4.2 Article Proceedings Paper

Structure Correlated Enhancement in Dielectric and Electrical Properties of Strontium Based Niobates

Journal

INTEGRATED FERROELECTRICS
Volume 122, Issue -, Pages 1-11

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/10584587.2010.492285

Keywords

X-ray diffraction; dielectric properties; SEM; Ferroelectric; Conductivity; 1:2 Niobates

Ask authors/readers for more resources

Structural, dielectric and transport properties of single phase Sr(B-1/3'Nb-2/3)O-3 where (B' = Mg2+, Co2+, Cu2+) relaxor ferroelectric compounds synthesized by standard solid state reaction technique, are reported here. All the samples exhibit strong correlation between structure, dielectric and transport behavior. In this system significant Jahn-Teller distortion, induces enhancement in dielectric properties. Further, weak Jahn-Teller distortion due to unevenly occupied t(2g) levels in Co2+ produces intermediate rise in epsilon' as well as inbuilt flexibility to conduction electron movement enhances dielectric loss (tan delta). On the other hand, strong Jahn-Teller effects in Cu2+ substituted compound, due to unevenly occupied e(g) levels, results in large enhancement in epsilon' and frequency exponent 's'. This is accompanied by significant fall in dielectric loss due to localization of conduction electrons within oxygen octahedron.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.2
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Multidisciplinary

Preparation and structural, optical studies of Al substituted chromium oxide; ern (Cr2O3) nanoparticles

Jarnail Singh, Vikram Verma, Ravi Kumar

VACUUM (2019)

Article Materials Science, Multidisciplinary

Effect of structural and thermal disorder on the optical band gap energy of Cr2O3 nanoparticles

Jarnail Singh, Vikram Verma, Rajesh Kumar, Sandeep Sharma, Ravi Kumar

MATERIALS RESEARCH EXPRESS (2019)

Correction Materials Science, Multidisciplinary

Effect of structural and thermal disorder on the optical band gap energy of Cr2O3 nanoparticles (vol 6, 085039, 2019)

Jarnail Singh, Vikram Verma, Rajesh Kumar, Sandeep Sharma, Ravi Kumar

MATERIALS RESEARCH EXPRESS (2019)

Article Materials Science, Multidisciplinary

Structural, optical and electrical characterization of epitaxial Cr2O3 thin film deposited by PLD

Jarnail Singh, Vikram Verma, Rajesh Kumar, Ravi Kumar

MATERIALS RESEARCH EXPRESS (2019)

Article Materials Science, Multidisciplinary

Consequences of R3+ cationic radii on the dielectric and magnetic behavior of RCrO3 perovskites

Kapil Dev Singh, Fouran Singh, R. J. Choudhary, Ravi Kumar

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2020)

Article Engineering, Electrical & Electronic

Structural and optoelectronic properties of epitaxial Ni-substituted Cr2O3 thin films for p-type TCO applications

Jarnail Singh, Rajesh Kumar, Vikram Verma, Ravi Kumar

Summary: Transparent and conducting epitaxial thin films of pristine chromium oxide (Cr2O3) and nickel (Ni) substituted Cr2O3 were deposited on sapphire substrates using pulsed laser deposition (PLD) technique. The addition of nickel (Ni) led to an increase in carrier concentration and a decrease in optical band gap energy. This material has potential applications in optoelectronics due to its high transparency and conductivity properties.

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING (2021)

Article Materials Science, Ceramics

XAS and XPS analysis of double magnetic transition, canonical spin glass behavior and magnetoresistance in LaMn1-xCoxO3 (0.1 ≤ x ≤ 0.5) system

F. H. Bhat, G. Anjum, Ravi Kumar, Manzoor A. Malik, R. J. Choudhary, D. K. Shukla

Summary: Polycrystalline LaMn1-xCoxO3 (0.1 <= x <= 0.5) samples synthesized using conventional ceramic method exhibit strong magnetic properties with double transition and spin glass state. These characteristics are mainly influenced by the interactions between Co and Mn ions, showing significant magnetoresistance effects.

CERAMICS INTERNATIONAL (2021)

Article Physics, Condensed Matter

Enhanced Electroactive Phases in Bi3.3La0.7Ti3O12-poly (vinylidene fluoride) composites with Improved Dielectric Properties

Sumit Bhardwaj, J. D. Sharma, Subhash Chand, K. K. Raina, Ravi Kumar

Summary: Lead-free ceramic-polymer nanocomposites were synthesized using the solution casting method, with homogeneously dispersed BLT ceramic particles enhancing the electroactive phases of PVDF. The nanocomposites exhibited superior dielectric and ferroelectric properties, showing potential in flexible sensors, data storage, and energy harvesting applications.

SOLID STATE COMMUNICATIONS (2021)

Article Chemistry, Inorganic & Nuclear

Structural, optical and magnetic characterization of Ni2+ions doped chromium oxide (Cr2O3) nanoparticles

Pankaj Bhardwaj, Jarnail Singh, Rajesh Kumar, Ravi Kumar, Vikram Verma

Summary: In this study, the suitability of chromium oxide as diluted magnetic oxide was systematically investigated, with nanoparticles doped with Ni2+ ions successfully synthesized. Various analyses confirmed the structural characteristics of the nanoparticles and revealed the presence of oxygen defects. The study also demonstrated marginal changes in optical bandgap and weak room temperature ferromagnetism in the doped nanoparticles.

SOLID STATE SCIENCES (2021)

Article Materials Science, Multidisciplinary

Influence of samarium doping on structural, elastic, magnetic, dielectric, and electrical properties of nanocrystalline cobalt ferrite

Mohd. Hashim, Nehru Boda, Ateeq Ahmed, S. K. Sharma, D. Ravinder, Edapalli Sumalatha, Anwar Ul-Hamid, Mukhlis M. Ismail, Mohd. Chaman, Sagar E. Shirsath, Ravi Kumar, Shalendra Kumar, Sher Singh Meena, Mohammad Nasir

Summary: In this study, samarium-doped cobalt ferrite nanoparticles were synthesized using citrate gel auto-combustion method and annealed at 500 degrees C for 4 hours. The doping of samarium was found to strongly influence the magnetic properties of the nanoparticles, leading to a decrease in saturation magnetization values. Rietveld analysis confirmed the formation of a single-phase structure in all compositions.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2021)

Article Materials Science, Multidisciplinary

Structural, diffuse reflectance and luminescence study of t-Mg2B2O5 nanostructures

Jitender Kumar, Rajesh Kumar, Mukhtiyar Singh, Shalendra Kumar, Ravi Kumar, Sung Ok Won, Ranjeet Brajpuriya, Sourabh Dwivedi, Ram K. Sharma, Ankush Vij

Summary: The study investigated the structural, reflectance, photoluminescence, and thermoluminescence properties of t-Mg2B2O5 nanostructures synthesized using an optimized combustion method. The direct band gap of 5.23 eV was determined, contrary to previous reports, and first principle calculations confirmed this. The t-Mg2B2O5 nanoparticles exhibited yellow-reddish photoluminescence and UV responsive thermoluminescence, suggesting potential applications in luminescence-based technologies and UV dosimetry. Additionally, the study demonstrated the anti-biofilms activity of Mg2B2O5 nanoparticles against pseudomonas aeruginosa bacterial cells.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2021)

Article Engineering, Chemical

Evaluation and comparison of mineralogical, micromeritics and rheological properties of waste machining chips, coal fly ash particulates with metal and ceramic powders

Amarjit Singh, Harish Singh Dhami, Manoj Kumar Sinha, Ravi Kumar

Summary: This article presents a detailed study of the mineralogy, micromeritics, and rheology of various materials, including powders and metal chips. The density and morphology of the particles were found to greatly influence their properties. The study also suggests that waste metallic chips can be recycled through powder metallurgy, saving time compared to ball milling.

POWDER TECHNOLOGY (2022)

Article Engineering, Electrical & Electronic

Effect of Varying Rare-Earth Cations on the Electronic Structure of RCrO3 Perovskites

Kapil Dev Singh, Dinesh Kumar Shukla, Ravi Kumar

Summary: By utilizing x-ray absorption near-edge spectroscopy (XANES) measurements, we investigated the electronic structure of perovskite-type RCrO3 (R = La, Nd, Eu, Gd, Dy, and Y) compounds. The results showed significant differences in the framework of the metal-oxygen hybridization caused by different rare earth elements (R). The dominant role of Cr3+ was found in all these perovskite-type RCrO3 samples, except for EuCrO3 where Cr existed in a mixed-valence state of +3 and +4. The ligand field-splitting values increased consistently with decreasing rare-earth (R) cationic radii, except for an anomaly in the case of Eu.

JOURNAL OF ELECTRONIC MATERIALS (2022)

Proceedings Paper Multidisciplinary Sciences

The Effect of pH on Preparation of Single Phase Zinc Stannate Nanoparticles

Sacheen Kumar, Nav Deepak, Ravi Kumar

ADVANCES IN BASIC SCIENCES (ICABS 2019) (2019)

Proceedings Paper Physics, Applied

Influence of Intrinsic Strain on the Optical Band Gap Energy of AlxCr2-xO3 Nanoparticles

Jarnail Singh, Vikram Verma, Ravi Kumar

DAE SOLID STATE PHYSICS SYMPOSIUM 2018 (2019)

No Data Available