4.6 Article

A monitoring strategy to detect CO2 intrusion in deeper freshwater aquifers

Journal

INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL
Volume 9, Issue -, Pages 262-271

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ijggc.2012.03.016

Keywords

CO2 geological storage; CO2 leakage; Monitoring parameters; CO2 intrusion; Freshwater aquifers

Funding

  1. German Federal Ministry of Education and Research (BMBF)
  2. EnBW Energie Baden-Wurttemberg AG
  3. E.ON Energie AG
  4. E.ON Gas Storage AG
  5. RWE Dea AG
  6. Vattenfall Europe Technology Research GmbH
  7. Wintershall Holding AG
  8. Stadtwerke Kiel AG, CO2-MoPa joint project

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The study provides guidance for the design of site-tailored monitoring protocols at CO2 storage sites. Monitoring of geochemical changes induced by CO2 intrusion in freshwater aquifers which are located between storage formations and close-to-surface compartments can enable the early detection of CO2 leakage events and ensure the safety of freshwater resources. The suitability of the hydroelectric conductivity (EC), the total inorganic carbon (TIC) concentration, and the pH of groundwater, which have been proposed as monitoring parameters for shallow aquifers, are investigated by means of reactive scenario modeling at depths between 10 and 450 m. Simulation results suggest that all parameters are well suited and allow distinguishing intrusion of CO2 from intrusion of high-salinity water or a mixture of both. However, EC may not be well-suited for the monitoring of shallow mature clastic aquifers. The study proposes to consider the combination of geophysical and geochemical measurements in site-specific monitoring protocols. (C) 2012 Elsevier Ltd. All rights reserved.

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