Article
Chemistry, Inorganic & Nuclear
Katherine L. Meehan, Devon Fa Fontaine, Alistair D. Richardson, Samantha M. Fowles, Benjamin Mukda, Jeffrey C. Monroe, Christopher P. Landee, Diane A. Dickie, Mark M. Turnbull, Shu Jiang, Fan Xiao
Summary: In this study, a family of Ni(II) halide complexes of substituted aniline derivatives were prepared and characterized using single-crystal X-ray diffraction and magnetic measurements. The complexes exhibit variable stability and show different properties upon the loss of coordinated solvent molecules. Analysis of the magnetic properties reveals the presence of single-ion anisotropy, weak interactions, or a combination of both.
Article
Chemistry, Inorganic & Nuclear
S. Thalamuthu, M. A. Neelakantan
Summary: A novel phenolato and acetato bridged trinuclear Ni(II) complex [Ni3L2] was synthesized and characterized, showing catalytic activity in urea hydrolysis similar to jack bean urease at the molecular level.
INORGANICA CHIMICA ACTA
(2021)
Article
Chemistry, Inorganic & Nuclear
Erik T. Ouellette, Julian S. Magdalenski, Robert G. Bergman, John Arnold
Summary: We report the synthesis and characterization of a novel rhenium-group 9 heterobimetallic diazenido species and its related diazenido and hydride complexes. Furthermore, we demonstrate the possibility of N-C bond formation in heterobimetallic complexes and investigate their properties using spectroscopy and computational studies.
INORGANIC CHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Lukas Masaryk, Barbora Tesarova, Duane Choquesillo-Lazarte, Vedran Milosavljevic, Zbynek Heger, Pavel Kopel
Summary: In this study, a nickel(II) coordination compound with interesting biological behavior was synthesized, showing higher uptake by malignant cells, significant cytotoxicity differences, and the ability to hydrolyze DNA.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2021)
Article
Chemistry, Physical
Weifeng Huang, Jianxin Kang, Tingwen Chen, Dawei Pang, Lihua Wang, Hang Wei, Changchun Yang, Dongfeng Zhang, Lin Guo
Summary: Nickel based magnetic nanocrystals have wide applications in magnetic and catalytic fields. Tunable magnetic properties of nickel can be achieved through non-magnetic doping or phase transformation. This study presents a way to control the magnetism of Au@Ni-carbide magnetic materials by adjusting the amount of carbon in the Ni layer, and provides solid evidence for the carbonation process from fcc-Ni to Ni X C instead of phase transformation to hcp-Ni. Further investigation reveals that the magnetism of the hybrids is mainly contributed from the residual fcc-Ni.
Article
Chemistry, Inorganic & Nuclear
Soumen Sinhababu, Neal P. Mankad
Summary: A study on a heterobimetallic Al-Fe complex revealed its diverse reaction chemistry, demonstrating its versatility in various reactions.
Article
Chemistry, Physical
Fei Yuan, Yan Wu, Chun-Mei Yuan, Hai-Xia Ma, Cheng-Fang Qiao, Bao-Yue Cao, Chun-Sheng Zhou, Devyani Srivastava, Abhinav Kumar
Summary: Three new complexes with similar mononuclear structures have been synthesized and characterized. They form 3D supramolecular networks through intermolecular hydrogen bonding and π-π stacking interactions. The weak interactions in their frameworks have been assessed using Hirshfeld surface analyses. The thermal stabilities, magnetic and photoluminescence properties of these complexes have also been investigated.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Inorganic & Nuclear
Arghya Dutta, Arnab Chatterjee, Tathagata Sarkar, Shubhamoy Chowdhury, Vinayak B. Kamble, Rajarshi Ghosh
Summary: The sulphur bridged pentanuclear Pd(II) complex displays electrical conductivity at room temperature, with conductivity increasing exponentially as temperature rises, showing behavior ranging from metallic to semiconductor-like.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Chao Yue Zhang, Xuan Lu, Xu Han, Jing Yu, Chaoqi Zhang, Chen Huang, Lluis Balcells, Alba Garzon Manjon, Jordi Jacas Biendicho, Junshan Li, Jordi Arbiol, Gengzhi Sun, Jin Yuan Zhou, Andreu Cabot
Summary: This study investigates the influence of the geometric configuration and composition of ABX spinel catalysts on their catalytic mechanisms and polysulfide conversion. The results show that Co-oh (3+) serves as the active site for breaking S-S bonds, while Co-td (2+) functions as the active site for forming S-Na bonds. This research highlights the subtle relationship between the activity and geometric configuration of spinel catalysts, offering insights for the rational development of improved catalysts by optimizing their atomic geometric configuration.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Inorganic & Nuclear
Li-Cheng Song, Yin-Peng Wang, Yi-Xiong Dong, Xi-Yue Yang
Summary: A series of new biomimetics for the active site of [NiFe]-H(2)ases have been prepared using various synthetic methods. These biomimetics can catalyze proton reduction to generate hydrogen and undergo a range of chemical reactions.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Elif Avcu Altiparmak, Sibel Yazar, Namik Ozdemir, Tulay Bal-Demirci, Bahri Ulkuseven
Summary: Copper(II) and nickel(II) mixed ligand complexes synthesized from 4-methoxysalicylaldehyde-N-phenylthiosemicarbazone and 3,5-lutidine were characterized using various techniques, showing antioxidant capacity for both the ligand and its metal complexes.
Article
Chemistry, Inorganic & Nuclear
Hassan Keypour, Azar Tafazzoli, Seyed Hamed Moazzami Farida, Molood Abdollahi-Moghadam, Robert William Gable
Summary: A new hexaaza Schiff base ligand with a piperazine ring was synthesized and characterized. A novel complex of the ligand with nickel was prepared and characterized, showing a distorted octahedral environment around the nickel ion. The anti-cancer activity and antioxidant property of the ligand and complex were evaluated, and the binding mode of the ligand to nickel ion was investigated using DFT calculations. Theoretical and experimental findings were in agreement.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Iaroslav Doroshenko, Lucie Simonikova, Zdenek Moravec, Jan Vanco, Zdenek Travnicek, Jiri Pinkas
Summary: In this study, a dinuclear copper phosphonate and two related complexes were synthesized, and their structures were determined using single-crystal X-ray diffraction. Complex 2 formed a 1D chain structure through substitution of water ligands, while complex 3 resulted from the splitting of the dinuclear copper phosphonate into an ionic complex due to the chelating effect of the ligands.
Article
Chemistry, Physical
Sadia Nazir, Tehreem Naz, Muhammad Nazir Tahir, Muhammad Abid Rashid, Muhammad Yaseen, Adrian Charles Whitwood
Summary: The X-ray crystallographic and physicochemical investigation of a newly synthesized nickel coordination complex is presented in this manuscript. The study reveals the spontaneous solubilization of the complex in micelles, driven by enthalpy and entropy, as well as the interaction of the complex with surfactant leading to red-shift in UV-Vis spectra.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Azeem Shakeel, Hamed Bakhshi, Touqeer Ahmed, Lara Watanabe, Mark M. Turnbull, Ahmed Al-Harrasi, Muhammad U. Anwar
Summary: A new class of heterometallic hexanuclear Mn4Ln2 systems has been prepared using the ditopic ligand L4, which contains a carbohydrazide with terminal pyridyl moieties. The complexes exhibit ferromagnetic exchange interactions, and complex 2 shows slow relaxation of magnetization. The findings provide insights into the magnetic properties of these heterometallic systems.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Inorganic & Nuclear
Kuheli Pramanik, Zvonko Jaglicic, Radovan Herchel, Paula Brandao, Narayan Ch. Jana, Anangamohan Panja
Summary: A series of Ln(III) complexes with different ligands were synthesized and characterized. Some of the complexes exhibited zero field single-molecule magnet behavior, while others showed field-induced single-molecule magnet behavior. The single-molecule magnet performance was significantly enhanced by introducing a methyl substitution in the ligand framework.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Ivana Loubalova, Eva Zahradnikova, Lukas Masaryk, Ivan Nemec, Lucie Hochvaldova, Ales Panacek, Libor Kvitek, Renata Vecerova, Marcin Swiatkowski, Pavel Kopel
Summary: A series of nickel and copper complexes were synthesized and characterized. These complexes exhibited moderate antibacterial activity and could potentially be used to treat skin wounds.
INORGANICA CHIMICA ACTA
(2023)
Article
Pharmacology & Pharmacy
Zdenek Travnicek, Tomas Malina, Jan Vanco, Marek Sebela, Zdenek Dvorak
Summary: The paper describes the synthesis and characterization of six heteroleptic copper(II) complexes with different ligands. The results showed that complex 2 exhibited high cytotoxicity against cancer cells, while showing low toxicity against healthy cells. Further experiments revealed that complex 2 induced apoptosis and autophagy in A2780 cancer cells through the activation of caspases 3/7, ROS overproduction, and autophagy induction.
Article
Chemistry, Multidisciplinary
Nikoleta Malinova, Jana Jurakova, Barbora Brachnakova, Jana Dubnicka Midlikova, Erik Cizmar, Vinicius Tadeu Santana, Radovan Herchel, Milan Orlita, Ivan Mohelsky, Jan Moncol, Petr Neugebauer, Ivan Salitros
Summary: The synthesis of a mononuclear Co(II) complex 1 using a novel tridentate ligand L was investigated. The molecular structure of complex 1 was confirmed by single-crystal X-ray structural analysis and noncovalent contacts were examined. The magnetic properties of complex 1 were analyzed using the Griffith-Figgis Hamiltonian, and calculations and spectroscopic study showed good agreement. The AC magnetic investigation revealed slow relaxation of magnetization in complex 1 with involvement of direct, Raman, and Orbach processes.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Chemistry, Multidisciplinary
Biswarup Dutta, E. Carolina Sanudo, Radovan Herchel, Debashis Ray
Summary: This study discovered two different types of mixed-valence tetranuclear cobalt complexes through the reaction of the multisite ligand H3L with Co(ClO4)2 center dot 6H2O in the presence of ancillary ligands NaPiv and NH4SCN. The first type of complex achieved connectivity for different numbers of CoIII and CoII ions through water-molecule-derived HO- plus O2- linkers and ligand-anion-based double phenolato bridges, while the second type achieved aggregation through terminal thiocyanate coordination. The structural distortions in these two types of aggregates lead to different magnitudes of easy-axis magnetic anisotropy and a small but non-negligible transverse component.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Chemistry, Multidisciplinary
Ivan Nemec, Lucie Kotaskova, Radovan Herchel
Summary: We crystallized the Schiff-base iron(III) spin-crossover complex [Fe(3,5Cl-L5)(NCSe)] from different solvent mixtures and found significant differences in magnetic properties. The crystal structures of the low-spin and high-spin phases were studied both theoretically and experimentally.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Crystallography
Tomas Silha, Radovan Herchel, Ivan Nemec
Summary: A series of five novel Mn-salen-based compounds (1a-1c, 2a, 2b) were synthesized through the reaction between precursor chloride complexes and potassium silver/gold dicyanide. The compounds were structurally and magnetically characterized. The findings revealed that the Mn(III) central atoms exhibited axial magnetic anisotropy, and weak magnetic exchange was observed in compounds with a special supramolecular topology involving O-H···O hydrogen-bonded dimers.
Article
Chemistry, Inorganic & Nuclear
Radka Krikavova, Michaela Romanovova, Zuzana Jendzelovska, Martin Majernik, Lukas Masaryk, Pavel Zoufaly, David Milde, Jan Moncol, Radovan Herchel, Rastislav Jendzelovsky, Ivan Nemec
Summary: Half-sandwich complexes with thiadiazole-based ligand showed hydrolytic stability, catalytic activity, and selective inhibitory effects on cancer cells.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Jana Jurakova, Ondrej F. Fellner, Soren Schlittenhardt, Sarka Vavreckova, Ivan Nemec, Radovan Herchel, Erik Cizmar, Vinicius Tadeu Santana, Milan Orlita, Denis Gentili, Giampiero Ruani, Massimiliano Cavallini, Petr Neugebauer, Mario Ruben, Ivan Salitros
Summary: Two new hexacoordinated Co(II)-based single-ion magnets were synthesized and characterized. The complexes exhibited metal-centered coordination with nitrate anions and a 2,6-bis(1H-benzimidazole-2-yl)pyridine ligand with n-octyl or n-dodecyl chains. The presence of long aliphatic chains allowed for their solubility in low polarity and volatile solvents, enabling the preparation of microstructural layers and patterns on relevant substrates using wet lithographic techniques. The complexes displayed positive axial D parameters and showed field-induced slow relaxation of magnetization.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Inorganic & Nuclear
Biswarup Dutta, Thierry Guizouarn, Fabrice Pointillart, Kamil Kotrle, Radovan Herchel, Debashis Ray
Summary: A new family of binuclear Ni-II-Ln(III) complexes [NiLn(L)(2)(NO3)(3)]0.5H(2)O (Ln = Gd, 1; Tb, 2; Dy, 3; Ho, 4; Er, 5; Yb, 6; Y, 7) was synthesized using a thioether group-bearing Schiff base. These complexes exhibit distorted pseudo-octahedral geometry for the Ni-II center and distorted bicapped square-antiprism geometry for the Ln(III) centers. The study highlights the mutual distortion of coordination geometry induced by the flexibility of the ligand backbone and the simultaneous binding of two different metal ions.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Multidisciplinary
Narayan Ch. Jana, Marko Jagodic, Paula Brandao, Moumita Patra, Radovan Herchel, Zvonko Jaglicic, Anangamohan Panja
Summary: Six new Ni-II complexes with different N3O donor Schiff base ligands have been synthesized and characterized, showing ferromagnetic interaction through bridging pseudohalides. The cyanate-bridged complexes have lower ferromagnetic coupling constant J compared to azide analogues due to the presence of polarizable p systems and two different N and O donor atoms. The inclusion of these new complexes in the series of mu(1,1)-NCO bridged systems allows for a detailed analysis of the magneto-structural correlation, revealing that the J value increases with an increase in bridging angles and is also influenced by the Ni1-Ni2-N-b-X-t dihedral angle.
Article
Biochemistry & Molecular Biology
Zdenek Travnicek, Jan Vanco, Jan Belza, Jan Hosek, Zdenek Dvorak, Rene Lenobel, Igor Popa, Karel Smejkal, Pavel Uhrin
Summary: Motivated by the success of Auranofin, a gold(I) metallotherapeutic, in treating inflammation and cancer, the researchers prepared and characterized a [Au(kin)(PPh3)] complex (1) with kinetin. In vitro studies showed that complex (1) had significant cytotoxicity against human cancer cell lines, outperforming Cisplatin and comparable to Auranofin. Furthermore, it was found to positively influence PPAR gamma, reducing inflammation. The cellular effects of complex (1) were also investigated, revealing its impact on cell cycle, apoptosis, ROS production, caspase activation, mitochondrial membrane potential, and proteomic analysis.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Inorganic & Nuclear
Petr Halas, Ivan Nemec, Radovan Herchel
Summary: The hexacoordinate Co(II) complex [Co(neo)2(cin)][BPh4]center dot 1/2Me2CO was synthesized and characterized. The complex exhibits large magnetic anisotropy and slow magnetization relaxation under an applied field, behaving as a field-induced single-molecule magnet.
Article
Chemistry, Physical
Jorge Navarro Giraldo, Jakub Hruby, Sarka Vavreckova, Ondrej F. Fellner, Lubomir Havlicek, Davonne Henry, Shehan de Silva, Radovan Herchel, Miroslav Bartos, Ivan Salitros, Vinicius T. Santana, Paola Barbara, Ivan Nemec, Petr Neugebauer
Summary: This study presents both theoretical and experimental investigations of two tetracoordinate Co(ii)-based complexes with semi-coordination interactions. The results show that these interactions enhance the thermal and structural stability of the compounds, allowing successful deposition on graphene. The compounds exhibit axial magnetic anisotropy and weak intermolecular antiferromagnetic coupling, as confirmed by various experimental techniques and theoretical calculations. Additionally, the study explores the electrical properties of these compounds on graphene and demonstrates electron transfer-induced n-type doping of graphene.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Inorganic & Nuclear
Weiyang Li, Xiaochun Li, Koen Robeyns, Mariusz Wolff, Joseph Kfoury, Julianna Olah, Radovan Herchel, Serhiy Demeshko, Franc Meyer, Yann Garcia
Summary: In this study, two new types of edge-bridged spin crossover supramolecular cages were constructed, and their magnetic properties were investigated in the presence of different solvents and anions.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Angela Lis, Viorica Gladchi, Gheorghe Duca, Sergey Travin
Summary: This work presents studies on the photochemical transformations of TU and Cys with the addition of Cu(II) or Fe(III) ions. The results show that the oxidation rate of the thiols increases significantly when Cu(II) or Fe(III) ions are added to the system. It has also been found that TU and Cys can form stable complex compounds with the studied metal ions. The oxidation rates of the thiols are found to depend on the radiation intensity and emission spectrum of the irradiation sources.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Cristiane F. A. Teixeira, Estefane I. Teixeira, J. P. C. Nascimento, M. Amilcar Junior, L. M. C. Pinto, Anderson R. L. Caires, G. B. Alcantara, Ana C. Micheletti, Victor M. Deflon, Davi F. Back, Heveline Silva, Lucas Pizzuti, Gleison Antonio Casagrande
Summary: Novel binuclear heteroleptic copper(I) complexes based on mixed DPPE/thiocarbamoyl-pyrazoline ligands were synthesized and structurally characterized. These complexes exhibited similar structural behavior around the Copper(I) atoms and showed promising antimicrobial and anticancer activities.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Chen Chen, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Hai-Mei Qin
Summary: Thermally activated delayed fluorescent (TADF) Cu(I) halide complexes with short lifetimes and intense emissions were synthesized and characterized. These complexes exhibit intense green to yellow-green delayed fluorescence and are suitable for OLED devices.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Tian-Yu Zhang, Xue-Qian Wu, Heng-Yu Ruan, Yi Yuan, Le Wang, Ya-Pan Wu, Qing-Wen Han, Ruan Chi, Dong-Sheng Li
Summary: In this study, a novel Ni(II)-based metal-organic framework with good electrocatalytic oxidation performance was successfully synthesized, showing potential for direct alcohol fuel cells.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Susanta Das Baishnab, R. N. Dutta Purkayastha, Waldemar Maniukiewicz, Rosa M. Gomila, Antonio Frontera
Summary: The synthesis, structure, and DNA binding ability of three decavanadate complexes containing cationic organic moieties were reported. The complexes were characterized by various techniques and their solid-state structures were analyzed. The complexes showed interesting assembly patterns and exhibited moderately strong intercalative binding with CTDNA. Additionally, their micellization behavior in the presence of the surfactant CTAB was studied.
INORGANICA CHIMICA ACTA
(2024)
Review
Chemistry, Inorganic & Nuclear
Jubaraj B. Baruah
Summary: Isomorphous series are generated by replacing atoms or molecules to form materials with similar compositions. They allow modulation of structure and properties, and generate equivalent compositions with novel material properties. The study of stereo-electronic aspects of different equivalent compositions can improve the utility of the original composition.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Kamelah S. Al-Rashdi, Bandar A. Babgi, Ehab M. M. Ali, Bambar Davaasuren, Abdul-Hamid M. Emwas, Mariusz Jaremko, Mark G. Humphrey, Mostafa A. Hussien
Summary: Tridentate ligands were used to synthesize a set of palladium complexes, which were characterized and found to have DNA and BSA binding abilities. The complexes also showed differences in anticancer activities.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Diane Isaacs, Chandler Cox, Mark A. Bezpalko, W. Scott Kassel, William G. Dougherty
Summary: The structure and electrochemical properties of zinc(II) complexes with a face-capping ligand have been investigated, revealing the effect of the ligand on bound semiquinonate (SQ) radicals. The substitution pattern of the SQ ring plays a crucial role in determining the fate of the bound SQ radicals. Additionally, the protective pocket formed by the ligand's phenyl substituents is unable to prevent decomposition of SQ radicals with minimal steric bulk, suggesting that substitution of the SQ ring is the main contributor to their stabilization.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Xingliang Chen, Zhiqiang Jiang
Summary: Here, a series of zinc tetrahedral tetrazolate frameworks (Zn-TTFs) are presented, and it is demonstrated that rotation of carboxyl group can generate structural diversity. Compound 3 exhibits a unique zeolite-like structure, while compound 4 shows both super acid and alkali resistance.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Ankita Puri, Allison Mcaninch, Sheng Shu, Khashayar Rajabimoghadam, Maxime A. Siegler, Marcel Swart, Isaac Garcia-Bosch
Summary: In this article, the synthesis and characterization of copper, nickel, and palladium complexes bound by bidentate ligands derived from ortho-phenylenediamine are described. The complexes contain tunable H-bond donors and their crystal structures reveal intramolecular H-bonding interactions between the ligand scaffolds. Variations in the coordination sphere led to the isolation of the complexes in square-planar or twisted pseudo-tetrahedral geometries. Structural analysis showed that intramolecular H-bonding interactions can be altered by disrupting the bonds between countercations, solvent of crystallization, and ligand scaffold, resulting in changes in the geometry of the complexes. DFT calculations confirmed that Cu complexes prefer twisted geometries while Ni and Pd complexes favor square-planar geometries.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Laiane dos Santos Oliveira, Pedro Henrique de Souza Guarda, Leticia Bazilio Rosa, Gustavo Clauss Rodrigues, Daniele Daiane Affonso, Joao Ernesto de Carvalho, Igor Andrade Santos, Mark Harris, Douglas Hideki Nakahata, Jose Ricardo Sabino, Danilo Ciccone Miguel, Ana Lucia Tasca Gois Ruiz, Ana Carolina Gomes Jardim, Camilla Abbehausen
Summary: Chalcones are chemical precursors of flavonoids that have various biological properties. In this study, novel copper(II)-2'-hydroxy-4-benzyloxychalcone complexes were synthesized and evaluated for their antileishmanial, antiproliferative, and antiviral activities. The results demonstrated that these complexes showed potential effects against tumor cells, leishmania parasites, and SARS-CoV-2 virus. The study also highlighted the influence of ligand structure on biological activity.
INORGANICA CHIMICA ACTA
(2024)
Review
Chemistry, Inorganic & Nuclear
Archana Thakur, Harpreet Kaur, Vishal Tyagi
Summary: This review article discusses the findings of research on the 13C NMR spectra of di- and tri-butyltin carboxylates, highlighting the importance of 13C NMR chemical shifts in determining the chemical surroundings of carbon nuclei and their role in structure elucidation.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Qiang Zhao, Qi-Yang Li, Zhi Shen, Guo Zang, Wen-Jun Lv
Summary: In this study, five metal complexes were synthesized using a solvothermal reaction and their structures were analyzed by single crystal X-ray diffraction. Fluorescence and magnetic properties of some complexes were also investigated.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Jeremy Erb, Darcy Setter, Jake Swavey, Frederick Willits, Shawn Swavey
Summary: Three BODIPY-Ru(II) complexes were synthesized by coordinating [Ru(bpy)2Cl]+ complexes to BODIPY ligands. The spectroscopic and electrochemical properties of the complexes were characterized. The complexes exhibited intense absorption peaks due to the pi pi* transitions localized on the BODIPY core, and additional charge transfer transitions associated with the metal center. The complexes showed significant singlet oxygen generation and were able to induce photo-nicking of DNA.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Sahin Reja, Dilip Sarkar, Kaushik Sarkar, Deboshmita Mukherjee, T. K. S. Fayaz, Palash Sanphui, Rajesh Kumar Das
Summary: A promising bioinspired metallocatalyst has been produced and characterized, showing high catalytic activity in oxygen dependant enzymatic radical pathway. The catalyst also exhibits inter and intra molecular H-bonding and C-H-pi interactions.
INORGANICA CHIMICA ACTA
(2024)
