Synthesis and electrical properties of Al-doped Sr2MgMoO6-δ as an anode material for solid oxide fuel cells

Aluminum doped Sr2MgMoO6-delta (SMMO) was synthesized via citrate-nitrate route. Dense samples of Sr2Mg1-xAlxMoO6-delta (0 <= x <= 0.05) were prepared by sintering the pellets at 1500 degrees C in air and then reducing at 1300 degrees C in 5%H-2/Ar. The electrical conductivity strongly depended on the preparing atmosphere, samples reduced in 5%H-2/Ar exhibited higher conductivity than those unreduced. Al-doping increased remarkably the electrical conductivity of Sr2Mg1-xAlxMoO6-delta. The reduced samples displayed a relatively stable electrical conductivity under oxygen partial pressure (Po-2) from 10(-19) to 10(-14) atm at 800 degrees C, and exhibited an excellent recoverability in electrical conductivity when cycled in alternative air and 5%H2/Ar atmospheres. Sr2Mg0.95Al0.05MoO6-delta material showed a good chemical compatibility with LSGM and GDC electrolytes below 1000 degrees C, while there was an obvious reaction with YSZ. Al-doping improves the anode performance of SMMO in half-cell of Pt/Sr2Mg1-xAlxMoO6-delta vertical bar GDC vertical bar Pt in H-2 fuel. The present results demonstrate that Sr2Mg1-xAlxMoO6-delta is a potential anode material for intermediate temperature-Solid Oxide Fuel Cells (IT-SOFCs). Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.