Fe–Cu octahedral carbide clusters, and the replacement of their labile halide ligands: Synthesis, solid state structure, substitution and electrochemical reactivity of [Fe5C(CO)14(CuBr)]2−, [Fe4C(CO)12(CuCl)2]2−, [{Fe4Cu2C(CO)12(μ-Cl)}2]2−, [Fe5C(CO)14(CuOC4H8)]− and [Fe4C(CO)12(CuNCMe)2]

Title

Fe–Cu octahedral carbide clusters, and the replacement of their labile halide ligands: Synthesis, solid state structure, substitution and electrochemical reactivity of [Fe5C(CO)14(CuBr)]2−, [Fe4C(CO)12(CuCl)2]2−, [{Fe4Cu2C(CO)12(μ-Cl)}2]2−, [Fe5C(CO)14(CuOC4H8)]− and [Fe4C(CO)12(CuNCMe)2]

Authors

Keywords

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Journal

INORGANICA CHIMICA ACTA

Volume 363, Issue 3, Pages 586-594

Publisher

Elsevier BV

Online

2009-02-01

DOI

10.1016/j.ica.2009.01.025