Article
Chemistry, Inorganic & Nuclear
Qumars Poladian, Onur Sahin, Tuncay Karakurt, Berat Ilhan-Ceylan, Yasemin Kurt
Summary: A new unsymmetrical N2O2-tetradentate Schiff-base complex of zinc(II) was synthesized and characterized by various analytical techniques. Experimental and theoretical data were compared comprehensively, with molecular docking studies and antioxidant capacity evaluation conducted to support in vitro studies.
Article
Chemistry, Physical
Mayada S. Ali, Mohamad Hasan
Summary: The study investigated the chelating capability of H2L with various metal ions, revealing different coordination structures and properties. The complexes were classified into conducting and nonconducting based on molar conductivity values, with unique coordination modes identified through IR and NMR spectra analysis. The anti-bacterial activity of the VO2+ complex was highlighted, while some complexes exhibited unique structures like binuclear coordination and S bridge connections.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Inorganic & Nuclear
Berat Ilhan-Ceylan, Olcay Bolukbasi, Ayberk Yilmaz, Kerem Kaya, Yasemin Kurt, Bahri Ulkuseven
Summary: The new compounds and their complexes were synthesized and characterized using various analytical techniques, including single crystal X-ray diffraction. The molybdenum atom in the complex exhibits a distorted octahedral coordination, with the sixth coordination site occupied by a methanol molecule.
Article
Chemistry, Physical
Mohammed Bakir, Mark A. W. Lawrence, Junior Johnson, Colin McMillen
Summary: The study reported the structure characterization and electrochemical properties of fac-[Re(CO)(3)(kappa(2)-N-im,S-bptsc)Cl] (2) synthesized by reacting Re(CO)5Cl and benzophenone thiosemicarbazone in toluene with air. The authenticity of compound 2 was confirmed through elemental analysis, spectroscopic measurements, and X-ray crystallographic analysis, with findings of structural changes in its electrochemical behavior elucidated. Potential mechanisms for the oxidative and reductive electrochemical decomposition of 1 and 2 were proposed and found to be in good agreement with literature reports on related compounds.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Multidisciplinary
Fathy A. El-Saied, Mohamad M. E. Shakdofa, Mayada S. Ali, Reham M. W. Faried, Ahmed El-Asmy, Metwally Madkour
Summary: In this study, complexes of N-ethyl-2-(2-hydroxybenzylidene) hydrazine-1-carbothioamide with Pd2+, Pt2+, Ni2+ and Cu2+ were prepared and characterized. Ni2+, Pd2+ and Pt2+ complexes were used as single precursors for noble metal/metal oxide nanoparticles, with Pt/NiO exhibiting the highest photocatalytic activity.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2021)
Article
Multidisciplinary Sciences
Elesha R. Hoffarth, Kersti Caddell Haatveit, Eugene Kuatsjah, Gregory A. MacNeil, Simran Saroya, Charles J. Walsby, Lindsay D. Eltis, K. N. Houk, Marc Garcia-Borras, Katherine S. Ryan
Summary: Recent study uncovers a mechanism by which the organic cofactor PLP activates molecular oxygen for oxidation reactions, particularly in the desaturation or hydroxylation of arginine. The proposed mechanism suggests the precise positioning of a water molecule in the active site plays a crucial role in controlling the final reaction outcome. This mechanism provides a unified framework to understand the activation of oxygen by PLP-dependent enzymes and elucidates a shared mechanistic pathway and intertwined evolutionary history for arginine desaturases and hydroxylases.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2021)
Article
Biochemistry & Molecular Biology
Dusan S. Dimic, Goran N. Kaluderovic, Edina H. Avdovic, Dejan A. Milenkovic, Marko N. Zivanovic, Ivan Potocnak, Erika Samolova, Milena S. Dimitrijevic, Luciano Saso, Zoran S. Markovic, Jasmina M. Dimitric Markovic
Summary: In this study, four new compounds synthesized from 4-hydroxycoumarin and tyramine/octopamine/norepinephrine/3-methoxytyramine were characterized and analyzed spectroscopically, chromatographically, and structurally. The stability, antitumor activity, and ecotoxicology of these compounds were investigated using experimental and computational methods.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Chemistry, Physical
Mayada S. Ali, Fathy A. El-Saied, Mohamad ME. Shakdofa, Sadashiva Karnik, Laila A. Jaragh-Alhadad
Summary: Thiosemicarbazone compound exhibits significant anticancer activity, which is enhanced by the presence of metal ions. New Ni(II), Cu(II), Pd(II), and Pt(II) complexes synthesized from the ligand H3L showed potent antiproliferation activity at the micromolar level.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Applied
Nimya Ann Mathews, M. R. Prathapachandra Kurup
Summary: This study synthesized new ternary complexes derived from multisubstituted thiosemicarbazone ligands and characterized their properties using various spectroscopic and analytical methods. The complexes showed strong interactions with DNA, cleaving DNA without external agents, and exhibited potential cytotoxicity against human breast cancer cells.
APPLIED ORGANOMETALLIC CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Debasish Das, S. Kannan, Mukesh Kumar, Biswajit Sadhu, Liladhar B. Kumbhare
Summary: Researchers have synthesized a new platinum complex and found that it exhibits luminescence and catalytic properties. The mechanism of its catalytic reactions was further elucidated through theoretical calculations.
INORGANICA CHIMICA ACTA
(2022)
Article
Chemistry, Physical
K. Jayakumar, E. B. Seena, M. R. Prathapachandra Kurup, Savas Kayac, Goncagul Serdaroglu, E. Suresh, Riadh Marzouki
Summary: Six novel Ni(II) complexes of an NNS donor 2-benzoylpyridine-N-4-methyl-3-thiosemicarbazone(HL) were synthesized and characterized. The coordination behavior of thiosemicarbazone to the nickel center was studied using various physicochemical techniques. A four-coordinated Ni(II) complex [NiLN3] was crystallized, and its molecular and crystal structures were determined using single-crystal X-ray crystallography. The chemical reactivity of HL and the six Ni(II) complexes was evaluated using CAM-B3LYP quantum chemical calculations.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Physics, Applied
Jong Woo Kim, Mathew J. Cherukara, Ashish Tripathi, Zhang Jiang, Jin Wang
Summary: Coherent surface scattering imaging requires a mathematical conversion to visualize specimen structures, which can now be predicted using a deep learning neural network model to instantly obtain results from scattering patterns. This is highly beneficial for both experimental effectiveness and data analysis.
APPLIED PHYSICS LETTERS
(2021)
Article
Biochemistry & Molecular Biology
Danny Farhat, Fatemeh Rezaei, Milica Ristovski, Yidai Yang, Albert Stancescu, Lucia Dzimkova, Sabrina Samnani, Jean-Francois Couture, Jyh-Yeuan Lee
Summary: The ATP-binding cassette (ABC) sterol transporters play important roles in maintaining cholesterol homeostasis and preventing abnormal accumulation of plant sterols. The crystal structure analysis of ABCG5/G8 suggests a sterol-binding site and reveals its functional implications in cholesterol/sterol transport. Furthermore, docking analysis reveals the sterol-binding selectivity of ABCG5/G8, providing insights into its physiological role.
JOURNAL OF MOLECULAR BIOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Cen Chen, Ziyuan Fang, Zhen Huang
Summary: Crystallization phasing and obtaining high-quality crystals are major challenges for X-ray crystallographic analysis of nucleic acids. In this study, the authors addressed these challenges by incorporating selenium atoms into DNA duplexes, which resulted in larger and higher quality crystals compared to standard DNA crystals. These findings provide a simple strategy to overcome crystallization challenges in nucleic acid crystallography.
CRYSTAL GROWTH & DESIGN
(2022)
Article
Biochemistry & Molecular Biology
Charles Eldrid, Mire Zloh, Constantina Fotinou, Tamas Yelland, Lefan Yu, Filipa Mota, David L. Selwood, Snezana Djordjevic
Summary: Vascular endothelial growth factors (VEGFs) are essential regulators for blood and lymphatic vessels, interacting with neuropilins and tyrosine kinase receptors. The selectivity of neuropilins and VEGF receptors in binding to VEGF proteins affects their physiological roles. Studies have shown that conformational preferences of VEGF-derived peptides beyond the C-terminal arginine contribute to the ligand selectivity of neuropilins. These findings have implications for designing selective antagonists of neuropilin functions.
Article
Chemistry, Applied
Entsar A. Saad, Shadia A. Elsayed, Mohamed M. Hassanien, Menna S. AL-Adl
APPLIED ORGANOMETALLIC CHEMISTRY
(2020)
Article
Chemistry, Physical
Amany M. Ismail, Shadia A. El Sayed, Ian S. Butler, Sahar Mostafa
JOURNAL OF MOLECULAR STRUCTURE
(2020)
Article
Chemistry, Applied
Shadia A. Elsayed, Hoda M. El-Gharabawy, Ian S. Butler, Faten M. Atlam
APPLIED ORGANOMETALLIC CHEMISTRY
(2020)
Article
Biochemistry & Molecular Biology
Shadia A. Elsayed, Shane Harrypersad, Heba A. Sahyon, Mohammed Abu El-Magd, Charles J. Walsby
Article
Chemistry, Applied
Marwa E. El-Afify, Shadia A. Elsayed, Thanaa M. Shalaby, Elshahat A. Toson, Ahmed M. El-Hendawy
Summary: In this study, a series of V(IV), Mo(VI), and Ru(II) complexes containing the ligand 2,4-dihydroxyacetophenone-S-methyl dithiocarbazate (H(2)dhasm) were synthesized. These complexes exhibited good DNA binding ability, DNA cleavage activity, and showed high anti-tumor cell activity and antibacterial activity.
APPLIED ORGANOMETALLIC CHEMISTRY
(2021)
Article
Chemistry, Physical
Hala A. El Asmy, Ian S. Butler, Sahar I. Mostafa
Summary: This study focuses on synthesizing and characterizing Pd(II), Pt(II), Ag(I), and Rh(III) complexes with adenine and additional ligands, with the aim of developing new low-toxic and effective anticancer metal-based molecules. The in vitro anticancer activity against human breast cancer and ovarian cancer cell lines was evaluated using selected Pt(II) and Pt(II) mixed ligand complexes, and their CT-DNA-binding properties were studied using CD spectroscopy, showing intercalative capability.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Green & Sustainable Science & Technology
Eman M. Saad, Ian S. Butler, Sahar Mostafa
Summary: The article introduces a novel reduction process using ecofriendly vitamin C tablets to reduce toxic chromium(VI) ions to less harmful chromium(III) ions, with efficient adsorption properties on functionalized cellulose. The process also involves the use of green algae to enhance the uptake of reduced chromium ions.
ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY
(2021)
Article
Chemistry, Organic
Amany M. Ismail, Ian S. Butler, Weam M. Abou El Maaty, Sahar I. Mostafa
Summary: The synthesis of several metal complexes using indol-3-acetic acid as the primary chelate and N,N- or P- as the secondary chelate was reported in this study. The molecular structures and properties of these complexes were analyzed using various methods. Some of the complexes showed anticancer activity against human ovarian cancer cell lines, and their DNA-binding properties were investigated.
POLYCYCLIC AROMATIC COMPOUNDS
(2022)
Article
Multidisciplinary Sciences
Shimaa R. Dalal, Mervat H. Hussein, Noura El-Ahmady El-Naggar, Sahar I. Mostafa, Sami A. Shaaban-Dessuuki
Summary: Alginates derived from Sargassum latifolium have shown high biocompatibility, and can serve as growth promoters for Chlorella vulgaris, enhancing biomass production and total soluble proteins and carbohydrates. Additionally, sodium alginate hydrolysate supplementation can also increase total phenolics content and guaiacol peroxidase activity, showing promising effects on drug bead formulations.
SCIENTIFIC REPORTS
(2021)
Article
Chemistry, Applied
Shadia A. Elsayed, Islam M. Elnabky, Armando di Biase, Ahmed M. El-Hendawy
Summary: Four new mixed ligand copper(II) complexes were synthesized and characterized. Two complexes showed better in vitro anticancer activity compared to cisplatin, inducing DNA fragmentation and cell apoptosis. Further studies revealed their potential mechanisms of action in cancer cells.
APPLIED ORGANOMETALLIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Mohamed A. Ali, Sami A. Shaaban-Dessuuki, Noha A. El-Wassefy, Sahar I. Mostafa, Mervat H. Hussein
Summary: A new AG-CMC-Agnp nanocomposite was synthesized for efficient removal of crude and waste diesel oil from water. The composite showed high adsorption capacity and excellent recyclability. Kinetic and isotherm studies revealed that diesel oil diffusion into the composite followed a pseudo-first order model and best fit with the Langmuir model, respectively.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Energy & Fuels
Sahar Mostafa, Mohamed A. Ali, Noha A. El-Wassefy, Eman M. Saad, Mervat H. Hussein
Summary: In this study, Agar-carboxymethylcellulose-silver nanoparticle (AG-CMC-AgNP) nanocomposite was successfully fabricated and characterized. The adsorption of methylene blue (MB) dye onto AG-CMC-AgNP was investigated, and the results showed that AG-CMC-AgNP had a high adsorption capacity and good adsorption performance for MB. The adsorption process followed the Langmuir isotherm and pseudo-second-order reaction kinetic model. The biosorbent was found to be reusable, although the adsorption capacity slightly decreased after multiple cycles.
BIOMASS CONVERSION AND BIOREFINERY
(2022)
Article
Materials Science, Multidisciplinary
Sahar Ibrahim Mostafa, Marwa S. S. Ismail, Hagag A. A. Mohammed, Manal F. F. Osman, Noha A. A. Elwassefy
Summary: Prepared and characterized a new nanocomposite, mag-HA-Ald np, for bone tissue scaffold formation. Iron oxide nanoparticles (Fe3O4 np) were added to aqueous solutions of Ca(NO3)(2)& BULL;4H(2)O and (NH4)(2)HPO4 to obtain mag-HA np. The structure of the nanocomposites was investigated using spectral and microscopy techniques, while the cytotoxicity was evaluated using MTT assay. The results confirmed the successful synthesis of mag-HA-Ald np and revealed a positive correlation between Ald and iron oxide content with cell viability. Additionally, magnetic field application significantly decreased cell viability.
EMERGENT MATERIALS
(2023)
Article
Biochemistry & Molecular Biology
Shadia A. Elsayed, Elham E. Saleh, Mohamed M. Aboelnaga, Elshahat A. Toson
Summary: Two silver(I) complexes ([Ag2(L)2] (1) and [Ag(L)(PPh3)2](2)) were synthesized and characterized. The molecular structures of the ligands and complexes were determined using Density Function Theory (DFT) calculations. The complexes showed different coordination geometries and exhibited high toxicity towards cancer cells. Flow cytometry and gene expression analysis suggest that the complexes induce cell cycle arrest and apoptosis in cancer cells.
JOURNAL OF INORGANIC BIOCHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Sahar Ibrahim Mostafa, Nesma M. Abdelfattah, Sayed M. Ghorab, Manal F. Osman, Noha A. Elwassefy
Summary: This study reports the preparation and characterization of new biocompatible injectable bone paste (IBP) nanocomposites, including hydroxyapatite-gelatin (HA-Gel) and hydroxyapatite-gelatin-alendronate (HA-Gel-Ald np). The IBP nanocomposites HA-Gel np were synthesized from mixing gelatin with aqueous solutions of Ca(NO3)(2).4H(2)O and (NH4)(2)HPO4. The target nanocomposites HA-Gel-Ald np were obtained by reacting alendronate (Ald) aqueous solution with HA-Gel np nanocomposites. The physico-chemical measurements confirmed the successful isolation of HA-Gel np and HA-Gel-Ald np nanocomposites with different ratios, and the cytotoxicity of the nanocomposites on stem cells was assessed.
EMERGENT MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Angela Lis, Viorica Gladchi, Gheorghe Duca, Sergey Travin
Summary: This work presents studies on the photochemical transformations of TU and Cys with the addition of Cu(II) or Fe(III) ions. The results show that the oxidation rate of the thiols increases significantly when Cu(II) or Fe(III) ions are added to the system. It has also been found that TU and Cys can form stable complex compounds with the studied metal ions. The oxidation rates of the thiols are found to depend on the radiation intensity and emission spectrum of the irradiation sources.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Cristiane F. A. Teixeira, Estefane I. Teixeira, J. P. C. Nascimento, M. Amilcar Junior, L. M. C. Pinto, Anderson R. L. Caires, G. B. Alcantara, Ana C. Micheletti, Victor M. Deflon, Davi F. Back, Heveline Silva, Lucas Pizzuti, Gleison Antonio Casagrande
Summary: Novel binuclear heteroleptic copper(I) complexes based on mixed DPPE/thiocarbamoyl-pyrazoline ligands were synthesized and structurally characterized. These complexes exhibited similar structural behavior around the Copper(I) atoms and showed promising antimicrobial and anticancer activities.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Chen Chen, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Hai-Mei Qin
Summary: Thermally activated delayed fluorescent (TADF) Cu(I) halide complexes with short lifetimes and intense emissions were synthesized and characterized. These complexes exhibit intense green to yellow-green delayed fluorescence and are suitable for OLED devices.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Tian-Yu Zhang, Xue-Qian Wu, Heng-Yu Ruan, Yi Yuan, Le Wang, Ya-Pan Wu, Qing-Wen Han, Ruan Chi, Dong-Sheng Li
Summary: In this study, a novel Ni(II)-based metal-organic framework with good electrocatalytic oxidation performance was successfully synthesized, showing potential for direct alcohol fuel cells.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Susanta Das Baishnab, R. N. Dutta Purkayastha, Waldemar Maniukiewicz, Rosa M. Gomila, Antonio Frontera
Summary: The synthesis, structure, and DNA binding ability of three decavanadate complexes containing cationic organic moieties were reported. The complexes were characterized by various techniques and their solid-state structures were analyzed. The complexes showed interesting assembly patterns and exhibited moderately strong intercalative binding with CTDNA. Additionally, their micellization behavior in the presence of the surfactant CTAB was studied.
INORGANICA CHIMICA ACTA
(2024)
Review
Chemistry, Inorganic & Nuclear
Jubaraj B. Baruah
Summary: Isomorphous series are generated by replacing atoms or molecules to form materials with similar compositions. They allow modulation of structure and properties, and generate equivalent compositions with novel material properties. The study of stereo-electronic aspects of different equivalent compositions can improve the utility of the original composition.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Kamelah S. Al-Rashdi, Bandar A. Babgi, Ehab M. M. Ali, Bambar Davaasuren, Abdul-Hamid M. Emwas, Mariusz Jaremko, Mark G. Humphrey, Mostafa A. Hussien
Summary: Tridentate ligands were used to synthesize a set of palladium complexes, which were characterized and found to have DNA and BSA binding abilities. The complexes also showed differences in anticancer activities.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Diane Isaacs, Chandler Cox, Mark A. Bezpalko, W. Scott Kassel, William G. Dougherty
Summary: The structure and electrochemical properties of zinc(II) complexes with a face-capping ligand have been investigated, revealing the effect of the ligand on bound semiquinonate (SQ) radicals. The substitution pattern of the SQ ring plays a crucial role in determining the fate of the bound SQ radicals. Additionally, the protective pocket formed by the ligand's phenyl substituents is unable to prevent decomposition of SQ radicals with minimal steric bulk, suggesting that substitution of the SQ ring is the main contributor to their stabilization.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Xingliang Chen, Zhiqiang Jiang
Summary: Here, a series of zinc tetrahedral tetrazolate frameworks (Zn-TTFs) are presented, and it is demonstrated that rotation of carboxyl group can generate structural diversity. Compound 3 exhibits a unique zeolite-like structure, while compound 4 shows both super acid and alkali resistance.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Ankita Puri, Allison Mcaninch, Sheng Shu, Khashayar Rajabimoghadam, Maxime A. Siegler, Marcel Swart, Isaac Garcia-Bosch
Summary: In this article, the synthesis and characterization of copper, nickel, and palladium complexes bound by bidentate ligands derived from ortho-phenylenediamine are described. The complexes contain tunable H-bond donors and their crystal structures reveal intramolecular H-bonding interactions between the ligand scaffolds. Variations in the coordination sphere led to the isolation of the complexes in square-planar or twisted pseudo-tetrahedral geometries. Structural analysis showed that intramolecular H-bonding interactions can be altered by disrupting the bonds between countercations, solvent of crystallization, and ligand scaffold, resulting in changes in the geometry of the complexes. DFT calculations confirmed that Cu complexes prefer twisted geometries while Ni and Pd complexes favor square-planar geometries.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Laiane dos Santos Oliveira, Pedro Henrique de Souza Guarda, Leticia Bazilio Rosa, Gustavo Clauss Rodrigues, Daniele Daiane Affonso, Joao Ernesto de Carvalho, Igor Andrade Santos, Mark Harris, Douglas Hideki Nakahata, Jose Ricardo Sabino, Danilo Ciccone Miguel, Ana Lucia Tasca Gois Ruiz, Ana Carolina Gomes Jardim, Camilla Abbehausen
Summary: Chalcones are chemical precursors of flavonoids that have various biological properties. In this study, novel copper(II)-2'-hydroxy-4-benzyloxychalcone complexes were synthesized and evaluated for their antileishmanial, antiproliferative, and antiviral activities. The results demonstrated that these complexes showed potential effects against tumor cells, leishmania parasites, and SARS-CoV-2 virus. The study also highlighted the influence of ligand structure on biological activity.
INORGANICA CHIMICA ACTA
(2024)
Review
Chemistry, Inorganic & Nuclear
Archana Thakur, Harpreet Kaur, Vishal Tyagi
Summary: This review article discusses the findings of research on the 13C NMR spectra of di- and tri-butyltin carboxylates, highlighting the importance of 13C NMR chemical shifts in determining the chemical surroundings of carbon nuclei and their role in structure elucidation.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Qiang Zhao, Qi-Yang Li, Zhi Shen, Guo Zang, Wen-Jun Lv
Summary: In this study, five metal complexes were synthesized using a solvothermal reaction and their structures were analyzed by single crystal X-ray diffraction. Fluorescence and magnetic properties of some complexes were also investigated.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Jeremy Erb, Darcy Setter, Jake Swavey, Frederick Willits, Shawn Swavey
Summary: Three BODIPY-Ru(II) complexes were synthesized by coordinating [Ru(bpy)2Cl]+ complexes to BODIPY ligands. The spectroscopic and electrochemical properties of the complexes were characterized. The complexes exhibited intense absorption peaks due to the pi pi* transitions localized on the BODIPY core, and additional charge transfer transitions associated with the metal center. The complexes showed significant singlet oxygen generation and were able to induce photo-nicking of DNA.
INORGANICA CHIMICA ACTA
(2024)
Article
Chemistry, Inorganic & Nuclear
Sahin Reja, Dilip Sarkar, Kaushik Sarkar, Deboshmita Mukherjee, T. K. S. Fayaz, Palash Sanphui, Rajesh Kumar Das
Summary: A promising bioinspired metallocatalyst has been produced and characterized, showing high catalytic activity in oxygen dependant enzymatic radical pathway. The catalyst also exhibits inter and intra molecular H-bonding and C-H-pi interactions.
INORGANICA CHIMICA ACTA
(2024)
