Article
Chemistry, Multidisciplinary
Jan Alfuth, Olivier Jeannin, Marc Fourmigue
Summary: The face-to-face association of bpen molecules stabilized by chalcogen bonding provides a photoreactive system for [2+2] photodimerizations. Design and synthesis of chelating chalcogen bond donors are crucial for the study of intramolecular ChB interactions.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Ji-Xin Jing, Nian Shi, Yan-Qiong Sun, Xin-Xiong Li, Shou-Tian Zheng
Summary: A novel inorganic organic hybrid lanthanide polyoxotungstogermanate was directly prepared using raw materials by hydrothermal synthesis method and characterized by various analytical techniques. The compound exhibits a unique crystal structure containing dimer anions and cations, and displays characteristic luminescent properties of Eu3+ ions.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Biochemistry & Molecular Biology
Xinlan Han, Jinhua Li, Siyu Tao, Guowei Dou, Sanawar Mansur, Xinqian Zhang
Summary: This study prepared environmentally stable organic-inorganic hybrid perovskite luminescent materials using Pb-MOF as a lead source through a mechanochemical method, and optimized the preparation conditions. The morphological characteristics and composition of the composite material were analyzed using electron microscopy, XRD and XPS. The results showed that the mechanochemical method has good universality in preparing organic-inorganic hybrid perovskite/MOF composites.
Article
Chemistry, Inorganic & Nuclear
Wei-Bo Ren, Sai Sun, Zhixin Gao, Bo Li, Xinyu Chen, Qianqian Liu, Hong-Ying Zang
Summary: In this study, metal phosphovanadate materials with high proton conductivity were successfully synthesized by controlling the structure and enhancing stability. These materials exhibited good performance in terms of high temperature and long-term stability, providing a new approach for the development and design of porous proton-conducting materials.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Teng-Fei Cao, Hao Xiao, Zhi-Huang Xu, Li-Wang Ye, Yuan-Jie Wang, Xin-Xin Zhuang
Summary: Two novel organic-inorganic hybrid single crystals were reported, showing long lifetime blue emission and characterized systematically for their thermal and photoluminescence properties. One compound displayed reversible phase transition and significant heat anomaly during DSC tests, leading to good switchable dielectric response and anisotropy. This work provides a new example in the effective design of multifunctional response materials.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Haruka Ikuma, Shunsuke Aoki, Kai Kawahara, Seiji Ono, Hironori Iwamatsu, Jun Kobayashi, Yoshiki Kiyota, Yosuke Okamura, Masashi Higuchi, Takeru Ito
Summary: Surfactants are functional molecules that can form nanometer-sized architectures. Bolaamphiphile surfactants with two hydrophilic heads are effective in constructing inorganic-organic hybrids. In this study, a hybrid crystal consisting of polyoxotungstate and a bolaamphiphile was successfully formed.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Multidisciplinary
Rishika Rai, Ravichandran Khazeber, Kana M. Sureshan
Summary: A covalent helical polymer was synthesized by biomimicry, which exhibited high strength and load-bearing capacity in its single crystals, making it suitable for various technological applications.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Inorganic & Nuclear
Kui Wang, Xiao-Fan Jiang, Xue-Ru Liu, Hao-Hao Liu, Qian Zhang, Jie Pan, Qi Wei, Li Wei
Summary: The compound was synthesized via solvothermal method, featuring a 3D hybrid framework and displaying blue photoluminescence.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Debobroto Sensharma, Daniel J. O'Hearn, Amin Koochaki, Andrey A. Bezrukov, Naveen Kumar, Benjamin H. Wilson, Matthias Vandichel, Michael J. Zaworotko
Summary: Hybrid ultramicroporous materials (HUMs) are modular materials composed of metal cations and combinations of inorganic and organic ligands, making them suitable for crystal engineering studies. They have practical significance due to their excellent gas separation performance in industrial gas mixtures. This study reports the design and synthesis of a sulfate-linked HUM and sets a benchmark for the difference in sorption heats between C2H2 and CO2 at low loadings.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Optics
Ruoxian Hou, Hanzhang Chen, Defu Sun, Nana Zhang, Chuanying Shen, Duanliang Wang
Summary: This research reports the synthesis, crystal structure, and optical properties of two new organic-inorganic hybrid materials. Transparent single crystals were successfully obtained using the solvent evaporation approach at room temperature. X-ray single crystal diffraction confirmed the layered structure of the crystals, with sulfamic acid and organics connected by hydrogen bonds. The optical properties of the crystals, including UV absorption and fluorescence spectra, were investigated, and the crystals exhibited low light absorption and distinct fluorescence characteristics.
Article
Chemistry, Inorganic & Nuclear
Yahui Li, Rui Zheng, Zhi-Hua Fu, Gang Xu, Guan-E Wang
Summary: This paper introduces the use of organic cations as structural templates to regulate the structure of inorganic anions, thereby controlling the luminescence properties of materials. Materials with one-dimensional structures exhibit typical semiconductor behavior and achieve controllable adjustment of fluorescent light color.
INORGANIC CHEMISTRY COMMUNICATIONS
(2022)
Article
Chemistry, Physical
A. Kaiba, Mohammed H. Geesi, P. Guionneau, Yassine Riadi, Talal A. Aljohani, Ammar Elsanousi, Oussama Ouerghi
Summary: A new organic-inorganic hybrid material with a two-dimensional perovskite structure has been successfully synthesized and characterized using micro-Raman spectroscopy technique. The compound's structure was solved, showing a combination of [Cd-0.5 Cl-3](-) anions, organic +NH3(CH2)CO2H cations, and water molecules forming hydrogen-bonding network for cohesion.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Multidisciplinary
De-Xuan Liu, Hao-Lin Zhu, Wei-Xiong Zhang, Xiao-Ming Chen
Summary: Melt-quenched glasses of organic-inorganic hybrid crystals have gained attention as a class of hybrid materials with good processability and formability. A new hybrid crystal with thermal-induced reversible crystal-liquid-glass-crystal transitions was reported. By using mild conditions, a hybrid glass-ceramic thin film with enhanced nonlinear optical effect was successfully fabricated.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Environmental Sciences
Chao-Yun Feng, Kang-Hong Wang, Shuangfei Li, Dong-Shen Liu, Zhen Yang
Summary: In this work, enzymatic methods using mushroom tyrosinase immobilized as enzyme-metal hybrid composites were developed for efficient removal of phenolic pollutants from industrial wastewaters. The immobilized enzymes showed superior dephenolization efficiency and reusability compared to other supports. The hybrid biocomposites demonstrated complete elimination of typical phenolic pollutants within a short time period and their operability and reusability were enhanced by entrapping or incorporating with magnetic nanoparticles. The magnetic biocatalyst exhibited high dephenolization efficiency after multiple cycles and continuous treatment for at least 24 hours.
Article
Engineering, Environmental
Xiaobing Cao, Lei Hao, Zijin Liu, Gengyang Su, Xin He, Qingguang Zeng, Jinquan Wei
Summary: Solvent engineering technology is important for fabricating high quality perovskite films and high-performance perovskite solar cells. However, the usage of toxic solvents poses a serious threat to health and the environment. This study presents an all green solvent engineering approach to prepare high quality perovskite films and achieve efficient solar cell performance, addressing the issue of solvent toxicity in perovskite film production.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Nanoscience & Nanotechnology
Kuaibing Wang, Saier Wang, Jiadi Liu, Yuxuan Guo, Feifei Mao, Hua Wu, Qichun Zhang
Summary: Two-dimensional Fe-based metal-organic framework (FeSC1) and one-dimensional coordination polymer (FeSC2) were synthesized through reaction among FeSO4 center dot 7H(2)O, the tripodal ligand 4,4',4 ''-s-triazine-2,4,6-triyl-tribenzoate (H(3)TATB), and flexible secondary building blocks p/m-bis((1H-imidazole-1-yl)methyl)benzene (bib). Both materials showed outstanding electrochemical performances, with charge storage mainly dominated by diffusion-controlled section through power-law equations (i proportional to v(0.5)). Long-term cycling loops also revealed partial phase transformations to more stable FeOOH.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Nanoscience & Nanotechnology
Cheng Zhang, Yang Li, Zhuang Li, Yucheng Jiang, Jinlei Zhang, Run Zhao, Jingyun Zou, Yanan Wang, Kuaibing Wang, Chunlan Ma, Qichun Zhang
Summary: In this study, a modified electrophoretic-induced self-assembly deposition (EPAD) technique was proposed to control the morphologies of organic functional materials. The EPAD approach can produce nanofiber structures under specific conditions, which are different from the nanopillar structures formed by conventional methods. Molecular dynamics simulations and density-functional theory (DFT) calculations were used to uncover the assembly process and the memory mechanism.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Inorganic & Nuclear
Yan Wang, Bei-Bei Yin, Wei Xu, Yun-Yun Zhang, Jing Liang, Ling-Long Fan, Ya-Jie Lu, Rong Hu, Ning-Ning Gao, Hao Jiang, Jia-Yin Sun, Xiao-Ming Kai
Summary: A new luminescent metal-organic framework (LMOF) was synthesized and characterized. The framework showed specific topological structures and could act as a sensitive and selective probe for the detection of Fe3+, CrO42-, and Cr2O72- ions.
JOURNAL OF COORDINATION CHEMISTRY
(2022)
Review
Chemistry, Inorganic & Nuclear
Ye Hong, Yuting Wang, Yuxuan Guo, Kuaibing Wang, Hua Wu, Cheng Zhang, Qichun Zhang
Summary: This article reviews the application of pillar-layered metal-organic frameworks (MOFs) in the field of supercapacitors. It discusses the roles of interpenetrating and non-interpenetrating MOFs and the strategies to improve their electrochemical performance as electrode materials for supercapacitors.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
(2022)
Article
Chemistry, Physical
Yan Wang, Yun-Yun Zhang, Xue-Hong Liao, Bei-Bei Yin, Yong Zhao, Ning-Ning Gao, Hao Jiang, Duo-Run Mao, Yi-Xin Yang
Summary: Two metal-organic frameworks were synthesized and structurally characterized. One of the frameworks showed turn-off luminescent sensing ability for Fe3+, CrO42-, and Cr2O72- ions.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Multidisciplinary
Bei B. Yin, Ning N. Gao, An R. Xu, Jing Liang, Li J. Wang, Yan Wang
Summary: In this study, a new complex was synthesized and characterized using various techniques. The complex exhibited multi-response photoluminescence sensing properties and showed excellent selectivity and sensitivity towards certain sewage and antibiotics.
Article
Chemistry, Multidisciplinary
Ye Hong, Tianqi Chen, Kuaibing Wang, Changyun Chen, Cheng Zhang, Hua Wu
Summary: A coordination polymer precursor, Ni-TATB, was synthesized and studied for its electrochemical performance after calcination at different temperatures. Lower calcination temperatures below 370 degrees Celsius were found to enhance the electrochemical performance, while higher temperatures led to a decrease in performance. The Ni-TATB-365 electrode showed the highest specific capacity and energy density, making it a promising candidate for powering LEDs.
Article
Chemistry, Physical
Bing Jin, Changyun Chen, Ye Hong, Jiadi Liu, Kuaibing Wang, She Tang, Cheng Zhang, Qichun Zhang
Summary: In this study, a composite of double-carbon matrix (CNTs and meso-C)-supported K-MnO2 was synthesized by combining carbon nanotubes and mesoporous carbon materials. The composite exhibited redox pseudocapacitor behavior in neutral aqueous electrolyte, with high specific capacity and ultrahigh potential range.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Inorganic & Nuclear
Ning Ning Gao, Bei Bei Yin, Zhang Xia Wang, Hui Sun, Yan Wang
Summary: In this paper, a new sensor [Cd(HPA)(3-bpmh)](n) (1), based on 3-bpmh ligand and H(2)HPA, is studied. The sensor shows the ability to detect Fe3+, Cr6+ and Nitrofurazone antibiotic in water, which was confirmed by X-ray crystallography, infrared spectra, and thermogravimetric analysis. The Cd-MOF fluorescence sensor has excellent selectivity and high sensitivity, which is of great significance for the development of luminescence sensing in metal organic framework materials. The possible mechanism is also discussed.
JOURNAL OF COORDINATION CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Kuaibing Wang, Changyun Chen, Yihao Li, Ye Hong, Hua Wu, Cheng Zhang, Qichun Zhang
Summary: Nanocomposites containing Ni, Co, or NiCo alloy and nitrogen-doped carbon were used as active elements in supercapacitors. The atomic contents were adjusted by adding Ni and Co salts. The NC/NiCo active materials showed superior electrochemical charge-storage performances due to their excellent surface groups and redox active sites. The NC/NiCo1/1 electrode performed better than other bimetallic/carbon and metal/carbon electrodes, thanks to factors such as high surface area, nitrogen content, Co/Ni ratio, and average pore size. The NC/NiCo electrode achieved a maximum capacity of 300.5 C g(-1) and 92.30% capacity retention after 3000 charge-discharge cycles, with a high energy density of 26.6 Wh kg(-1) achieved in the hybrid device.
Article
Chemistry, Multidisciplinary
Yan Wang, Ningning Gao, Jiaqi Hu
Summary: A zinc-based metal organic framework (MOF) [Zn(LBIX)(HEA)](n) (1) was synthesized using hydrothermal synthesis method with 4,4'-bis((1H-imidazol-1-yl)methyl)-1,1'-biphenyl (LBIX) and 1,2-phenylenediacetic acid (H(2)HEA) as ligands. The structure of the MOF was characterized using X-ray diffraction, elemental analysis, infrared spectroscopy, and thermogravimetric analysis. The fluorescence experiments demonstrated that the MOF exhibited strong fluorescence in aqueous solution and could be used for rapid identification of Fe3+, CrO42-, and Cr2O72- ions with high quenching efficiencies and low detection limits.
Article
Chemistry, Multidisciplinary
Ningning Gao, Yunyun Zhang, Jing Huang, Yan Wang
Summary: In this study, a high-performance fluorescent material, [Cd(2-bpmh)(BDC)H2O](n) (2-bpmh=1,4-bis(2-pyridyl)-2,3-diaza-1,3-butadiene, H2BDC=terephthalic acid), was successfully synthesized for the detection of toxic pollutants in water through solvothermal reaction. Single crystal X-ray analysis revealed that the material forms a one-dimensional chain structure and further assembles into a three-dimensional structure through hydrogen bonding interactions. The luminescence sensing research demonstrated that the material not only exhibited excellent luminescence quenching efficiency, but also selectively recognized Cr2O72-, CrO42-, and Fe3+ ions in water.
Article
Chemistry, Inorganic & Nuclear
Tianqi Chen, Sujuan Bian, Xutian Yang, Wenjie Lu, Kuaibing Wang, Yuxuan Guo, Cheng Zhang, Qichun Zhang
Summary: A hollow urchin-like Ni-based MOF material called NiPSC was synthesized and used directly as an active electrode material in supercapacitors. The NiPSC electrode exhibited excellent electrochemical performance, including high specific capacity, good rate capability, and outstanding cycling stability even under alkaline conditions. The NiPSC//AC device with NiPSC as the positive electrode and active carbon as the negative electrode showed promising capacitance retention, energy density, and potential practicality.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Physical
Ningning Gao, Min Zhang, Yan Wang
Summary: A novel complex [Zn(L)(HEA)]n (1) was synthesized by hydrothermal method, which exhibited excellent fluorescence detection performance and could be utilized for detecting Fe(III), Cr(VI), and some nitroimidazole antibiotics.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Inorganic & Nuclear
Yuxuan Guo, Changyun Chen, Yumeng Wang, Ye Hong, Hua Wu, Kuaibing Wang, Dongdong Niu, Cheng Zhang, Qichun Zhang
Summary: The Cu/CuxO@C electrodes prepared by calcination procedure exhibit excellent electrochemical performance in supercapacitors with larger specific surface area and better ion transport ability. Among them, the 900-BTC electrode performs the best in a three-electrode configuration and maintains a capacitance retention rate of 91.7% after 3000 cycles.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Angela Lis, Viorica Gladchi, Gheorghe Duca, Sergey Travin
Summary: This work presents studies on the photochemical transformations of TU and Cys with the addition of Cu(II) or Fe(III) ions. The results show that the oxidation rate of the thiols increases significantly when Cu(II) or Fe(III) ions are added to the system. It has also been found that TU and Cys can form stable complex compounds with the studied metal ions. The oxidation rates of the thiols are found to depend on the radiation intensity and emission spectrum of the irradiation sources.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Cristiane F. A. Teixeira, Estefane I. Teixeira, J. P. C. Nascimento, M. Amilcar Junior, L. M. C. Pinto, Anderson R. L. Caires, G. B. Alcantara, Ana C. Micheletti, Victor M. Deflon, Davi F. Back, Heveline Silva, Lucas Pizzuti, Gleison Antonio Casagrande
Summary: Novel binuclear heteroleptic copper(I) complexes based on mixed DPPE/thiocarbamoyl-pyrazoline ligands were synthesized and structurally characterized. These complexes exhibited similar structural behavior around the Copper(I) atoms and showed promising antimicrobial and anticancer activities.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Chen Chen, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Hai-Mei Qin
Summary: Thermally activated delayed fluorescent (TADF) Cu(I) halide complexes with short lifetimes and intense emissions were synthesized and characterized. These complexes exhibit intense green to yellow-green delayed fluorescence and are suitable for OLED devices.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Tian-Yu Zhang, Xue-Qian Wu, Heng-Yu Ruan, Yi Yuan, Le Wang, Ya-Pan Wu, Qing-Wen Han, Ruan Chi, Dong-Sheng Li
Summary: In this study, a novel Ni(II)-based metal-organic framework with good electrocatalytic oxidation performance was successfully synthesized, showing potential for direct alcohol fuel cells.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Susanta Das Baishnab, R. N. Dutta Purkayastha, Waldemar Maniukiewicz, Rosa M. Gomila, Antonio Frontera
Summary: The synthesis, structure, and DNA binding ability of three decavanadate complexes containing cationic organic moieties were reported. The complexes were characterized by various techniques and their solid-state structures were analyzed. The complexes showed interesting assembly patterns and exhibited moderately strong intercalative binding with CTDNA. Additionally, their micellization behavior in the presence of the surfactant CTAB was studied.
INORGANICA CHIMICA ACTA
(2024)
Review
Chemistry, Inorganic & Nuclear
Jubaraj B. Baruah
Summary: Isomorphous series are generated by replacing atoms or molecules to form materials with similar compositions. They allow modulation of structure and properties, and generate equivalent compositions with novel material properties. The study of stereo-electronic aspects of different equivalent compositions can improve the utility of the original composition.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Kamelah S. Al-Rashdi, Bandar A. Babgi, Ehab M. M. Ali, Bambar Davaasuren, Abdul-Hamid M. Emwas, Mariusz Jaremko, Mark G. Humphrey, Mostafa A. Hussien
Summary: Tridentate ligands were used to synthesize a set of palladium complexes, which were characterized and found to have DNA and BSA binding abilities. The complexes also showed differences in anticancer activities.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Diane Isaacs, Chandler Cox, Mark A. Bezpalko, W. Scott Kassel, William G. Dougherty
Summary: The structure and electrochemical properties of zinc(II) complexes with a face-capping ligand have been investigated, revealing the effect of the ligand on bound semiquinonate (SQ) radicals. The substitution pattern of the SQ ring plays a crucial role in determining the fate of the bound SQ radicals. Additionally, the protective pocket formed by the ligand's phenyl substituents is unable to prevent decomposition of SQ radicals with minimal steric bulk, suggesting that substitution of the SQ ring is the main contributor to their stabilization.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Xingliang Chen, Zhiqiang Jiang
Summary: Here, a series of zinc tetrahedral tetrazolate frameworks (Zn-TTFs) are presented, and it is demonstrated that rotation of carboxyl group can generate structural diversity. Compound 3 exhibits a unique zeolite-like structure, while compound 4 shows both super acid and alkali resistance.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Ankita Puri, Allison Mcaninch, Sheng Shu, Khashayar Rajabimoghadam, Maxime A. Siegler, Marcel Swart, Isaac Garcia-Bosch
Summary: In this article, the synthesis and characterization of copper, nickel, and palladium complexes bound by bidentate ligands derived from ortho-phenylenediamine are described. The complexes contain tunable H-bond donors and their crystal structures reveal intramolecular H-bonding interactions between the ligand scaffolds. Variations in the coordination sphere led to the isolation of the complexes in square-planar or twisted pseudo-tetrahedral geometries. Structural analysis showed that intramolecular H-bonding interactions can be altered by disrupting the bonds between countercations, solvent of crystallization, and ligand scaffold, resulting in changes in the geometry of the complexes. DFT calculations confirmed that Cu complexes prefer twisted geometries while Ni and Pd complexes favor square-planar geometries.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Laiane dos Santos Oliveira, Pedro Henrique de Souza Guarda, Leticia Bazilio Rosa, Gustavo Clauss Rodrigues, Daniele Daiane Affonso, Joao Ernesto de Carvalho, Igor Andrade Santos, Mark Harris, Douglas Hideki Nakahata, Jose Ricardo Sabino, Danilo Ciccone Miguel, Ana Lucia Tasca Gois Ruiz, Ana Carolina Gomes Jardim, Camilla Abbehausen
Summary: Chalcones are chemical precursors of flavonoids that have various biological properties. In this study, novel copper(II)-2'-hydroxy-4-benzyloxychalcone complexes were synthesized and evaluated for their antileishmanial, antiproliferative, and antiviral activities. The results demonstrated that these complexes showed potential effects against tumor cells, leishmania parasites, and SARS-CoV-2 virus. The study also highlighted the influence of ligand structure on biological activity.
INORGANICA CHIMICA ACTA
(2024)
Review
Chemistry, Inorganic & Nuclear
Archana Thakur, Harpreet Kaur, Vishal Tyagi
Summary: This review article discusses the findings of research on the 13C NMR spectra of di- and tri-butyltin carboxylates, highlighting the importance of 13C NMR chemical shifts in determining the chemical surroundings of carbon nuclei and their role in structure elucidation.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Qiang Zhao, Qi-Yang Li, Zhi Shen, Guo Zang, Wen-Jun Lv
Summary: In this study, five metal complexes were synthesized using a solvothermal reaction and their structures were analyzed by single crystal X-ray diffraction. Fluorescence and magnetic properties of some complexes were also investigated.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Jeremy Erb, Darcy Setter, Jake Swavey, Frederick Willits, Shawn Swavey
Summary: Three BODIPY-Ru(II) complexes were synthesized by coordinating [Ru(bpy)2Cl]+ complexes to BODIPY ligands. The spectroscopic and electrochemical properties of the complexes were characterized. The complexes exhibited intense absorption peaks due to the pi pi* transitions localized on the BODIPY core, and additional charge transfer transitions associated with the metal center. The complexes showed significant singlet oxygen generation and were able to induce photo-nicking of DNA.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Sahin Reja, Dilip Sarkar, Kaushik Sarkar, Deboshmita Mukherjee, T. K. S. Fayaz, Palash Sanphui, Rajesh Kumar Das
Summary: A promising bioinspired metallocatalyst has been produced and characterized, showing high catalytic activity in oxygen dependant enzymatic radical pathway. The catalyst also exhibits inter and intra molecular H-bonding and C-H-pi interactions.
INORGANICA CHIMICA ACTA
(2024)