Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 25, Issue -, Pages 60-64Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2012.09.002
Keywords
Polyoxometalate; Hexa-nuclear Cu-I cluster; 5-(4-Pyridyl)-tetrazole ligand; Photochemical catalysis; Electrochemical properties
Categories
Funding
- National Natural Science Foundation of China [21171025, 21101015]
- New Century Excellent Talents in University [NCET-09-0853]
- Natural Science Foundation [201102003]
- Doctoral Initiation Project of Liaoning Province [20111147]
Ask authors/readers for more resources
Two new isostructural 2D compounds based on hexa-nuclear [Cu-6(I)(ptz)(6)] clusters and Keggin anions, [Cu-6(I)(ptz)(6)][H3XMo12O40]center dot 2H(2)O (X=P for 1; As for 2) (ptz=5-(4-pyridyl)-tetrazole), have been hydrothermally synthesized. The hexa-nuclear [Cu-6(I)(ptz)(6)] subunits are constructed from five [Cu2N4] units with a cycle connecting cycle mode and further connected by the ptz to form 1D chains. These adjacent 1D chains are further linked by the Keggin anions to construct the intriguing 2D networks. (C) 2012 Elsevier RV. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available