Article
Biochemistry & Molecular Biology
Eva T. Gyamfi, Michael Ackah, Damian B. Gore
Summary: In this study, 36 traditional medicines were evaluated using T-XRF and PBET methods, and potentially toxic trace elements were detected. By comparing the ADI values of each medicine with the USEPA RfD limits, it was found that the risks of these medicines were within acceptable range. In summary, this study provides new insights into the health risks of potentially toxic and essential trace elements in traditional medicines.
Article
Engineering, Environmental
Nina Zupancic, Milos Miler, Ana Asler, Natalija Pompe, Simona Jarc
Summary: In Celje, Slovenia, children playing in sandboxes are at risk of poisoning due to toxic elements from zinc ore smelting and iron industry contamination. Some sandboxes contain sand from lead-zinc mine waste with higher than allowed levels of As, Ba, Cd, Pb and Zn. The study emphasizes the importance of combining health risk evaluation with bioaccessibility of elements in order to undertake remedial measures effectively.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Review
Environmental Sciences
Yan Li, Elio Padoan, Franco Ajmone-Marsan
Summary: Studies have shown significant differences in the bioaccessibility of PTE in soil across different size fractions, with a general trend of higher bioaccessibility in finer size fractions. The relationship between bioaccessibility and soil size fraction varies for different elements, suggesting the need for consensus on methods to determine PTE bioaccessibility for more accurate human health risk assessment.
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
(2021)
Review
Food Science & Technology
Esther Lima de Paiva, Sher Ali, Elsa Reis Vasco, Paula Cristina Alvito, Carlos Augusto Fernandes Oliveira
Summary: The introduction of complementary foods is a crucial step in the transition to solid foods for infants, but these foods may contain potentially harmful toxic elements. Understanding the bioaccessibility of these elements is essential for assessing the potential risks to infants. Standardized assessment methods and regulatory guidelines have been established, but there are still research opportunities and significant knowledge gaps.
FOOD RESEARCH INTERNATIONAL
(2023)
Article
Engineering, Environmental
Marija Zupancic, Mojca Sustersic, Spela Bavec, Mateja Gosar
Summary: This study evaluated the oral and inhalation bioaccessibility of PTE in household dust in a small town, revealing low bioaccessibility for mercury and varying bioaccessibility for different elements in the stomach and intestine. Daily ingestion and inhalation doses of PTE from household dust were found to be below recommended limits by the European Food Safety Authority.
ENVIRONMENTAL GEOCHEMISTRY AND HEALTH
(2021)
Article
Environmental Sciences
Veronica Martin-Leon, Carmen Rubio, Angel Rodriguez-Hernandez, Manuel Zumbado, Andrea Acosta-Dacal, Luis Alberto Henriquez-Hernandez, Luis D. Boada, Maria del Mar Travieso-Aja, Octavio P. Luzardo
Summary: This study examined the contribution of leafy green vegetables to the daily intake of 47 elements in different scenarios and age groups in the Canary Islands. Spinach, arugula, watercress, and chard were found to have the highest levels of elements. Essential elements such as iron and zinc were most prevalent in spinach and watercress, while toxic elements like cadmium and arsenic were also present.
Article
Environmental Sciences
Ksenija Jakovljevic, Tomica Misljenovic, Slobodan Jovanovic, Milica Grujic, Nevena Mihailovic, Gordana Tomovic
Summary: Plantago subulata is a facultative serpentinophyte with predominantly ultramafic distribution in Serbia and Montenegro. The study showed that high concentrations of specific elements were found in the plant and soil samples from abandoned mining sites, indicating the accumulation potential of this species. The plant acted as an indicator species for elements like Zn, Ni, and Cr, and showed exclusion and root sequestration as tolerance strategies for elements like Cd and Pb.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Review
Environmental Sciences
Mayara de Almeida Ribeiro Carvalho, Wander Gustavo Botero, Luciana Camargo de Oliveira
Summary: This study used a systematic literature review to identify sources of potentially toxic elements (PTEs) in the aquatic environment. The analysis revealed both natural and anthropogenic sources, such as mining, agriculture, industries, and domestic effluents. The study also highlighted specific locations where environmental remediation studies should be conducted to prevent and address PTE pollution.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Agronomy
Michael O. Asare, Jirina Szakova
Summary: This study evaluated the fertility of anthropogenic soils from an abandoned dumpsite in Awotan, Nigeria, and assessed the bioaccessibility of elements in selected plant species. The results showed that the anthropogenic soils had high organic matter and nutrient content, but also posed potential risks to the health of crop and herb consumers.
Article
Environmental Sciences
S. T. Mullineaux, S. H. A. Redpath, N. Ogle, J. M. McKinley, N. J. Marks, D. M. Scantlebury, R. Doherty
Summary: This study examined the accumulation patterns of heavy metals in Eurasian Badgers through compositional statistical methods, revealing geo-spatial patterns of potentially toxic elements in soil and badger tissues, as well as the mechanisms by which they move in the environment.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Review
Plant Sciences
Flavio Henrique Silveira Rabelo, Jaco Vangronsveld, Alan J. M. Baker, Antony van der Ent, Luis Reynaldo Ferracciu Alleoni
Summary: The review synthesizes information on mechanisms, suitable grass species, strategies to improve remediation efficiency, and advantages, disadvantages, and perspectives of using grasses for phytoremediation of trace element-polluted soils.
FRONTIERS IN PLANT SCIENCE
(2021)
Article
Environmental Sciences
Bin Jia, Yingze Tian, Yuqing Dai, Rui Chen, Peng Zhao, Jingjing Chu, Xin Feng, Yinchang Feng
Summary: This study investigated the deposited and dissolved bioaccessibility of potentially toxic elements (PTEs) in different sizes of particulate matter (PM) in a Chinese megacity. The results showed that fine PM had higher dissolved bioaccessible fraction (DBF) of certain elements compared to coarse PM. The presence of oxide/silicate compounds from coal combustion was found to lower the DBF of certain elements in fine particle sizes. Inhalation health risks were highest in particulate sizes below 0.43 μm and between 2.1-3.3 μm, with cancer risk exceeding the threshold value. Uncertainty analysis revealed that total concentrations and DBF of certain elements in the particle size segment below 0.43 μm had a greater influence on the probabilistic risk.
ENVIRONMENTAL POLLUTION
(2022)
Article
Engineering, Environmental
Tanmay Laha, Manash Gope, Sreemanta Datta, Reginald Ebhin Masto, Srinivasan Balachandran
Summary: In this study, an in vitro oral bioaccessibility assay was conducted to assess the bioaccessible potentially toxic elements (PTEs) in playground soils of Khagra, West Bengal, India. The results showed that some of the soils had potential health risks, especially for children, highlighting the need for a risk management plan to protect their health and safety.
ENVIRONMENTAL GEOCHEMISTRY AND HEALTH
(2023)
Article
Environmental Sciences
Piotr Hulisz, Szymon L. Rozanski, Anton Boman, Marta Rauchfleisz
Summary: This study analyzed the mobility of Cr, Cu, Ni, Pb, and Zn in acid sulfate soils in the reverse delta of the Swina River in NE Poland. The results showed that despite the relatively low metal content, these soils could potentially be a source of metal contamination affecting the coastal environment in the southern Baltic Sea region.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Environmental Sciences
Yue Yang, Lu Wang, Hanghang Zhao, Fan Yan, Shaohua Li, Bin Guo, Chi Lue, Xuniong Huang, Puhui Ji
Summary: This study used one-step modification of fly ash to generate modified fly ash with high adsorption capacity for removing heavy metals from aqueous solutions. The modified fly ash showed a destroyed surface structure, 12 times increase in specific surface area, and successful adsorption of metal ions. The adsorption effects were influenced by pH, ionic strength, and co-existing cations. The adsorption mechanisms were ion exchange, electrostatic attraction, and complexation. The modified fly ash also showed the ability to release absorbed heavy metal ions in organisms and aquatic environments.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Applied
Agnese Giacomino, Andrea Ruo Redda, Rocco Caligiuri, Paolo Inaudi, Stefania Squadrone, Maria Cesarina Abete, Ornella Abollino, Sara Morandi, Eleonora Conca, Mery Malandrino
Summary: A portable measurement and speciation procedure for inorganic mercury (HgIN) and methylmercury (CH3Hg) was developed, showing comparable quantification results to Direct Mercury Analyser (DMA). The new homemade sorbent demonstrated selectivity for HgIN and stability during retention tests. Overall, the portable method offers a convenient and reliable way to determine mercury species in samples.
Article
Environmental Sciences
Daniele Ziegler, Mery Malandrino, Claudia Barolo, Gianpiero Adami, Milena Sacco, Francesco Pitasi, Ornella Abollino, Agnese Giacomino
Summary: This study evaluated the contribution of a municipal solid waste incinerator to PM10 concentration and chemical composition in Turin, confirming that newly installed incinerators have a lower impact on atmospheric PM10 composition. Direct incinerator emissions were found to influence the concentrations of several heavy metal elements significantly.
Article
Environmental Sciences
Eleonora Conca, Mery Malandrino, Agnese Giacomino, Paolo Inaudi, Annapaola Giordano, Francisco Ardini, Rita Traversi, Ornella Abollino
Summary: The study evaluated the elemental composition of Arctic PM10 samples and applied a sequential extraction procedure to obtain more information on the sources. Results showed that elements with anthropogenic origins were more easily extractable in late winter and early spring, as well as elements with crustal origins in samples collected during this time period.
Review
Dentistry, Oral Surgery & Medicine
Giacomo Baima, Giovanni Iaderosa, Matteo Corana, Federica Romano, Filippo Citterio, Agnese Giacomino, Giovanni N. Berta, Mario Aimetti
Summary: This systematic review investigated the distinctive salivary ion profile in periodontitis compared to periodontal health, with sodium and potassium levels consistently higher in periodontitis patients. The findings suggest potential for high-resolution periodontal diagnosis based on differences in macro and trace elements in saliva samples.
JOURNAL OF PERIODONTAL RESEARCH
(2022)
Article
Biochemistry & Molecular Biology
Paolo Inaudi, Elio Mondino, Ornella Abollino, Mery Malandrino, Monica Argenziano, Laura Favilli, Roberto Boschini, Agnese Giacomino
Summary: A measurement and speciation procedure for the determination of total mercury, inorganic mercury, and methylmercury has been developed and demonstrated to be applicable for on-site determination. The analytes were successfully extracted and separated using an optimized sample pretreatment procedure and home-made columns packed with a new sorbent material. The quantification results obtained using the proposed method showed good performance, as confirmed through comparison with a direct mercury analyzer.
Article
Chemistry, Multidisciplinary
Stefano Bertinetti, Silvia Berto, Mery Malandrino, Davide Vione, Ornella Abollino, Eleonora Conca, Matteo Marafante, Anna Annibaldi, Cristina Truzzi, Silvia Illuminati
Summary: This study examines the behavior of metals in wet depositions and predicts the effects of increasing solution component concentrations using a chemical model. The findings highlight the importance of inorganic anions and organic acids in complexing metal cations, and identify the formation constants that have the most significant impact on the chemical system.
APPLIED SCIENCES-BASEL
(2022)
Article
Biochemistry & Molecular Biology
Eleonora Conca, Mery Malandrino, Aleandro Diana, Ornella Abollino, Agnese Giacomino, Rafael Bartroli, Teresa Moreno, Xavier Querol, Fulvio Amato
Summary: An efficient analytical procedure was developed for the determination of metals in PM samples collected on aluminium foils by a cascade impactor, allowing for accurate size distribution and elemental composition analysis. The procedure proved effective in determining extremely low concentrations of analytes in different size fractions of PM emitted by a brake system.
Article
Chemistry, Multidisciplinary
Silvia Berto, Enrico Cagno, Enrico Prenesti, Giulia Aragona, Stefano Bertinetti, Agnese Giacomino, Paolo Inaudi, Mery Malandrino, Emanuele Terranova, Ornella Abollino
Summary: The knowledge gained from this study on the electrochemical behavior of diclofenac is crucial for the development of a voltammetric sensor for detecting the drug in water samples. Different carbon-based electrodes were examined, and the optimal voltammetric procedure for determining diclofenac concentration was established. The results showed that the glassy carbon electrode and the smaller surface of the screen-printed carbon electrode immersed in solution had the lowest detection limits.
APPLIED SCIENCES-BASEL
(2022)
Article
Biochemistry & Molecular Biology
Agnese Giacomino, Paolo Inaudi, Gessica Silletta, Aleandro Diana, Stefano Bertinetti, Elisa Gaggero, Mery Malandrino, Federico Stilo, Ornella Abollino
Summary: The determination of the authenticity of extra virgin olive oils (EVOOs) has gained increasing interest, especially in Italy, which has the highest number of Protected Designation of Origin (PDO) oils in Europe. This study focused on using the inorganic content and electrochemical properties as markers to identify the region of origin and plant species of EVOOs. The results showed that the inorganic composition can be a useful marker for the geographical origin of EVOOs, while the voltammetric analysis can effectively distinguish the plant species of origin. This method could also be used to monitor the conservation status of the oils.
Article
Environmental Sciences
Aleandro Diana, Stefano Bertinetti, Ornella Abollino, Agnese Giacomino, Sandro Buoso, Laura Favilli, Paolo Inaudi, Mery Malandrino
Summary: This work evaluates the air quality of two industrial cities in Italy, Turin and Biella, and identifies the main sources of pollution and its evolution over 15 years. The analysis reveals that urban activities and soil/road dust resuspension are the main contributors to metal pollution. Although Biella has lower pollution levels than Turin, the daily average concentration of PM10 frequently exceeds the European limit value.
Article
Chemistry, Physical
Federica Solano, Paolo Inaudi, Ornella Abollino, Agnese Giacomino, Mario Chiesa, Enrico Salvadori, Gabriele Kociok-Kohn, Enrico da Como, Tommaso Salzillo, Claudio Fontanesi
Summary: The electronic properties of a charge-transfer semiconducting organic co-crystal, Perylene:F4-TCNQ (PE:F4), are studied experimentally and theoretically. The co-crystal's electronic characteristics are probed using electron paramagnetic resonance and solid state electrochemical techniques. The experimental findings are discussed based on density functional theory calculations, showing satisfactory agreement with the theoretical band gaps.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Analytical
Michel Rocha Baqueta, Augusto Cesar Costa-Santos, Ana Paula Rebellato, Gisele Marcondes Luz, Juliana Azevedo Lima Pallone, Federico Marini, Alexsandro Lara Teixeira, Douglas N. Rutledge, Patricia Valderrama
Summary: This study reports the essential element composition of new Brazilian Canephora coffees and applies chemometric tools for analysis. The results demonstrate the suitability of this method for origin and species discrimination based on the inorganic fraction of coffee.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Mengjie Li, Jiapeng Wang, You Zhou, Yang Chen, Lingying Xia
Summary: A novel photoelectrochemical biosensor based on gold nanoparticles and specific structures was developed for highly sensitive detection of mercury ion. The multiple sandwich structures hindered electron supply and light harvesting, resulting in a weakened PEC signal, while the specific structures extinguished the PEC signal, enabling quantitative detection of Hg2+. The sensor exhibited high selectivity and stability, with potential applications in environmental detection, biological analysis, and medical research.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Mohamed A. Korany, Rasha M. Youssef, Marwa A. A. Ragab, Mostafa A. Afify
Summary: A stability-indicating fit-for-purpose method was developed for the determination of HC, TL, and PS in syrup dosage form. The method successfully separated CL from THY and quantified the analytes using HPLC-DAD. The robustness of the method was assessed through statistical analysis and self-validation.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Lingling Lin, Minyu Li, Ping Li, Chenqing Ye, Huanglong Zhuang, Shaohuang Weng, Feng Chen
Summary: This study developed a highly sensitive and selective electrochemical sensor for simultaneous detection of dopamine and uric acid. The sensor exhibited excellent anti-interference and stability, and could accurately measure dopamine and uric acid in human urine samples.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Peifang Chen, Caiyun Jiang, Zhouping Wang, Hong-zhen Lian, Xiaoyuan Ma
Summary: In this study, a high-performance SERS-active aptasensor was successfully developed for the quantitative analysis of AFB1 in cereal grains, which is of great significance in the field of food safety.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
E. Abas, C. Marina-Montes, C. Perez-Marin, J. Puimedon, J. Anzano
Summary: This study conducted a comprehensive measurement of natural and anthropogenic radionuclides in soil, water, and air in different locations around Deception Island in Antarctica. The results revealed significant levels of 210Pb and anthropogenic 137Cs in soil samples near old human settlements and facilities, as well as detectable levels of 137Cs and 60Co in water samples from old hunting areas. The findings also suggested potential resuspension processes based on higher-than-expected air quality results.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Joao Franciso Allochio, Nayara A. dos Santos, Nathalia dos S. Conceicao, Clara S. D. Baptista, Keyller B. Borges, Valdemar Lacerda Jr, Wanderson Roma
Summary: This study developed a fiber spray ionization mass spectrometry (FSI-MS) method, which shows great potential in detecting illicit drugs. Compared with paper spray ionization mass spectrometry (PSI-MS), FSI-MS demonstrates higher sensitivity in COC detection.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Dina A. Ahmed, Ola G. Hussein, Mamdouh R. Rezk, Mohamed Abdelkawy, Yasmin Rostom
Summary: The main goal of this study was to develop two green chromatographic techniques, HPLC and TLC, for the determination of alcaftadine (ALF) in pharmaceutical formulation and biological samples. The developed HPLC technique showed high efficiency and minimal environmental impact, successfully identifying ALF in the presence of its degradate. The TLC method provided a stability indicating study for ALF and was determined to be safe, green, and eco-friendly.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Abdullah Taner Bisgin
Summary: A green, speedy, and handy method for separation and determination of four commonly used food colorants was established using vortex assisted sequential-simultaneous liquid phase micro-extraction (VA-SS-LPME). The method does not require any instrumental chromatographic techniques. The procedure includes sequential separation steps using different extractants and simultaneous UV-vis spectrophotometric determination steps. The method is environmentally friendly and applicable for determination of colorants in food and pharmaceuticals.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Yifan Zhang, Tong Zhang, Wenjing Ba, Li Liu, Yuan Rao, Xiaodan Zhang, Hanhan Zhang, Xiu Jin
Summary: This paper proposes a novel spectral transfer modelling method based on neural network architecture searching for the asymptomatic prediction of Akizuki pear cork spot disorder. The experiments show that the model by this method is more effective, achieving an accuracy of 82.61%.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Krzysztof Greda, Maja Welna, Anna Szymczycha-Madeja, Pawel Pohl
Summary: For the first time, a dispersive micro-solid phase extraction (D-mu SPE) based on graphene oxide was used for the ultrasensitive determination of Cd. With this method, Cd can be efficiently extracted from a mixture of alkali and alkaline earth metals without the need for an elution step. The combination of D-mu SPE and SAGD OES significantly reduces matrix effects and improves the tolerance of Cd to alkali metals. The method shows simplicity in the measurement system and the commercially available nanosorbent used.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
P. K. Fathima Anjila, G. R. Tharani, Anand Sundaramoorthy, Venkat Kumar Shanmugam, Karthikeyan Subramani, Shanmugavel Chinnathambi, Ganesh N. Pandian, Vimala Raghavan, Andrews Nirmala Grace, Singaravelu Ganesan, Mangaiyarkarasi Rajendiran
Summary: This work proposes a rapid and sensitive spectroscopic method for detecting melamine in food products using rare-earth Terbium-doped Graphene Quantum Dots (Tb-GQDs) synthesized by microwave and simple chemical conjugation methods. The synthesized Tb-GQDs show a spherical shape with a size of approximately 6 nm and a quantum yield of 52%. The maximum detection limit for melamine concentration in milk and milk products is found to be 0.31 μM. The dual emitting Tb-GQDs provide a sensitive and effective platform for real-time detection of melamine in food samples, particularly in milk, and show promising potential in the food industry.
MICROCHEMICAL JOURNAL
(2024)
Review
Chemistry, Analytical
Piyush Dey, Mandeep Kaur, Akhil Khajuria, Dilmeet Kaur, Manpreet Singh, Hema Kumari Alajangi, Neha Singla, Gurpal Singh, Ravi Pratap Barnwal
Summary: Environmental issues, such as the uncontrolled release of dangerous pollutants, have significant impacts on human health. Traditional methods for detecting pollutants require specialized personnel and equipment, but nanotechnology has improved the performance of biosensors. This article discusses the use of nanotechnology in pollutant detection and the associated techniques.
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Sa Dong, Qiuyun Shi, Lingjun Guan, Yulong Wang, Pengyan Liu, Cunzheng Zhang, Jianguo Feng
Summary: In this study, a highly sensitive indirect competitive chemiluminescence enzyme immunoassay (icCLEIA) method was developed for the determination of sodium pentachlorophenolate (PCP-Na) and its metabolite pentachlorophenol (PCP). The method showed high specificity and affinity with a detection limit of 0.0032 ng/mL for PCP-Na and 0.0192 ng/mL for PCP. The method had no cross reaction with other chlorophenols compounds except for PCP. The average recoveries in chicken, pork and fish samples were 81.3-105.8% with low coefficient of variation (CV).
MICROCHEMICAL JOURNAL
(2024)
Article
Chemistry, Analytical
Palaniappan Ilayaraja, Murugan Manivannan, Paramasivam Parthiban
Summary: Nirmatrelvir, an antiviral drug used for the treatment of COVID-19, has been recommended by the World Health Organization. We developed an optimized analytical method for the quantification of Nirmatrelvir and its products, with high sensitivity and a wide linear range. The method also meets the requirements for greenness evaluation.
MICROCHEMICAL JOURNAL
(2024)
