Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 16, Issue -, Pages 61-64Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2011.11.031
Keywords
Polyoxometalate; High-core cluster; Coordination geometry; Copper
Categories
Funding
- National Natural Science Foundation of China [20901067]
- Monash Fellowship Program
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Two polyanion clusters [Mo36O108(NO)(4)(H2O)(16)](12-) (1) and [Mo36O112(H2O)(16)Cu-0.5(H2O)(2)](7-) (2) were obtained through 'one-pot' reaction at ambient temperature and pressure. Both of 1 and 2 consist of {Mo-36} anionic clusters. Interestingly, compound 2 represents a case that the transitional metal copper is anchored into the framework of a giant {Mo-36} isopolyanion. (C) 2011 Elsevier B.V. All rights reserved.
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