Journal
INORGANICA CHIMICA ACTA
Volume 362, Issue 7, Pages 2519-2522Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2008.10.019
Keywords
Dye-sensitized solar cell; Ruthenium(II) complex; 2-Quinolinecarboxylate ligand
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Funding
- Incorporated Administrative Agency New Energy and Industrial Technology Development Organization (NEDO) under Ministry of Economy, Trade and Industry (METI)
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A new type of ruthenium(II) complex containing a 2-quinolinecarboxylate ligand was designed and synthesized as a sensitizer for dye-sensitized solar cells, and its photophysical and photochemical properties were characterized. The solar cells created with this complex exhibited efficient panchromatic sensitization over the entire visible wavelength range extending into the near-IR region. An overall conversion efficiency of 8.2% was attained under standard air mass 1.5 irradiation (100 mW cm (2)) with the short-circuit photocurrent density of 18.2 mA cm (2), the open-circuit photovoltage of 0.63 V and the fill factor of 0.72. (C) 2008 Elsevier B.V. All rights reserved.
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