Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 14, Issue 10, Pages 1588-1590Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2011.06.009
Keywords
Solvothermal synthesis; Isonicotinate; Topology; Crystal structure; Gas sorption
Categories
Funding
- Natural Science Foundation of Fujian Province [2009J01045, 2008I0013, 2010J01029]
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A porous metal organic framework [(NiNi2II)-Ni-III(mu(3)-OH)(bdc)(1.5)(int)(3)](n) x(solvents) (1: bdc = 1,4-benzenedicarboxylate; int = isonicotinate) based on the trinuclear Ni-3(mu(3)-OH) units was solvothermally synthesized and structurally characterized. It features a three-dimensional 9-connected ncb-type framework with two kinds of cage substructures and large one-dimensional channels. Both N-2 and CO2 gas sorption studies of 1 were investigated to demonstrate the permanent porosity in 1. (C) 2011 Elsevier B.V. All rights reserved.
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