Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 38, Issue 11, Pages 4508-4512Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2013.01.196
Keywords
Ni-MgO-Ce0.8Zr0.2O2; CO2; CH4; Intimate interaction
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Funding
- Samsung Advanced Institute of Technology (SAIT), Samsung Electronics Co. Ltd.
- Basic Science Research Program through the National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology [2010-0002521]
- National Research Foundation of Korea [2010-0002521] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Ni-Ce0.8Zr0.2O2 and Ni-MgO-Ce0.8Zr0.2O2 catalysts were investigated for H-2 production from CO2 reforming of CH4 reaction at a very high gas hourly space velocity of 480,000 h(-1) Ni-MgO-Ce0.8Zr0.2O2 exhibited higher catalytic activity and stability (CH4 conversion >95% at 800 degrees C for 200 h). The outstanding catalytic performance is mainly due to the basic nature of MgO and an intimate interaction between Ni and MgO. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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