Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 14, Issue 9, Pages 1479-1484Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2011.05.051
Keywords
Supramolecular isomers; Temperature-induced; Stacking modes; Luminescent properties
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Funding
- National Natural Science Foundation of China [20772037, 21071056]
- Science and Technology Planning Project of Guangdong Province [2006A10 902002, 2010B031100018]
- Natural Science Foundation of Guangdong Province [9251063101000006, 10351063101000001]
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Two copper (II) supramolecular isomers 1a and 1b formulated as [Cu(H2EDC)(2)](n) (H3EDC = 2-ethyl-1H-imidazole-4,5-dicarboxlylate) have been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. Coordination modes, hydrogen bonding interactions and stacking modes are different in the two isomers. Meanwhile, luminescent properties of the complexes were studied. (C) 2011 Published by Elsevier B.V.
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