Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 14, Issue 1, Pages 115-117Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2010.09.045
Keywords
Molecular oxide; Polytantalate; Lindqvist anion; Protonation
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The first protonated hexatantalate, [H2Ta6O19](6-), has been synthesized and structurally characterized. X-ray diffraction analysis revealed that the protons are selectively attached to the O atoms that bridge two Ta atoms. The overall structure of the [H2Ta6O19](6-) anion is virtually identical to that predicted by a DFT calculation. (C) 2010 Elsevier B.V. All rights reserved.
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