4.2 Article

Calcium bismuth borates in the CaO-Bi2O3-B2O3 system

Journal

INORGANIC MATERIALS
Volume 44, Issue 1, Pages 70-75

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0020168508010123

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The 600 degrees C (subsolidus) section of the CaO-Bi2O3-B2O3 phase diagram has been studied by x-ray diffraction and differential thermal analysis. A new calcium bismuth borate of composition CaBi2B4O10 has been identified, and the existence of CaBi2B2O7 has been confirmed. According to T-x phase diagram data, these compounds form peritectically at 700 +/- 5 and 783 +/- 5C, respectively.

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