4.7 Article Proceedings Paper

Relationships between the optical properties of coal macerals and the chars resulting from fluidized bed pyrolysis

Journal

INTERNATIONAL JOURNAL OF COAL GEOLOGY
Volume 111, Issue -, Pages 80-89

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.coal.2012.11.017

Keywords

Collotelinite; Fusinite; Macrinite; Chars; RIS parameters; Microstructural changes

Ask authors/readers for more resources

In this study the values of the RIS axes and parameters were calculated using Kilby's method to the characterization of the textural anisotropy and structure of the basic structural units of coal macerals (collotelinite, fusinite, and macrinite). Their microstructural evolution after having been subjected to fluidized bed pyrolysis at 800 degrees C was investigated, using the same parameters, on their respective char portions (fused char, fusinoids, and inertoids). Thus, this work represents the first attempt to determine the variations of the optical properties of fluidized bed chars. After the thermal treatment, the fusinoids and the inertoids presented similar R-r% values and RIS parameters values, indicating that after pyrolysis these materials are texturally and structurally similar. Collotelinite produced fused chars with a higher reflectance than those resulting from fusinoids and inertoids. Their reflectance increase in lower and decrease in higher rank coals. The highest R-MAX%, R-ev, and R-am increase occurred in the fused char portions derived from the collotelinite of coals in the 0.86-1.60 R-r% range, indicating substantial chemical and spatial rearrangement. (C) 2012 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Geochemistry & Geophysics

Integrative Study Assessing Space and Time Variations with Emphasis on Rare Earth Element (REE) Distribution and Their Potential on Ashes from Commercial (Colombian) Coal

Ana Claudia Santos, Alexandra Guedes, David French, Aurora Futuro, Bruno Valentim

Summary: The increasing demand and supply risk of rare earth elements (REEs) have led to the research on alternative secondary sources. This study focuses on coal and coal combustion ash as potential raw materials for REEs. The results show that the concentrations of REEs in ash are higher than in feed coals. The fine and nonmagnetic fractions of the ash are found to be enriched with REEs. However, the concentrations of REE oxides are still below the economical cutoff of 1000 ppm.

MINERALS (2022)

Article Archaeology

Raman microspectroscopy applied to flint provenance at the chalcolithic settlement of Zambujal (Torres Vedras, Portugal)

Patricia Jordao, Alexandra Guedes, Nuno Pimentel

Summary: In this study, the mineralogical characteristics of both archaeological and geological flint were investigated using Raman microspectroscopy and X-ray diffraction (XRD). The degree of quartz crystallinity in archaeological materials could be inferred by evaluating its crystallinity through Raman analysis. The evaluation of moganite content allowed for better differentiation among Cenomanian flints from different locations.

ARCHAEOMETRY (2022)

Article Energy & Fuels

Petrology of the Parvadeh coals, Tabas Basin, Iran

R. Esmailpour, S. Alipour, F. Doulati Ardejani, S. Rodrigues, J. Esterle

Summary: The Tabas Basin in Iran has the country's largest coal deposits, primarily in the Parvadeh Coalfield. The basin is structurally characterized by thrust faults and strike-slip faults that separate the coalfields. The study examines the coalification history and the occurrence of pseudovitrinite in the Parvadeh coals.

INTERNATIONAL JOURNAL OF COAL GEOLOGY (2022)

Article Energy & Fuels

Reservoir lithofacies study of the Toolebuc Formation, Eromanga Basin, Australia as a potential unconventional target

Xiaoxiao Mao, Sandra Rodrigues, Joan S. Esterle, Suzanne D. Golding

Summary: Open file data and new laboratory data were integrated to interpret reservoir properties of the Toolebuc Formation. The formation is divided into an upward deepening cycle (UDC) followed by an upward shallowing cycle (USC), with different lithofacies present. Facies 1 is clay and silica-rich with low TOC, Facies 2 has mixed mineralogical composition with high TOC, and Facies 3 is enriched in carbonates. The lithofacies stacking pattern corresponds to changes in GR response, TOC, Brittleness Index (BI), and clay content.

INTERNATIONAL JOURNAL OF COAL GEOLOGY (2023)

Article Chemistry, Analytical

Early Identification of Unbalanced Freight Traffic Loads Based on Wayside Monitoring and Artificial Intelligence

R. Silva, A. Guedes, D. Ribeiro, C. Vale, A. Meixedo, A. Mosleh, P. Montenegro

Summary: This study aims to develop a methodology to automatically identify unbalanced vertical loads in freight trains circulation, which is crucial for railways management companies and operators to prevent service interruptions or derailments with high financial costs.

SENSORS (2023)

Article Green & Sustainable Science & Technology

Characterization and Thermal Treatment of the Black Mass from Spent Lithium-Ion Batteries

Elsayed Mousa, Xianfeng Hu, Ludvig Annhagen, Guozhu Ye, Antonella Cornelio, Ario Fahimi, Elza Bontempi, Patrizia Frontera, Charlotte Badenhorst, Ana Claudia Santos, Karen Moreira, Alexandra Guedes, Bruno Valentim

Summary: This paper reports on the characterization of two grades of black mass from spent lithium-ion batteries and their behavior during heating trials. The study provides important insights for optimizing lithium-ion battery recycling processes by fully characterizing black mass samples before and after heating.

SUSTAINABILITY (2023)

Article Energy & Fuels

Characterisation of coal using hyperspectral core scanning systems

Sandra Rodrigues, Lionel Fonteneau, Joan Esterle

Summary: Commercially available hyperspectral drill core scanning systems were used to characterise coal samples of varying rank with different preparations. The observed spectral features of the coals changed with increasing coalification. The ratio of the area of the aromatic absorption feature to that of the aliphatic absorption features, called Rank Spectral Index, displayed a strong linear correlation with coal rank parameters.

INTERNATIONAL JOURNAL OF COAL GEOLOGY (2023)

Article Geology

The Pen?a do Seo W-Sn deposit, NW Iberia: Petrology, fluid inclusions and O-H-S isotopes

P. Caldevilla, L. Gonzalez-Menendez, T. Martin-Crespo, E. Vindel, A. Guedes, E. Berrezueta, A. M. Castanon, F. Gomez-Fernandez

Summary: The Pen deposit in NW Iberia is mainly composed of quartz veins containing wolframite, cassiterite, and minor molybdenite. The study combined whole rock geochemistry, mineral characterization, fluid inclusions, and stable isotope geochemistry to understand the hydrothermal mineralization conditions. Four stages of mineralization were identified, including an alteration stage, three mineralization stages, and a supergene stage.

ORE GEOLOGY REVIEWS (2023)

Article Geochemistry & Geophysics

Contamination Fingerprints in an Inactive W (Sn) Mine: The Regoufe Mine Study Case (Northern Portugal)

Helena Sant'Ovaia, Claudia Cruz, Alexandra Guedes, Helena Ribeiro, Patricia Santos, Sonia Pereira, Jorge Espinha Marques, Maria dos Anjos Ribeiro, Catarina Mansilha, Helena Cristina Brites Martins, Bruno Valentim, Joana Torres, Ilda Abreu, Fernando Noronha, Deolinda Flores

Summary: The study focused on the tungsten Regoufe mine, which stopped operations in the 1970s. The research evaluated the contamination of soil, plants, and water in the mining area, specifically looking at potentially toxic elements (PTEs). The results showed that the area had a high level of contamination, posing ecological risks, particularly due to contributions from arsenic (As) and cadmium (Cd). However, it was difficult to establish a direct link between As contamination and mining activities, as the soils were already enriched in metals and metalloids from natural geological processes. The study also found that PTE levels in plants were lower than in soil, but bioaccumulation was influenced by site-specific soil concentrations of As and Pb. Magnetic studies indicated the presence of technogenic particles, likely formed during ore processing/mining activities. Overall, the levels of PTEs in surface and groundwater samples were relatively low, with the exception of As, which exceeded drinking water standards.

MINERALS (2023)

Article Energy & Fuels

Before and after: A visual glimpse into the coking behaviour of coal macerals

Tara Congo, Sandra Rodrigues, Joan Esterle, Karen Steel, Silvio Maranha

Summary: This paper briefly reviews the founding research in coal petrography as a tool for predicting coke quality and proposes a technique for direct optical comparison of a semicoke to its precursory coal. The method involves imaging a polished block sample of coal, pyrolysing it in a furnace, embedding the resulting semicoke in resin, and re-imaging the surface of interest. The observations of two Permian coals are also presented.
Article Biochemistry & Molecular Biology

Hybrid Zn-β-Aminoporphyrin-Carbon Nanotubes: Pyrrolidine and Direct Covalent Linkage Recognition, and Multiple-Photo Response

Susana L. H. Rebelo, Cesar A. T. Laia, Monika Szefczyk, Alexandra Guedes, Ana M. G. Silva, Cristina Freire

Summary: Unveiling and shaping the molecular connectivity in (metallo)porphyrin-carbon nanotube hybrids is crucial for their various applications in medicine, photoelectronics, catalysis, and photocatalysis. This study successfully modified multi-walled carbon nanotubes through 1,3-dipolar cycloaddition reactions and demonstrated the presence of different porphyrin-carbon nanotube connectivity in the resulting nanohybrid. Photophysical studies further confirmed energy/charge transfer in the photoactivated nanohybrid.

MOLECULES (2023)

Article Green & Sustainable Science & Technology

Recovery of Graphite from Spent Lithium-Ion Batteries

Charlotte Badenhorst, Iwona Kuzniarska-Biernacka, Alexandra Guedes, Elsayed Mousa, Violeta Ramos, Gavin Rollinson, Guozhu Ye, Bruno Valentim

Summary: This paper presents a separation process for recovering graphite from spent lithium-ion batteries, along with the recovery of LMO, Cu, and Al as by-products. The process is simple, environmentally friendly, and cost-effective, using readily available equipment in the market.

RECYCLING (2023)

No Data Available