Review
Chemistry, Physical
Changhyo Sun, Chenxi Wang, Taejun Ha, Joonho Lee, Jae-Hyeok Shim, Yunseok Kim
Summary: Increasing demand for renewable and clean energy due to environmental pollution and energy consumption has led to increased attention towards hydrogen storage materials. These materials have high safety and large volumetric density for hydrogen storage, making them suitable for large-capacity and long-term energy storage capability. Various characterization techniques have been used to understand the mechanisms of hydrogen absorption and desorption, with a recent focus on local characterization techniques to study surface and nanostructural interface effects. This article reviews the application of these characterization techniques in exploring hydrogen storage materials.
Review
Chemistry, Physical
N. A. Ali, N. A. Sazelee, M. Ismail
Summary: Metal hydrides and complex hydrides are the most convenient method for hydrogen storage, offering high hydrogen capacity, but facing challenges of high operating temperature and low reversibility.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Mahvash Afzal, Nandlal Gupta, Aashish Mallik, K. S. Vishnulal, Pratibha Sharma
Summary: This study continues the computational analysis of a reactor with hexagonal honeycomb-based heat transfer enhancements, investigating the performance of a metal alloy and the reactor experimentally. It determines the gravimetric capacity and reaction kinetics of the alloy La0.9Ce0.1Ni5, while also exploring the impact of operating conditions on reactor performance. Additionally, evaporative cooling is tested for the first time as a heat removal technique for metal hydride based hydrogen storage reactors and found to significantly improve heat transfer.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Sadhasivam Thangarasu, Gowthami Palanisamy, Yeong Min Im, Tae Hwan Oh
Summary: Hydrogen energy has significant benefits for future energy needs and environmental concerns. However, the challenges in terms of hydrogen storage, particularly in metal hydrides, need to be addressed. This review focuses on alternative methods, such as polymer-hydride systems, to prevent contamination and improve hydrogen sorption properties.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Energy & Fuels
Nozomi Noto, Shigehito Isobe, Naoyuki Hashimoto
Summary: The research evaluated the dehydrogenation properties of several hydride-hydroxide systems and found that only the KH-LiOH system showed potential for reversible hydrogen adsorption/desorption, although rehydrogenation would require extremely high pressure.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Review
Materials Science, Multidisciplinary
Xin F. Tan, Manjin Kim, Kazuhiro Yasuda, Kazuhiro Nogita
Summary: Bulk Mg-based hydrogen storage materials have the potential to provide a low-cost solution for energy storage and transportation. They are safer and more oxidation resistant compared to nano powders. Various alloying elements and innovative processing methods can be used to improve the performance of bulk Mg alloys in terms of hydrogen sorption kinetics and stability.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Boris P. Tarasov, Pavel V. Fursikov, Alexey A. Volodin, Mikhail S. Bocharnikov, Yustinas Ya Shimkus, Aleksey M. Kashin, Volodymyr A. Yartys, Stanford Chidziva, Sivakumar Pasupathi, Mykhaylo V. Lototskyy
Summary: This article provides an overview of literature data and R&D activities on energy storage technologies using hydrogen and metal hydrides, with a focus on selecting metal hydride materials based on AB(5)- and AB(2)-type intermetallic compounds for hydrogen storage and compression applications. It also discusses features of integrated energy storage systems utilizing metal hydride hydrogen storage and compression components developed by IPCP and HySA Systems.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
A. G. Olabi, Adel Saleh Bahri, Aasim Ahmed Abdelghafar, Ahmad Baroutaji, Enas Taha Sayed, Abdul Hai Alami, Hegazy Rezk, Mohammad Ali Abdelkareem
Summary: Hydrogen has been identified as the most promising carrier of clean energy in the efforts to replace fossil fuels. Hydrogen generation technologies play a key role in the energy mix and integrating them with other renewable energy systems is becoming increasingly feasible. While progress has been made in large-scale production and storage of hydrogen, local conditions and multiple strategies may be needed to achieve significant production and storage.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Review
Energy & Fuels
Nejc Klopcic, Ilena Grimmer, Franz Winkler, Markus Sartory, Alexander Trattner
Summary: Efficient energy storage is crucial for the shift to renewable energies, and hydrogen storage in metal hydrides offers high energy densities and safety advantages. This work investigates the technical, economic, and environmental aspects of different metal hydride materials, including their properties, production methods, and potential enhancements. The impacts on material costs, raw material abundance, and import dependency are discussed, and the advantages and disadvantages of selected materials are derived for material selection. Further research on material properties and system-level improvements is needed for widespread application of metal hydrides.
JOURNAL OF ENERGY STORAGE
(2023)
Review
Engineering, Environmental
Thi-Thu Le, Mohsin Abbas, David M. Dreistadt, Thomas Klassen, Claudio Pistidda
Summary: In recent years, complex hydrides have attracted increasing interest for their potential applications in energy storage and conversion. This review provides a comprehensive overview of ionic conduction in complex hydrides and highlights possible approaches to enhance their ionic conductivity. Additionally, the use of complex hydrides as solid electrolytes for electrochemical conversion and storage applications is reviewed, along with the relationship between ionic conduction and hydrogen sorption properties.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Yang Meng, Shunlong Ju, Wei Chen, Xiaowei Chen, Guanglin Xia, Dalin Sun, Xuebin Yu
Summary: By fabricating V4Nb18O55 microspheres, the H-2 desorption and absorption properties of MgH2 can be improved and the uniform formation of Nb/V interfaces can be achieved, resulting in the reduction of dehydrogenation temperature of MgH2 and the enhancement of hydrogenation reaction rate.
Article
Chemistry, Physical
Xiaoyue Zhang, Yahui Sun, Guanglin Xia, Xuebin Yu
Summary: Light-weight solid-state hydrogen storage materials, such as metal hydrides and complex hydrides, have great application potential due to their high hydrogen storage densities. Neutron scattering techniques have become powerful tools for characterizing the hydrogen storage mechanism of these materials.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Multidisciplinary
Rui Shi, Haoxing Yan, Jiguang Zhang, Haiguang Gao, Yunfeng Zhu, Yana Liu, Xiaohui Hu, Yao Zhang, Liquan Li
Summary: A simple, cost-effective method of water treatment is proposed to produce highly reactive and air-stable bulk Mg-Ni-based hydrides in this study. The method can significantly decrease the dehydrogenation temperature and allow the hydrides to be stored under ambient conditions without losing activity, providing an alternative approach to design low-cost, highly active metal hydrides.
Article
Biochemistry & Molecular Biology
Melkizedeck H. Tsere, Tatiana P. Pogrebnaya, Alexander M. Pogrebnoi
Summary: The study demonstrates that complex metal hydrides can release hydrogen gas to form gaseous products at high temperatures and undergo heterophase reactions to produce solid products at lower temperatures. The stability of these hydrides to different dissociation channels was analyzed using thermodynamic methods.
JOURNAL OF MOLECULAR MODELING
(2021)
Review
Engineering, Environmental
Min Liu, Zhendong Yao, Jing Gu, Chao Li, Xu Huang, Liuting Zhang, Zengyang Huang, Meiqiang Fan
Summary: Hydrogen energy is considered important for low carbon energy and has wide application prospects. The production of hydrogen plays a crucial role in the hydrogen industry chain. The safe and stable acquisition of hydrogen remains a pressing issue, particularly for temporary or portable usage scenarios, due to inadequate infrastructure. This paper systematically investigates the research progress of hydrolytic hydrogen production materials in the past 15 years, categorizing them into four systems based on hydrolysis characteristics. The advantages, disadvantages, and technical bottlenecks of different materials are thoroughly analyzed, and promising candidates are identified for industrialization feasibility and cost-effectiveness.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
D. Pukazhselvan, Narendar Nasani, Tao Yang, Devaraj Ramasamy, Aliaksandr Shaula, Duncan Paul Fagg
APPLIED SURFACE SCIENCE
(2019)
Article
Chemistry, Inorganic & Nuclear
A. Ramesh, M. Jeyavelan, M. Sterlin Leo Hudson
DALTON TRANSACTIONS
(2018)
Article
Chemistry, Physical
H. G. T. Nguyen, L. Espinal, R. D. van Zee, M. Thommes, B. Toman, M. S. L. Hudson, E. Mangano, S. Brandani, D. P. Broom, M. J. Benham, K. Cychosz, P. Bertier, F. Yang, B. M. Krooss, R. L. Siegelman, M. Hakuman, K. Nakai, A. D. Ebner, L. Erden, J. A. Ritter, A. Moran, O. Talu, Y. Huang, K. S. Walton, P. Billemont, G. De Weireld
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY
(2018)
Article
Chemistry, Physical
Tao Yang, D. Pukazhselvan, E. L. da Silva, Mario C. Santos, Lijian Meng, Devaraj Ramasamy, Sathiskumar Jothi, Vanessa Graca, Shikao Shi
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2019)
Article
Chemistry, Physical
Katherine E. Hurst, Thomas Gennett, Jesse Adams, Mark D. Allendorf, Rafael Balderas-Xicohtencatl, Marek Bielewski, Bryce Edwards, L. Espinal, Brent Fultz, Michael Hirscher, M. Sterlin L. Hudson, Zeric Hulyey, Michel Latroche, Di-Jia Liu, Matthew Kapelewski, Emilio Napolitano, Zachary T. Perry, Justin Purewal, Vitalie Stayila, Mike Veenstra, James L. White, Yuping Yuan, Hong-Cai Zhou, Claudia Zlotea, Philip Parilla
Article
Chemistry, Physical
Devaraj Ramasamy, Narendar Nasani, D. Pukazhselvan, Duncan P. Fagg
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2019)
Article
Materials Science, Multidisciplinary
Farheen Khurshid, M. Jeyavelan, Tanveer Hussain, M. Sterlin Leo Hudson, S. Nagarajan
MATERIALS CHEMISTRY AND PHYSICS
(2020)
Article
Chemistry, Physical
D. Pukazhselvan, Karakkadparambil Sankaran Sandhya, Devaraj Ramasamy, Aliaksandr Shaula, Duncan Paul Fagg
Article
Energy & Fuels
Ashish Bhatnagar, Anant Prakash Pandey, M. Sterlin Leo Hudson, Pawan K. Soni, Satish K. Verma, Vivek Shukla, V. Sekkar, Manoj Tripathi, O. N. Srivastava
Summary: In this study, Carbon Aerogel (CA) with varying pore size and surface area was synthesized by adjusting the ratio of Resorcinol (R) and novel Catalyst (triethyl amine [TEA]) (C). The CA with R/C = 1000 exhibited the highest CO2 uptake capacity at 40 atm CO2 pressure, while the activated version of optimum CA (R/C = 1000) showed one of the highest CO2 storage capacities reported so far. This research proposes highly efficient and tunable CAs for enhanced CO2 storage.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Chemistry, Multidisciplinary
A. Ramesh, M. Jeyavelan, J. A. Alex Rajju Balan, O. N. Srivastava, M. Sterlin Leo Hudson
Summary: This paper discusses the electrochemical energy storage and gas adsorption performance of commercial nanoporous activated carbon. The results show that the sample exhibits high specific capacitance and low capacitance loss.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2021)
Article
Materials Science, Multidisciplinary
D. Pukazhselvan, Francisco J. A. Loureiro, Aliaksandr Shaula, Sergey Mikhalev, Igor Bdikin, Duncan Paul Fagg
Summary: This study compares the electrochemical performance of anatase titanium-based magnesium ion batteries using two different electrolytes. The results show that the storage capacity of the batteries varies with different temperatures and electrolytes. The study provides crucial evidence that the reactivity of the magnesium surface is a significant factor in achieving better battery performance.
JOURNAL OF MATERIALS SCIENCE
(2022)
Article
Metallurgy & Metallurgical Engineering
D. Pukazhselvan, K. S. Sandhya, Devaraj Ramasamy, Aliaksandr Shaula, Igor Bdikin, Duncan Paul Fagg
Summary: This study found that zirconia additive can chemically interact with MgH2, forming active in-situ catalysts to improve hydrogen storage performance.
JOURNAL OF MAGNESIUM AND ALLOYS
(2022)
Article
Chemistry, Physical
D. Pukazhselvan, Aliaksandr L. Shaula, Sergey M. Mikhalev, Igor Bdikin, Duncan P. Fagg
Summary: The current study investigated the interaction between graphene oxide (GO) additive and magnesium hydride (MgH2), leading to the transformation to reduced graphene oxide (rGO). The results showed that the in situ transformation of GO to rGO reduced the dehydrogenation temperature of MgH2, increased the hydrogen ab/desorption reaction kinetics, and decreased the dehydrogenation activation energy. The study also demonstrated the potential of using magnesium hydride to trigger the GO to rGO transformation for the preparation of rGO and rGO composite materials, which are important for energy storage applications.
Article
Energy & Fuels
Achayalingam Ramesh, Sourabh Basu, Vellaichamy Ganesan, Pawan Kumar Soni, Shanmugam Manivannan, Jeyakumar Kandasamy, Michael Sterlin Leo Hudson, Mohammad Abu Shaz
Summary: In this study, two-dimensional carbon nanosheets derived from biomass precursor were successfully synthesized through a cost-effective salt-templated process. The thickness and capacitance of the nanosheets were altered by adjusting the carbon precursor to salt-template ratio. Thinner carbon nanosheets exhibited superior electrochemical properties and capacitance compared to thicker ones, without the need for chemical activation.
Article
Chemistry, Multidisciplinary
Farheen Khurshid, M. Jeyavelan, M. Sterlin Leo Hudson, Samuthira Nagarajan