Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 29, Issue -, Pages 82-84Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2012.12.008
Keywords
Nickel coordination polymer; N-acetylsalicylhydrazide; 1D chain; Antiferromagnetic interaction; X-ray crystallography
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Funding
- Foundation for Science and Technology (FCT), Portugal [PTDC/QUI-QUI/102150/2008, PEst-OE/QUI/UI0100/2011]
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Synthesis of an interesting Ni(II) 1D-chain, [Ni-3(ashz)(2)(DMF)(2)(H2O)(2)](n)center dot 4DMF (1.4DMF), derived from N-acetylsalicylhydrazide (H(3)ashz) has been reported. The unprecedented bridging coordination mode involving the phenoate oxygen of ashz(3-) leads to the formation of a polynuclear 1D-chain without any additional spacer ligand. The coordination polymer 1 contains the Ni(II) cations in octahedral and in square-planar environments and shows antiferromagnetic interactions. (c) 2013 Elsevier B.V. All rights reserved.
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