4.7 Article

Exergy analysis on the simulation of a small-scale hydrogen liquefaction test rig with a multi-component refrigerant refrigeration system

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 35, Issue 15, Pages 8030-8042

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2010.05.049

Keywords

Exergy efficiency; Hydrogen liquefier; Hydrogen liquefaction; Cryogenic process; Refrigeration

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This study investigates the simulation of a proposed small-scale laboratory liquid hydrogen plant with a new, innovative multi-component refrigerant (MR) refrigeration system. The simulated test rig was capable of liquefying a feed of 2 kg/h of normal hydrogen gas at 21 bar and 25 degrees C to normal liquid hydrogen at 2 bar and 250 degrees C. The simulated power consumption for pre-cooling the hydrogen from 25 degrees C to -198 degrees C with this new MR cycle was 2.07 kWh/kg(GH2) from the ideal minimum of 0.7755 kWh per kilogram of feed hydrogen gas. This was the lowest power consumption available when compared to today's conventional hydrogen liquefaction cycles, which are approximately 4.00 kWh/kg(GH2). Hence, the MR cycle's exergy efficiency was 38.3%. Exergy analysis of the test rig's cycle, which is required to find the losses and optimize the proposed MR system, was evaluated for each component using the simulation data. It was found that the majority of the losses were from the compressors, heat exchangers, and expansion valves. Suggestions are provided for how to reduce exergy in each component in order to reduce the exergy loss. Finally, further improvements for better efficiency of the test rig are explained to assist in the design of a future large-scale hydrogen liquefaction plant. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.

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