence under excitation of ultraviolet and near-infrared light. The stability of the material was greatly improved due to the strong protection of the YF3 substrate. This research provides a general synthesis strategy for achieving multimode luminescence and high stability of CD-based luminescent materials and opens up new opportunities for their applications in advanced anti-counterfeiting and information encryption.
Review
Chemistry, Inorganic & Nuclear
Yujung Chen, Peisen Liao, Kehan Jin, Yun Zheng, Huaiyu Shao, Guangqin Li
Summary: This paper presents the application of metal-organic frameworks (MOFs) in electrocatalytic water splitting. MOFs, as a novel porous material, serve as valuable catalysts for efficient water electrolysis. The paper explains the mechanism of water splitting and summarizes the synthesis and performance enhancement strategies for MOFs and their derivatives. The current challenges and future research directions are also discussed.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Materials Science, Multidisciplinary
Huajun Zhao, Jun Wang, Huaiyu Shao, Kang Xu, Yonghong Deng
Summary: This study investigates the sources and mechanisms of gas generation in lithium-metal batteries using in situ differential electrochemical mass spectrometry, and proposes mechanisms for electrolyte additives to mitigate these irreversible reactions.
ENERGY & ENVIRONMENTAL MATERIALS
(2022)
Article
Chemistry, Physical
Xiaozhi Bao, Tian Sun, Yan Liu, Chuan Xu, Weiliang Ma, Junpo Guo, Yun Zheng, Shivananju Bannur Nanjunda, Huating Liu, Zongyu Huang, Shaojuan Li, Shenghuang Lin, Guichuan Xing, Wencai Ren, Qiaoliang Bao, Huaiyu Shao
Summary: Photodetectors based on the graphene-Mo2C heterostructure exhibit high responsivity over a broad wavelength range from visible to infrared, due to enhanced light absorption and minimal resistance for photoexcited carriers in both materials.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Review
Chemistry, Multidisciplinary
Zou Junyan, Zhang Yanyan, Chen Shi, Shao Huaiyu, Tang Yuxin
Summary: This article reviews the research progress in surface modification of electrodes and electrolytes of all-solid-state lithium batteries, as well as discusses classic methods of improving interface contact and reducing interface resistance. Based on traditional methods, new surface modification technologies will provide new ideas for enhancing the performance of all-solid-state lithium batteries in the future.
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
(2021)
Article
Materials Science, Multidisciplinary
D. F. Wu, L. Z. Ouyang, J. M. Huang, J. W. Liu, H. Wang, X. S. Yang, H. Shao, M. Zhu
Summary: The hydrolysis kinetics of Zr(BH4)(4)•8NH3 can be enhanced by changing hydrolysis solution and tuning the ammonia coordination number. The hydrolysis properties were significantly improved in MgCl2 and CoCl2 solutions. Tuning ammonia coordination number is an effective way to control the hydrolysis properties of Zr(BH4)(4)•xNH3 (x < 8).
PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
Bannur N. Shivananju, Lu Zhou, Yuefeng Yin, Wenzhi Yu, Babar Shabbir, Haoran Mu, Xiaozhi Bao, Yiqiu Zhang, Sun Tian, Qingdong Ou, Shaojuan Li, Mohammad M. Hossain, Yupeng Zhang, Huaiyu Shao, Guichuan Xing, Nikhil V. Medhekar, Chang-Ming Li, Jian Liu, Qiaoliang Bao
Summary: The study presents a novel approach using a photonic integrated graphene-optofluidic device to monitor DNA structural changes.
