Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 14, Issue 4, Pages 554-557Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2011.01.023
Keywords
Palladium; Cerium; Heterobimetallic complexes; X-ray structure
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Funding
- Russian Foundation for Basic Research [09-03-00514, 09-03-12114, 10-03-90420]
- Foundation of President of the Russian Federation [NSh-65264.2010.3]
- Foundation of the Russian Academy of Sciences
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Reaction of Pd-3(mu-OOCMe)(6) with Ce-III acetate in acetic acid is strongly water-dependent, producing the tetranuclear bis-paddlewheel [Pd(mu- OOCMe)(4)Ce(OH2)(2)(mu,eta(2)-OOCMe)](2,) pentanuclear cation-anionic (Pd(mu- OOCMe)(4)Ce (HOOCMe)(2)(OH2)(2)](+) [Pd2Ce(mu-OOCMe)(8)](-) x 2MeCOOH x 1.5H(2)O and 17-nuclear {[Pd(mu-OOCMe)(4)Ce(OOCMe)(4)](2) [Pd-4(mu- OOCMe)(4)](2)(mu(4)-O)(8)CePd4}(OH)(3) complexes. (C) 2011 Elsevier B.V. All rights reserved.
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