Article
Chemistry, Organic
Min Liu, Xing Wang, Ziqiong Guo, Hanyuan Li, Wei Huang, Hui Xu, Hui-Xiong Dai
Summary: In this study, the palladium-catalyzed asymmetric acyl-carbamoylation reaction was reported, producing alpha-quaternary chiral cycloketone with high yields and excellent enantioselectivity. The reaction proceeded via asymmetric 1,2-migratory insertions of acyl-Pd into alkenes and subsequent migratory insertion of isocyanides into C(sp(3))-Pd-II. The product could be further diversified, showcasing the synthetic utility of this protocol.
Article
Chemistry, Multidisciplinary
Majid Mohammadnia, Nazanin Poormirzaei
Summary: A new magnetic nanocatalyst, Pd supported on 5-carboxyoxindole functionalized cell@Fe3O4 nanoparticles, was synthesized and successfully employed for the Heck-type arylation of different substituted maleimides. This green catalyst can be easily recovered and reused multiple times without significant loss of activity, providing a clean and efficient synthetic procedure.
NANOSCALE ADVANCES
(2021)
Article
Materials Science, Paper & Wood
Melike Caliskan, Talat Baran
Summary: A novel nanocatalyst system (Pd@CS-ZnO) was developed by attaching palladium nanoparticles onto a hybrid nanocomposite of chitosan and ZnO nanoparticles. The catalytic efficiency of Pd@CS-ZnO was assessed for Heck coupling reaction, showing promising results. The Pd@CS-ZnO nanocatalyst demonstrated easy separation and high chemical stability, making it a cost-effective and eco-friendly catalyst system.
Article
Chemistry, Multidisciplinary
Fariba Jafari, Arash Ghorbani-Choghamarani, Neda Hasanzadeh
Summary: Boehmite nanoparticles were synthesized in aqueous solution by combining Al(NO3)3·9H2O and NaOH, which were then converted to Pd-Gu@BOEH nanocatalyst for chemoselective C-C bond formation reactions. The catalyst and products were characterized, and the recycled catalyst exhibited good stability during reaction processes.
RESEARCH ON CHEMICAL INTERMEDIATES
(2021)
Article
Chemistry, Multidisciplinary
Ziyan Zhang, Nikita Kvasovs, Anastasiia Dubrovina, Vladimir Gevorgyan
Summary: This method utilizes visible light-induced and Bronsted acid-assisted generation of hybrid palladium C(sp(3))-centered radical intermediate, enabling efficient transformation of a wide range of vinyl arenes, heteroarenes, and diazo compounds.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Review
Chemistry, Organic
Sabrina Giofre, Letizia Molteni, Egle M. Beccalli
Summary: This Review presents the progress in catalytic enantioselective mono- and difunctionalization of alkenes, with a focus on the fundamental role of ligands. Various types of asymmetric reactions involving different bond formation, such as C-O, C-N, and C-C bonds, have been developed. The urgency to discover new ligands and synthetic methodologies is emphasized to enhance control over reaction selectivity and activity, and to expand the applications in the synthesis of heterocyclic scaffolds and biologically active compounds.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Mohammad Hosein Sayahi, Mansoureh Toosibashi, Mehdi Bahmaei, Hosein Lijan, Leila Ma'Mani, Mohammad Mahdavi, Saeed Bahadorikhalili
Summary: In this study, a novel catalyst based on the immobilization of palladium onto modified mesoporous silica nanoparticles has been introduced. The catalyst exhibited excellent activity and efficiency in carbon-carbon bond formation reactions, and showed good reusability.
FRONTIERS IN CHEMISTRY
(2022)
Article
Chemistry, Physical
Victoria Dimakos, Daniel P. Canterbury, Sebastien Monfette, Philipp C. Roosen, Stephen G. Newman
Summary: This study describes a Pd-catalyzed method for the direct and selective alpha-arylation of cyclic enones using (hetero)aryl triflates. Optimized ligands and additives were employed to achieve high selectivity. Preliminary mechanistic investigations suggest that the reaction proceeds through enone activation and Pd-catalyzed enolate arylation, resembling a Morita-Baylis-Hillman reaction.
Article
Chemistry, Applied
Ze-Jian Xue, Meng-Yao Li, Bin-Bin Zhu, Zhi-Tao He, Chen-Guo Feng, Guo-Qiang Lin
Summary: The palladium-catalyzed cross-coupling of ortho-vinyl aromatic bromides and olefins using a controllable 1,4-palladium migration/Heck cascade protocol is a mild, efficient, and highly stereoselective method for the synthesis of trisubstituted 1,3-dienes, especially triaryl-substituted ones.
ADVANCED SYNTHESIS & CATALYSIS
(2021)
Review
Chemistry, Multidisciplinary
Jia-Qi Xie, Ren-Xiao Liang, Yi-Xia Jia
Summary: This review focuses on recent development of catalytic asymmetric Heck reaction and reductive Heck reaction, covering intermolecular and intramolecular versions since 2011. The article is organized in terms of the catalysts and olefin substrates, providing a clear structure for readers.
CHINESE JOURNAL OF CHEMISTRY
(2021)
Review
Chemistry, Applied
Xue-Song Zhang, Ya-Ping Han, Yuecheng Zhang, Yong-Min Liang
Summary: Elaborated molecular architectures, such as complex carbocycles, heterocycles, and polycyclic structures, are important organic compounds found in natural products, medicinal molecules, and functional materials. The development of efficient and selective methods for constructing these compounds from readily available starting materials is a major challenge in synthetic methodology. Transition-metal-catalyzed transformations involving Heck reaction have emerged as a powerful approach for accessing sophisticated polycyclic skeletons, streamlining the drug discovery process. This review summarizes the latest advances in transition-metal-catalyzed transformations involving Heck reaction, including six categories: Heck/Sonogashira tandem reaction, Heck/Suzuki tandem reaction, Heck/Heck tandem reaction, Heck/Hiyama tandem reaction, Heck/Cacchi tandem reaction, and Heck/C-H bond functionalization tandem reaction.
ADVANCED SYNTHESIS & CATALYSIS
(2023)
Article
Chemistry, Multidisciplinary
Alexey S. Galushko, Daniil A. Boiko, Evgeniy O. Pentsak, Dmitry B. Eremin, Valentine P. Ananikov
Summary: A method for characterizing supported catalysts in a spatially localized manner has been proposed. This approach utilizes various microscopes to track the evolution of metal particles, including individual atoms, in catalytic reactions. By studying the behavior of palladium atoms and nanoparticles, it was discovered that single atoms leach out into solution and exhibit higher catalytic activity compared to surface nanoparticles. These findings challenge the assumption that the superior catalytic activity comes from the operation of single atomic catalytic centers on the surface of the support.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Runyou Ye, Maoshuai Zhu, Xufei Yan, Yang Long, Ying Xia, Xiangge Zhou
Summary: This study reveals a chelation-assisted palladium-catalyzed C=C bond cleavage reaction to form alkenyl nitrile, based on a formal group-exchange reaction. The isolated active Pd(II) complex and deuterium-labeled experiment confirm the necessity of the chelation group, proposing a plausible catalytic pathway.
Article
Chemistry, Inorganic & Nuclear
Alexey S. Galushko, Darya O. Prima, Julia V. Burykina, Valentine P. Ananikov
Summary: Catalytic transformations involving aryl chlorides are challenging, even though the slow oxidative addition to palladium catalyst is usually considered the main reason for low reactivity. However, other factors were found to also significantly influence the reactivity of aryl halides, suggesting a need for a substantial revision of catalyst design principles.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Inorganic & Nuclear
Bahram Ahmadi Baloutaki, Mohammad Hosein Sayahi, Mohammad Nikpassand, Hassan Kefayati
Summary: In this study, a novel catalyst was designed, synthesized, and characterized by functionalizing magnetic iron oxide nanoparticles with terpyridine to immobilize palladium. The catalyst demonstrated excellent activity in carbon-carbon bond formation reactions, such as Heck and Suzuki reactions. Furthermore, the catalyst showed magnetic recoverability and maintained high activity even after 10 sequential reactions.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2021)
Article
Toxicology
Marta Siczek, Marcin Zawadzki, Milosz Siczek, Agnieszka Chlopas-Konowalek, Pawel Szpot
Summary: This study aimed to present the spectroscopic characteristics and crystal structure of the benzimidazole opioid etazene, which has recently emerged on the illegal drug market in Poland. The compound was analyzed using X-ray crystallography, gas and liquid chromatography combined with mass spectrometry, as well as other spectroscopic techniques. The authors described the identification and chemical characterization of etazene, highlighting its importance for the detection of new psychoactive substances in forensic and clinical laboratories.
FORENSIC TOXICOLOGY
(2021)
Article
Chemistry, Physical
Algirdas Ducinskas, Gee Yeong Kim, Davide Moia, Alessandro Senocrate, Ya-Ru Wang, Michael A. Hope, Aditya Mishra, Dominik J. Kubicki, Milosz Siczek, Wojciech Bury, Thomas Schneeberger, Lyndon Emsley, Joachim Maier, Jovana Milic, Michael Gratzel
Summary: While layered hybrid halide perovskites are generally believed to be more stable in humid conditions, this study reveals that the structure of Dion-Jacobson-type perovskites can be disrupted under such conditions. The original structure can be restored through annealing, and the hydration can be suppressed by generating a self-protective layer of PbI2.
ACS ENERGY LETTERS
(2021)
Article
Chemistry, Physical
Adam W. Augustyniak, Anna M. Trzeciak
Summary: Pd-nanocomposites fabricated from MOF showed enhanced catalytic activity and stability in the transfer hydrogenation of phenylacetylene, outperforming the pristine MOF material.
Article
Chemistry, Physical
M. Mart, A. M. Trzeciak
Summary: A new one-pot procedure for synthesizing β-enaminones was developed using a Pd/DNA catalyst and tertiary amine sources, resulting in successful synthesis of the target product and efficient recovery and reuse of the catalyst. The reaction mechanism involving the activity of immobilized Pd NPs was proposed.
MOLECULAR CATALYSIS
(2021)
Article
Chemistry, Inorganic & Nuclear
Adam W. Augustyniak, Anna M. Trzeciak
Summary: The palladium azolate/carboxylate network, Pd-dmpzc, catalyzes the selective hydrogenation of phenyl-acetylene to styrene in water. Under optimized conditions, Pd-dmpzc provided better results than other palladium catalysts, with analysis showing the presence of different Pd2+ species and Pd-0 NPs contributing to the catalytic reaction.
INORGANICA CHIMICA ACTA
(2021)
Article
Chemistry, Applied
Anna Skarzynska, Marta Kowalczyk, Mariusz Majchrzak, Marta Pietka, Adam W. Augustyniak, Milosz Siczek, Kinga Wlodarczyk, Aleksandra Simiczyjew, Dorota Nowak
Summary: Platinum complexes can serve as catalysts for Heck reactions and hydrosilylation, and also exhibit cytotoxicity towards triple negative breast cancer cells.
APPLIED ORGANOMETALLIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Neda Heydari, Rahman Bikas, Milosz Siczek, Tadeusz Lis
Summary: A Cu(II) complex [Cu(HL)(NO3)(CH3OH)]middotCH(3)OH (1) was synthesized by reacting Cu(NO3)2middot3H2O with H2L in methanol solvent. The structure of [Cu(HL)(NO3)(CH3OH)]middotCH(3)OH was determined by single-crystal X-ray analysis, showing that it is a mononuclear Cu(II) complex with a free NH2 functional group. The complex was supported on functionalized silica gel to prepare a heterogeneous catalyst (Si-Cu) which was characterized by various analytical techniques. Si-Cu exhibited good catalytic activity in carbon-carbon coupling reactions and showed stability for reuse.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Paulina Pachalska, Anna Skarzynska, Ines A. S. Matias, Anna M. Trzeciak
Summary: Borohydride imidazolium ionic liquids were used as reductants in the N-formylation of amines with CO2, resulting in excellent yield of formamides. Addition of halide imidazolium salts increased the selectivity to formamide, while some other ionic liquids had no effect on selectivity. Monitoring the reaction course using H-1 NMR provided new insights into the role of BH3 in the reduction of CO2 and functionalization of amines.
Article
Chemistry, Inorganic & Nuclear
Younes Mousazade, Subhajit Nandy, Rahman Bikas, Pavlo Aleshkevych, Keun Hwa Chae, Milosz Siczek, Tadeusz Lis, Suleyman I. Allakhverdiev, Mohammad Mahdi Najafpour
Summary: In the context of energy storage, the oxygen-evolution reaction (OER) through water-oxidation is an uphill reaction. Copper(II) coordination compounds have been widely used for OER, but understanding the mechanism in the presence of these compounds remains a challenge. This study investigates the electrochemical OER activity of a copper(II) coordination compound at pH 7 and focuses on the decomposition process.
DALTON TRANSACTIONS
(2022)
Article
Materials Science, Multidisciplinary
M. Wilk (Bieza), E. Tomaszewicz, M. Siczek, Y. Guyot, G. Boulon, M. Guzik
Summary: The structural and spectroscopic properties of a new optical material, La2MoWO9, were investigated. Micro-powder samples were obtained via solid-state reaction, and translucent micro-ceramics were demonstrated. Complementary techniques such as XRD, TEM/SEM, and high-resolution spectroscopic techniques were used for fundamental analysis, revealing the main features of this material.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
Marco Farinone, Monika Kijewska, Joanna Cybinska, Milosz Siczek, Milosz Pawlicki
Summary: Constructing monomeric subunits with carbonyl functionality allows for post-synthetic reactivity, leading to the formation of pi-extended defected units activated with BBr3. The choice between pyrido[2,3-g]quinoline and 4,7-phenanthroline motifs doped with boron(iii) is determined by kinetic or thermodynamic control, resulting in modulation of optical properties.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
W. Alsalahi, W. Tylus, A. M. Trzeciak
Summary: Pd/ZrO2 and PdO/ZrO2 composites show enhanced activity and selectivity in the hydrogenation reaction of acetophenone in aqueous solution.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Anna M. Szczepkowska, Mateusz Janeta, Milosz Siczek, Wlodzimierz Tylus, Anna M. Trzeciak, Wojciech Bury
Summary: Two model porphyrin metal-organic frameworks were utilized for the incorporation of Rh(I) species through post-synthetic metallation, resulting in the synthesis and structural characterization of new rhodium MOFs (Rh/MOFs), Rh/PCN-222 and Rh/NU-1102. These Rh/MOFs were demonstrated to be active heterogeneous catalysts for the hydrogenation of unsaturated hydrocarbons at mild reaction conditions, with an activation step required during the initial run of the catalytic process. In situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) was utilized to monitor the activation pathway of the catalyst under a H-2 atmosphere.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Multidisciplinary
Tomasz Bereta, Ewa Mieczynska, Sylwia Ronka, Wlodzimierz Tylus, Anna M. Trzeciak
Summary: In the hydrogenation of acetophenone catalyzed by a new Pd/S-DVB catalyst, a solvent effect was found to impact the reaction efficiency. The solvent's hydrogen-bond-acceptance capacity correlates with the conversion of acetophenone, and binary mixtures of alcohol and water significantly decrease the reaction efficiency due to the microheterogeneity and blocking of the catalyst surface.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Angela Lis, Viorica Gladchi, Gheorghe Duca, Sergey Travin
Summary: This work presents studies on the photochemical transformations of TU and Cys with the addition of Cu(II) or Fe(III) ions. The results show that the oxidation rate of the thiols increases significantly when Cu(II) or Fe(III) ions are added to the system. It has also been found that TU and Cys can form stable complex compounds with the studied metal ions. The oxidation rates of the thiols are found to depend on the radiation intensity and emission spectrum of the irradiation sources.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Cristiane F. A. Teixeira, Estefane I. Teixeira, J. P. C. Nascimento, M. Amilcar Junior, L. M. C. Pinto, Anderson R. L. Caires, G. B. Alcantara, Ana C. Micheletti, Victor M. Deflon, Davi F. Back, Heveline Silva, Lucas Pizzuti, Gleison Antonio Casagrande
Summary: Novel binuclear heteroleptic copper(I) complexes based on mixed DPPE/thiocarbamoyl-pyrazoline ligands were synthesized and structurally characterized. These complexes exhibited similar structural behavior around the Copper(I) atoms and showed promising antimicrobial and anticancer activities.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Chen Chen, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Hai-Mei Qin
Summary: Thermally activated delayed fluorescent (TADF) Cu(I) halide complexes with short lifetimes and intense emissions were synthesized and characterized. These complexes exhibit intense green to yellow-green delayed fluorescence and are suitable for OLED devices.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Tian-Yu Zhang, Xue-Qian Wu, Heng-Yu Ruan, Yi Yuan, Le Wang, Ya-Pan Wu, Qing-Wen Han, Ruan Chi, Dong-Sheng Li
Summary: In this study, a novel Ni(II)-based metal-organic framework with good electrocatalytic oxidation performance was successfully synthesized, showing potential for direct alcohol fuel cells.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Susanta Das Baishnab, R. N. Dutta Purkayastha, Waldemar Maniukiewicz, Rosa M. Gomila, Antonio Frontera
Summary: The synthesis, structure, and DNA binding ability of three decavanadate complexes containing cationic organic moieties were reported. The complexes were characterized by various techniques and their solid-state structures were analyzed. The complexes showed interesting assembly patterns and exhibited moderately strong intercalative binding with CTDNA. Additionally, their micellization behavior in the presence of the surfactant CTAB was studied.
INORGANICA CHIMICA ACTA
(2024)
Review
Chemistry, Inorganic & Nuclear
Jubaraj B. Baruah
Summary: Isomorphous series are generated by replacing atoms or molecules to form materials with similar compositions. They allow modulation of structure and properties, and generate equivalent compositions with novel material properties. The study of stereo-electronic aspects of different equivalent compositions can improve the utility of the original composition.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Kamelah S. Al-Rashdi, Bandar A. Babgi, Ehab M. M. Ali, Bambar Davaasuren, Abdul-Hamid M. Emwas, Mariusz Jaremko, Mark G. Humphrey, Mostafa A. Hussien
Summary: Tridentate ligands were used to synthesize a set of palladium complexes, which were characterized and found to have DNA and BSA binding abilities. The complexes also showed differences in anticancer activities.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Diane Isaacs, Chandler Cox, Mark A. Bezpalko, W. Scott Kassel, William G. Dougherty
Summary: The structure and electrochemical properties of zinc(II) complexes with a face-capping ligand have been investigated, revealing the effect of the ligand on bound semiquinonate (SQ) radicals. The substitution pattern of the SQ ring plays a crucial role in determining the fate of the bound SQ radicals. Additionally, the protective pocket formed by the ligand's phenyl substituents is unable to prevent decomposition of SQ radicals with minimal steric bulk, suggesting that substitution of the SQ ring is the main contributor to their stabilization.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Xingliang Chen, Zhiqiang Jiang
Summary: Here, a series of zinc tetrahedral tetrazolate frameworks (Zn-TTFs) are presented, and it is demonstrated that rotation of carboxyl group can generate structural diversity. Compound 3 exhibits a unique zeolite-like structure, while compound 4 shows both super acid and alkali resistance.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Ankita Puri, Allison Mcaninch, Sheng Shu, Khashayar Rajabimoghadam, Maxime A. Siegler, Marcel Swart, Isaac Garcia-Bosch
Summary: In this article, the synthesis and characterization of copper, nickel, and palladium complexes bound by bidentate ligands derived from ortho-phenylenediamine are described. The complexes contain tunable H-bond donors and their crystal structures reveal intramolecular H-bonding interactions between the ligand scaffolds. Variations in the coordination sphere led to the isolation of the complexes in square-planar or twisted pseudo-tetrahedral geometries. Structural analysis showed that intramolecular H-bonding interactions can be altered by disrupting the bonds between countercations, solvent of crystallization, and ligand scaffold, resulting in changes in the geometry of the complexes. DFT calculations confirmed that Cu complexes prefer twisted geometries while Ni and Pd complexes favor square-planar geometries.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Laiane dos Santos Oliveira, Pedro Henrique de Souza Guarda, Leticia Bazilio Rosa, Gustavo Clauss Rodrigues, Daniele Daiane Affonso, Joao Ernesto de Carvalho, Igor Andrade Santos, Mark Harris, Douglas Hideki Nakahata, Jose Ricardo Sabino, Danilo Ciccone Miguel, Ana Lucia Tasca Gois Ruiz, Ana Carolina Gomes Jardim, Camilla Abbehausen
Summary: Chalcones are chemical precursors of flavonoids that have various biological properties. In this study, novel copper(II)-2'-hydroxy-4-benzyloxychalcone complexes were synthesized and evaluated for their antileishmanial, antiproliferative, and antiviral activities. The results demonstrated that these complexes showed potential effects against tumor cells, leishmania parasites, and SARS-CoV-2 virus. The study also highlighted the influence of ligand structure on biological activity.
INORGANICA CHIMICA ACTA
(2024)
Review
Chemistry, Inorganic & Nuclear
Archana Thakur, Harpreet Kaur, Vishal Tyagi
Summary: This review article discusses the findings of research on the 13C NMR spectra of di- and tri-butyltin carboxylates, highlighting the importance of 13C NMR chemical shifts in determining the chemical surroundings of carbon nuclei and their role in structure elucidation.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Qiang Zhao, Qi-Yang Li, Zhi Shen, Guo Zang, Wen-Jun Lv
Summary: In this study, five metal complexes were synthesized using a solvothermal reaction and their structures were analyzed by single crystal X-ray diffraction. Fluorescence and magnetic properties of some complexes were also investigated.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Jeremy Erb, Darcy Setter, Jake Swavey, Frederick Willits, Shawn Swavey
Summary: Three BODIPY-Ru(II) complexes were synthesized by coordinating [Ru(bpy)2Cl]+ complexes to BODIPY ligands. The spectroscopic and electrochemical properties of the complexes were characterized. The complexes exhibited intense absorption peaks due to the pi pi* transitions localized on the BODIPY core, and additional charge transfer transitions associated with the metal center. The complexes showed significant singlet oxygen generation and were able to induce photo-nicking of DNA.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Sahin Reja, Dilip Sarkar, Kaushik Sarkar, Deboshmita Mukherjee, T. K. S. Fayaz, Palash Sanphui, Rajesh Kumar Das
Summary: A promising bioinspired metallocatalyst has been produced and characterized, showing high catalytic activity in oxygen dependant enzymatic radical pathway. The catalyst also exhibits inter and intra molecular H-bonding and C-H-pi interactions.
INORGANICA CHIMICA ACTA
(2024)
